A-level Chemistry Mark Scheme January 2010

Version 1.1: 21/01

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General Certificate of Education

Chemistry 1421

CHEM1 Foundation Chemistry

Mark Scheme

2010 examination - January series

Mark schemes are prepared by the Principal Examiner and considered, together with the relevant questions, by a panel of subject teachers. This mark scheme includes any amendments made at the standardisation meeting attended by all examiners and is the scheme which was used by them in this examination. The standardisation meeting ensures that the mark scheme covers the candidates' responses to questions and that every examiner understands and applies it in the same correct way. As preparation for the standardisation meeting each examiner analyses a number of candidates' scripts: alternative answers not already covered by the mark scheme are discussed at the meeting and legislated for. If, after this meeting, examiners encounter unusual answers which have not been discussed at the meeting they are required to refer these to the Principal Examiner.

It must be stressed that a mark scheme is a working document, in many cases further developed and expanded on the basis of candidates' reactions to a particular paper. Assumptions about future mark schemes on the basis of one year's document should be avoided; whilst the guiding principles of assessment remain constant, details will change, depending on the content of a particular examination paper.

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Chemistry - AQA GCE Mark Scheme 2010 January series

Question Part Sub Marking Guidance Part

1

(a)

2s22p63s1

Mark 1

1

(b) (i) Energy/enthalpy (needed) to remove one mole of electrons from 1

one mole of atoms/compounds/molecules/elements

OR

Energy to form one mole of positive ions from one mole of atoms OR

Energy/enthalpy to remove one electron from one atom

In the gaseous state (to form 1 mol of gaseous ions)

1

1

(b) (ii) Mg+(g) ? Mg2+(g) + e (?)

1

Mg+(g) + e (?) ? Mg2+(g) + 2e (?)

Mg+(g) - e (?) ? Mg2+(g)

1

(b) (iii) Electron being removed from a positive ion (therefore need more 1

energy)/ electron being removed is closer to the nucleus/Mg+

smaller (than Mg)/Mg+ more positive than Mg

1

(b) (iv) Range from 5000 to 9000 kJ mol-1

1

1

(c)

Increase

1

Bigger nuclear charge (from Na to Cl)/more protons

1

electron (taken) from same (sub)shell/ similar or same shielding/ 1 electron closer to the nucleus/smaller atomic radius

Comments

1s2 can be rewritten Allow 2s22px22py22pz23s1 Allow subscripts and capitals Energy given out loses M1

M2 is dependent on a reasonable attempt at M1

Energy needed for this change X(g) ? X+(g) + e (?) = 2 marks This equation alone scores one mark

Do not penalise MG Not equation with X

Allow from a + particle/ species Not electron from a higher energy level/or higher sub-level More protons = 0

If decrease CE = 0/3 If blank mark on QWC

If no shielding = 0 Smaller ionic radius = 0

3

1

(d)

Lower

Two/pair of electrons in (3)p orbital or implied repel (each other)

1

(e)

Boron/B or oxygen/O/ O2

Chemistry - AQA GCE Mark Scheme 2010 January series

1

If not lower CE = 0/3

If blank mark on

Allow does not increase

1

Not 2p

1

M3 dependent upon a reasonable

attempt at M2

1

4

Question Part Sub Marking Guidance Part

2

(a) (i) Mr = 132.1

0.0238

2

(a) (ii) 0.0476

2

(a) (iii) 1.21

2

(b)

34 x 100 212.1

= 16.0(3)%

2

(c)

100(%)

2

(d)

PV = nRT or n = PV

RT

n

= 100000 x 1.53 x 10-2

8.31 x 310

= 0.59(4)

5

Chemistry - AQA GCE Mark Scheme 2010 January series

Mark 1 1

1 1 1

1 1 1 1 1

Comments

132

Allow 0.024 Allow 0.0237 Penalise less than 2 sig fig once in (a)

0.0474-0.0476 Allow (a) (i) x 2

Allow consequential from (a) (ii) ie allow (a) (ii) x 1000 / 39.30 Ignore units even if wrong

Allow mass or Mr of desired product times one hundred divided by total mass or Mr of reactants/products If 34/212.1 seen correctly award M1 Allow 16% 16 scores 2 marks

Ignore all working

If rearranged incorrectly lose M1 and M3

M2 for mark for converting P and T into correct units in any expression

Allow 0.593 M3 consequential on transcription error only not on incorrect P and T

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