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SAFETY DATA SHEET1. IdentificationProduct identifier NAP-GC Solvent BlendOther means of identificationProduct code 0302577Recommended use SolventRecommended restrictions None known.2. Hazard(s) identificationPhysical hazards Flammable liquids Category 4Health hazards Acute toxicity, oral Category 4Acute toxicity, dermal Category 4Environmental hazards Not classified.OSHA defined hazards Not classified.Label elementsSignal word WarningHazard statementH227 Combustible liquid.H302 Harmful if swallowed.H312 Harmful in contact with skin.Prevention P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking.P264 - Wash hands thoroughly after handling.P270 - Do not eat, drink or smoke when using this product.P280 - Wear protective gloves/protective clothing.P280 - Wear protective gloves/eye protection/face protection.Response P301 + P312 - If swallowed: Call a poison center/doctor if you feel unwell.P302 + P350 - If on skin: Wash with plenty of water.P330 - Rinse mouth.P362 - Take off contaminated clothing and wash before reuse.P370 + P378 - In case of fire: Use appropriate media to extinguish.Storage P403 + P235 - Store in a well-ventilated place. Keep cool.Disposal P501 - Dispose of contents/container in accordance with local/regional/national/internationalregulations.3. Composition/information on ingredientsMixturesChemical name Common name and synonyms CAS number %N-Methyl-2-Pyrrolidinone 872-50-4 80-1002-Butoxyethanol 111-76-2Non-hazardous and other components below reportable levels 0.1-1010-30*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.4. First-aid measuresInhalation If overexposure to vapors or mist, move to fresh air. Call a physician if breathing becomes difficult.1 / 8Material name: NAP-GC Solvent Blend2263 Version #: 01 Issue date: 09-09-2014SDS USSkin contact Wash off with soap and plenty of water. Call a POISON CENTER or doctor/physician if you feelunwell. Get medical attention if irritation develops and persists.Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.Ingestion Rinse mouth. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.Indication of immediatemedical attention and specialtreatment neededProvide general supportive measures and treat symptomatically. In case of shortness of breath,give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.General information In the case of accident or if you feel unwell, seek medical advice immediately (show the labelwhere possible). Ensure that medical personnel are aware of the material(s) involved, and takeprecautions to protect themselves. Wash contaminated clothing before reuse.5. Fire-fighting measuresSuitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).Unsuitable extinguishingmediaDo not use water jet as an extinguisher, as this will spread the fire.Specific hazards arising fromthe chemicalThe product is combustible, and heating may generate vapors which may form explosive vapor/airmixtures. During fire, gases hazardous to health may be formed.Special protective equipmentand precautions forfirefightersSelf-contained breathing apparatus and full protective clothing must be worn in case of fire.Fire-fightingequipment/instructionsIn case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can doso without risk.Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.General fire hazards Combustible liquid.6. Accidental release measuresPersonal precautions,protective equipment andemergency proceduresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).Wear appropriate protective equipment and clothing during clean-up. Do not touch damagedcontainers or spilled material unless wearing appropriate protective clothing. Ensure adequateventilation. Local authorities should be advised if significant spillages cannot be contained. Forpersonal protection, see section 8 of the SDS.Methods and materials forcontainment and cleaning upEliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keepcombustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water.Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Use a non-combustible material likevermiculite, sand or earth to soak up the product and place into a container for later disposal. Usewater spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer,basements or confined areas. Following product recovery, flush area with water.Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.Environmental precautions Avoid discharge into drains, water courses or onto the ground.7. Handling and storagePrecautions for safe handling Keep away from open flames, hot surfaces and sources of ignition. Do not get this material incontact with skin. Do not taste or swallow. Avoid contact with eyes. Avoid prolonged exposure.Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personal protectiveequipment. Observe good industrial hygiene practices. When using, do not eat, drink or smoke.Wash hands thoroughly after handling. Wash contaminated clothing before reuse.Conditions for safe storage,including anyincompatibilitiesKeep away from heat, sparks and open flame. Store in original tightly closed container. Store in acool, dry place out of direct sunlight. Store in a well-ventilated place. Store away from incompatiblematerials (see Section 10 of the SDS). Keep in an area equipped with sprinklers.8. Exposure controls/personal protectionOccupational exposure limitsUS. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)Components Type Value2-Butoxyethanol (CAS PEL 240 mg/m3111-76-2)2 / 8Material name: NAP-GC Solvent Blend2263 Version #: 01 Issue date: 09-09-2014SDS USUS. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)Components Type Value50 ppmUS. ACGIH Threshold Limit ValuesComponents Type Value2-Butoxyethanol (CAS TWA 20 ppm111-76-2)US. NIOSH: Pocket Guide to Chemical HazardsComponents Type Value2-Butoxyethanol (CAS TWA 24 mg/m3111-76-2)5 ppmUS. AIHA Workplace Environmental Exposure Level (WEEL) GuidesComponents Type ValueN-Methyl-2-Pyrrolidinone TWA 40 mg/m3(CAS 872-50-4)10 ppmBiological limit valuesACGIH Biological Exposure IndicesComponents Value Determinant Specimen Sampling Time200 mg/g Butoxyaceticacid (BAA),with hydrolysisCreatinine inurine2-Butoxyethanol (CAS *111-76-2)100 mg/l 5-Hydroxy-N-methyl-2-pyrrolidoneN-Methyl-2-Pyrrolidinone Urine *(CAS 872-50-4)* - For sampling details, please see the source document.Exposure guidelinesUS - California OELs: Skin designation2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.US - Minnesota Haz Subs: Skin designation applies2-Butoxyethanol (CAS 111-76-2) Skin designation applies.US - Tennesse OELs: Skin designation2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.US NIOSH Pocket Guide to Chemical Hazards: Skin designation2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.US WEEL Guides: Skin designationN-Methyl-2-Pyrrolidinone (CAS 872-50-4) Can be absorbed through the skin.US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.Appropriate engineeringcontrolsGood general ventilation (typically 10 air changes per hour) should be used. Ventilation rates shouldbe matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or otherengineering controls to maintain airborne levels below recommended exposure limits. If exposurelimits have not been established, maintain airborne levels to an acceptable level.Individual protection measures, such as personal protective equipmentEye/face protection Wear eye/face protection. Wear safety glasses with side shields (or goggles).Hand protection Wear protective gloves.Skin protectionOther Wear appropriate chemical resistant clothing.Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn.General hygieneconsiderationsWhen using, do not eat, drink or smoke. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.3 / 8Material name: NAP-GC Solvent Blend2263 Version #: 01 Issue date: 09-09-2014SDS US9. Physical and chemical propertiesAppearance Clear.Physical state Liquid.Form Liquid.Color Colorless.Odor Typical Solvent.Odor threshold Not available.pH Not available.Melting point/freezing point -94 °F (-70 °C) estimatedInitial boiling point andboiling range336.2 °F (169 °C) estimatedFlash point 161.6 °F (72.0 °C) Lowest Flashing componentEvaporation rate > 1 (Butyl Acetate = 1)Flammability (solid, gas) Not available.Upper/lower flammability or explosive limitsFlammability limit - lower(%)1.1 % estimatedFlammability limit -upper (%)10.6 % estimatedExplosive limit - lower(%)Not available.Explosive limit - upper(%)Not available.Vapor pressure 0.47 hPa 1 hPa = 0.75006 mmHg estimatedVapor density > 1 (Air = 1)Relative density Not available.Solubility(ies)Solubility (water) Soluble.Partition coefficient(n-octanol/water)Not available.Auto-ignition temperature 471.2 °F (244 °C) estimatedDecomposition temperature Not available.Viscosity Not available.Other informationDensity 1.01 g/cm3Flash point class Combustible IIIAPercent volatile 100 %Pounds per gallon 8.42 lb/galSpecific gravity 1.01VOC (Weight %) 100 %10. Stability and reactivityReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Chemical stability Stable under normal conditions.Possibility of hazardousreactionsNo hazardous reaction known under normal conditions of use.Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Suitable precautions should be utilizedif using this product at temperatures above the flash point. Contact with incompatible materials.Incompatible materials Strong oxidizers and strong acids. Peroxides. Phenols.Hazardous decompositionproductsNo hazardous decomposition products are known if stored and applied as directed.11. Toxicological informationInformation on likely routes of exposureIngestion Harmful if swallowed.Inhalation Prolonged inhalation may be harmful.4 / 8Material name: NAP-GC Solvent Blend2263 Version #: 01 Issue date: 09-09-2014SDS USSkin contact Harmful in contact with skin.2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated andprolonged. These effects have not been observed in humans.Eye contact Direct contact with eyes may cause temporary irritation.Symptoms related to thephysical, chemical andtoxicological characteristicsDirect contact with eyes may cause temporary rmation on toxicological effectsAcute toxicity Harmful if swallowed. Harmful in contact with skin. Expected to be a low hazard for usual industrialor commercial handling by trained ponents Species Test Results2-Butoxyethanol (CAS 111-76-2)LD50 RabbitDermalAcute400 mg/kgLC50 MouseInhalation700 ppm, 7 HoursRat 450 ppm, 4 HoursLD50 Guinea pigOral1.2 g/kgMouse 1.2 g/kgRabbit 0.32 g/kgRat 560 mg/kgLD50 MouseOther1130 mg/kgRabbit 280 mg/kgRat 340 mg/kgN-Methyl-2-Pyrrolidinone (CAS 872-50-4)LD50 RabbitDermalAcute8000 mg/kgLD50 MouseOral5130 mg/kgRat 3914 mg/kg4.2 ml/kgLD50 MouseOther54.5 mg/kgRat 80.5 mg/kg* Estimates for product may be based on additional component data not shown.Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.Serious eye damage/eyeirritationDirect contact with eyes may cause temporary irritation.Respiratory or skin sensitizationRespiratory sensitization Not available.Skin sensitization This product is not expected to cause skin sensitization.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.IARC Monographs. Overall Evaluation of Carcinogenicity2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans.US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.5 / 8Material name: NAP-GC Solvent Blend2263 Version #: 01 Issue date: 09-09-2014SDS USReproductive toxicity Possible reproductive hazard.Specific target organ toxicity- single exposureNot classified.Specific target organ toxicity- repeated exposureNot classified.Aspiration hazard Not available.Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin.2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated andprolonged. These effects have not been observed in humans.12. Ecological informationEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the ponents Species Test Results* Estimates for product may be based on additional component data not shown.2-Butoxyethanol (CAS 111-76-2)AquaticFish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hoursPersistence and degradability No data is available on the degradability of this product.Bioaccumulative potential No data available.Partition coefficient n-octanol / water (log Kow)2-Butoxyethanol 0.83N-Methyl-2-Pyrrolidinone -0.54Mobility in soil No data available.Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.13. Disposal considerationsDisposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material andits container must be disposed of as hazardous waste. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose of contents/container in accordance with local/regional/national/internationalregulations.Local disposal regulations Dispose in accordance with all applicable regulations.Waste from residues /unused productsDispose of in accordance with local regulations. Empty containers or liners may retain some productresidues. This material and its container must be disposed of in a safe manner (see: Disposalinstructions).Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.14. Transport informationDOT BULKUN number NA1993Proper shipping name Compounds, Cleaning Liquid (Ethylene Glycol Monobutyl Ether, N-Methyl Pyrrolidone)Hazard class Combustible LiquidPacking group IIIERG code 128DOT NON-BULKNot regulated as dangerous goods.15. Regulatory informationUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard,29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.CERCLA Hazardous Substance List (40 CFR 302.4)2-Butoxyethanol (CAS 111-76-2) Listed.6 / 8Material name: NAP-GC Solvent Blend2263 Version #: 01 Issue date: 09-09-2014SDS USUS. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - NoReactivity Hazard - NoSARA 302 Extremely hazardous substanceNot listed.SARA 311/312Hazardous chemicalYesSARA 313 (TRI reporting)Chemical name CAS number % by wt.N-Methyl-2-Pyrrolidinone 872-50-4 80-1002-Butoxyethanol 111-76-2 10-30Ethylene Glycol 107-21-1 0.1-10Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListNot regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Not regulated.Safe Drinking Water Act(SDWA)Not regulated.US state regulationsUS. Massachusetts RTK - Substance List2-Butoxyethanol (CAS 111-76-2)N-Methyl-2-Pyrrolidinone (CAS 872-50-4)US. New Jersey Worker and Community Right-to-Know Act2-Butoxyethanol (CAS 111-76-2) 500 LBSN-Methyl-2-Pyrrolidinone (CAS 872-50-4) 500 LBSUS. Pennsylvania RTK - Hazardous Substances2-Butoxyethanol (CAS 111-76-2)N-Methyl-2-Pyrrolidinone (CAS 872-50-4)US. Rhode Island RTKN-Methyl-2-Pyrrolidinone (CAS 872-50-4)US. California Proposition 65WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductiveharm.US - California Proposition 65 - CRT: Listed date/Developmental toxinN-Methyl-2-Pyrrolidinone (CAS 872-50-4) Listed: June 15, 2001International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*Australia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial Chemical Substances Yes(EINECS)Europe European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances Yes(PICCS)United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).7 / 8Material name: NAP-GC Solvent Blend2263 Version #: 01 Issue date: 09-09-2014SDS US16. Other information, including date of preparation or last revisionIssue date 09-09-2014Version # 01Disclaimer This information is based on data available to us and is accurate and reliable to the best of ourknowledge at the time of printing. However, no warranty is expressed or implied regarding theaccuracy or completeness of the information contained herein. Final determination of the suitabilityof this material for the use contemplated is the sole responsibility of the user. Buyer assumes allrisk and liabilities. Buyer accepts and uses this material on these conditions.Revision Information Physical & Chemical Properties: Multiple PropertiesTransport Information: Material Transportation InformationRegulatory Information: United States8 / 8Material name: NAP-GC Solvent Blend2263 Version #: 01 Issue date: 09-09-2014US ................
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