Material Safety Data Sheet
Material Safety Data Sheet
Issuing Date 14-Jan-2014
Revision Date 14-Jan-2014
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name
Airborne Everyday Caplets
Recommended Use
Vitamins.
Supplier Address Reckitt Benckiser 399 Interpace Parkway Parsippany NJ 07054 US Phone:973-404-2445 Fax:973-404-3000 Contact:Jason Hicks Email:jason.hicks@ Contact Phone479-254-4451
2. HAZARDS IDENTIFICATION
Emergency Overview
May cause eye irritation Possibly cancer hazard by inhalation
Revision Number 1
Appearance White
Physical State Solid/Powder, Solid.
Odor Characteristic
Potential Health Effects Principle Routes of Exposure
Acute Toxicity Eyes Skin Inhalation Ingestion
Chronic Effects
Aggravated Medical Conditions
Environmental Hazard
Eye contact. Skin contact.
May cause irritation. No known effect based on information supplied. No known effect based on information supplied. No hazard from product as supplied. Ingestion above therapeutic dose may cause nausea, vomiting, dizziness, and headache.
Titanium dioxide has been classified by the International Agency for Research on Cancer (IARC) as possibly carcinogenic to humans (Group 2B) by inhalation.
Pre-existing eye disorders. Respiratory disorders.
See Section 12 for additional Ecological Information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
.
Chemical Name Magnesium Oxide
Silicon dioxide
CAS-No 1309-48-4 7631-86-9
Weight % 1 - 5 1 - 5
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1123571 - Airborne Everyday Caplets
Revision Date 14-Jan-2014
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Zinc citrate
546-46-3
1 - 5
Titanium dioxide
13463-67-7
1 - 5
Sucrose
57-50-1
0.1 - 1
4. FIRST AID MEASURES
Eye Contact
Skin Contact
Inhalation Ingestion Notes to Physician
Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician. Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician. Move to fresh air. If symptoms persist, call a physician. Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician. Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Flammable Properties
Not flammable.
Flash Point
Not determined.
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact
No.
Sensitivity to Static Discharge
No.
Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA
Health Hazard 1
Flammability 0
Stability 0
Physical and Chemical Hazards -
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Environmental Precautions Methods for Containment Methods for Cleaning Up
Avoid contact with eyes. Avoid dust formation. Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so. Use personal protective equipment. Pick up and transfer to properly labeled containers. Avoid dust formation. Clean contaminated surface thoroughly.
7. HANDLING AND STORAGE
Handling Storage
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes.
Keep container tightly closed.
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Chemical Name Magnesium Oxide
1309-48-4 Silicon dioxide
7631-86-9 Titanium dioxide
13463-67-7 Sucrose 57-50-1
ACGIH TLV TWA: 10 mg/m3inhalable fraction
10 mg/m3
TWA: 10 mg/m3
TWA: 10 mg/m3
OSHA PEL
20 mppcf TWA; ((80)/(% SiO2) mg/m3)
TWA: 15 mg/m3total dust (vacated) TWA: 10 mg/m3total dust
TWA: 15 mg/m3total dust TWA: 5 mg/m3respirable fraction (vacated) TWA: 15 mg/m3total dust (vacated) TWA: 5 mg/m3respirable
fraction
NIOSH IDLH
IDLH: 3000 mg/m3 TWA: 6 mg/m3
IDLH: 5000 mg/m3
TWA: 10 mg/m3 total dust TWA: 5 mg/m3 respirable dust
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.
Other Exposure Guidelines
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
Engineering Measures
Showers Eyewash stations Ventilation systems
Personal Protective Equipment Eye/Face Protection Skin and Body Protection Respiratory Protection
No special protective equipment required. No special protective equipment required. No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor Threshold pH
Flash Point Decomposition Temperature Melting Point/Range
Flammability Limits in Air
White. No information available No information available
No information available. No information available No information available
No information available
Water Solubility Evaporation Rate Vapor Density
Miscible with water No information available No data available
Odor Physical State
Autoignition Temperature Boiling Point/Range
Explosion Limits
Solubility Vapor Pressure
Characteristic. Solid/Powder Solid
No information available No information available
No information available
No information available No data available
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10. STABILITY AND REACTIVITY
Stability Incompatible Products Conditions to Avoid Hazardous Decomposition Products Hazardous Polymerization
Stable under recommended storage conditions. None known. Dust formation. Carbon oxides.
Hazardous polymerization does not occur.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity Product Information
Product does not present an acute toxicity hazard based on known or supplied information.
Chronic Toxicity Chronic Toxicity
Carcinogenicity
Chemical Name Silicon dioxide Titanium dioxide
Titanium dioxide has been classified by the International Agency for Research on Cancer (IARC) as possibly carcinogenic to humans (Group 2B) by inhalation.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
ACGIH
IARC Group 3 Group 2B
NTP
OSHA X
IARC: (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Group 3 - Not Classifiable as to Carcinogenicity in Humans OSHA: (Occupational Safety & Health Administration) X - Present
Target Organ Effects
Eyes. Lungs. Respiratory system. Skin.
12. ECOLOGICAL INFORMATION
Ecotoxicity The environmental impact of this product has not been fully investigated.
Chemical Name Silicon dioxide
Toxicity to Algae EC50: 440 mg/L (72 h )
Pseudokirchneriella subcapitata
Toxicity to Fish
Toxicity to Microorganisms Daphnia Magna (Water Flea)
LC50: 5000 mg/L (96 h static)
EC50: 7600 mg/L (48 h )
Brachydanio rerio
Ceriodaphnia dubia
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1123571 - Airborne Everyday Caplets
Revision Date 14-Jan-2014
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13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods
This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261).
Contaminated Packaging
Dispose of in accordance with local regulations.
US EPA Waste Number
D010
California Hazardous Waste Codes 331
Chemical Name Zinc citrate
California EHW
California Carc
California Hazardous Waste California Waste - Part 2
Toxic
STLC (for PBTs): 250 mg/L
TTLC (for PBTs): 5000 mg/kg
14. TRANSPORT INFORMATION
DOT TDG MEX ICAO IATA IMDG/IMO
NOT REGULATED Not regulated Not regulated Not regulated Not regulated Not regulated
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