Modern inorganic chemistry - Русхим-магазин
Modern
inorganic chemistry
AN INTERMEDIATE TEXT
C. CHAMBERS, B.Sc., Ph.D., A.R.I.C.
Senior Chemistry Master,
Bolton School
A. K. HOLLIDAY, Ph.D., D.Sc., F.R.I.C.
Professor of Inorganic Chemistry,
The University of Liverpool
BUTTERWORTHS
THE BUTTERWORTH GROUP
ENGLAND
Butterworth & Co (Publishers) Ltd
London: 88 Kingsway, WC2B 6AB
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First published 1975
?
Butterworth & Co (Publishers) Ltd 1975
Printed and bound in Great Britain by R. .).
Acford Ltd., Industrial Estate, Chichester,
Sussex.
Contents
1
The periodic table
1
2
Structure and bonding
25
3
Energetics
62
4 Acids and bases: oxidation and reduction
84
5
111
Hydrogen
6 Groups I and II
119
7 The elements of Group III
138
8
Group IV
160
9
Group V
206
10 Group VI
257
11
310
Group VII: the halogens
12 The noble gases
353
13 The transition elements
359
14 The elements of Groups IB and IIB
425
15
The lanthanides and actinides
440
Index
447
Preface
The welcome changes in GCE Advanced level syllabuses during the
last few years have prompted the writing of this new Inorganic
Chemistry which is intended to replace the book by Wood and
Holliday. This new book, like its predecessor, should also be of value
in first-year tertiary level chemistry courses. The new syllabuses have
made it possible to go much further in systematising and explaining
the facts of inorganic chemistry, and in this book the first four chapters-the periodic table; structure and bonding; energetics: and
acids and bases with oxidation and reductionprovide the necessary
grounding for the later chapters on the main groups, the first transition series and the lanthanides and actinides. Although a similar
overall treatment has been adopted in all these later chapters, each
particular group or series has been treated distinctively, where
appropriate, to emphasise special characteristics or trends.
A major difficulty in an inorganic text is to strike a balance between
a short readable book and a longer, more detailed text which can be
used for reference purposes. In reaching what we hope is a reasonable
compromise between these two extremes, we acknowledge that both
the historical background and industrial processes have been treated
very concisely. We must also say that we have not hesitated to simplify complicated reactions or other phenomenathus, for example,
the treatment of amphoterism as a pH-dependent sequence between
a simple aquo-cation and a simple hydroxo-anion neglects the presence of more complicated species but enables the phenomena to be
adequately understood at this level.
We are grateful to the following examination boards for permission
to reproduce questions (or parts of questions) set in recent years in
Advanced level (A), Special or Scholarship (S), and Nuffield (N)
papers: Joint Matriculation Board (JMB). Oxford Local Examinations (O). University of London (L) and Cambridge Local Examina-
PREFACE
tion Syndicate (C). We also thank the University of Liverpool for
permission to use questions from various first-year examination
papers. Where appropriate, data in the questions have been converted
to SI units, and minor changes of nomenclature have been carried
out; we are indebted to the various Examination Boards and to the
University of Liverpool for permission for such changes.
C.C
A.K.H.
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