PS.Ch6.Test.95



South Pasadena • AP Chemistry Name_____________________________________

Period _____ Date ___/___/___

12 ( The Gas Laws

PRESSURE UNITS

1 atm = 760 mmHg = 760 torr = 101.3 kPa = 14.7 psi

Background:

Pressure is defined as Force / Area such as pounds per square inch (psi).

The weight of air pushing down per square inch is 14.7 pounds per square inch or 14.7 psi.

A barometer can be used to measure pressure. A column of mercury (Hg) that is 0.760 meter (760 mm) tall has the same weight as a column of air from sea level to the edge of the stratosphere. The height of this column is a good measure of air pressure… 760 mmHg.

Evangelista Torricelli did a lot of experiments with pressure and so 1 mmHg is also called 1 torr. So, air pressure has a value of 760 torr. This amount of pressure is also called 1 atm (one atmosphere) because it IS the atmosphere.

In metric units, pressure if Newtons (force) per square meter (area). One Newton is not very much pressure… about the weight of a small apple (get it… apple… Newton)… and if that force is exerted over a square meter, the amount of pressure is very small and called a pascal (Pa). It is more useful to talk of kilopascals (kPa) which would be the weight of 1000 small apples exerted over a square meter. Air pressure is equal to 101.3 kPa.

Since each of these values (see the top of the page) represent the same amount of pressure, any two of them can be used as a conversion factor. You can convert one pressure unit into another.

Example:

| What is 515 mmHg in kPa? 515 mmHg x [pic] = 68.6440789 kPa = 68.4 kPa |

Problems:

1. 745 mmHg into psi

2. 727 mmHg into kPa

3. 52.5 kPa into atm

4. 0.729 atm into mmHg

5. 522 torr into kPa

6. 1.10 atm into psi

7. 800. mmHg into atm

8. 125 kPa into torr

BOYLE’S LAW

Boyle’s Law states that the volume of a gas varies inversely with its pressure if temperature is held constant.

(If one goes up, the other goes down.) We use the formula:

| |

|P1 ( V1 = P2 ( V2 |

Solve the following problems (assuming constant temperature). Assume all number are 3 significant figures.

1. A 175 mL sample of neon had its pressure changed from 75.0 kPa to 150 kPa. What is its new volume?

2. A sample of hydrogen at 1.50 atm had its pressure decreased to 0.50 atm producing a new volume of 750 mL. What was the sample’s original volume?

3. Chlorine gas occupies a volume of 1.20 liters at 720 torr pressure. What volume will it occupy at 1 atm pressure?

4. Fluorine gas exerts a pressure of 900 torr. When the pressure is changed to 1.50 atm, its volume is 250 mL. What was the original volume?

CHARLES’S LAW

Charles’ Law states the volume of a gas varies directly with the Kelvin temperature, assuming the pressure is constant. We use the following formulas:

|[pic] or V1 ( T2 = V2 ( T1 |

|K = (C + 273 |

Solve the following problems assuming a constant pressure. Assume all numbers are 3 significant figures.

1. A sample of nitrogen occupies a volume of 250 mL at 25 (C. What volume will it occupy at 95 (C?

2. Oxygen gas is at a temperature of 40 (C when it occupies a volume of 2.30 Liters. To what temperature should it be raised to occupy a volume of 6.50 Liters?

3. Hydrogen gas was cooled from 150 (C to 50 (C. Its new volume is 75.0 mL. What was its original volume?

4. Chlorine gas occupies a volume of 25.0 mL at 300 K. What volume will it occupy at 600 K?

5. A sample of neon gas at 50 (C and a volume of 2.50 Liters is cooled to 25 (C. What is the new volume?

THE COMBINED GAS LAW

In practical terms, it is often difficult to hold any of the variables constant. When there is a change in pressure, volume and temperature, the combined gas law is used.

|[pic] or P1 ( V1 ( T2 = P2 ( V2 ( T1 |

|K = (C + 273 |

Complete the following chart.

| |P1 |V1 |T1 |P2 |V2 |T2 |

|1 | | | | | | |

| |1.50 atm |3.00 L |20.0 (C |2.50 atm | |30.0 (C |

|2 | | |25.0 (C | |250. mL |50.0 (C |

| |720. torr |256. mL | | | | |

|3 |600. mmHg |2.50 L |22.0 (C |760. mmHg |1.80 L | |

|4 | |750. mL |0.00 (C |2.00 atm |500. mL |25.0 (C |

|5 |95.0 kPa |4.00 L | |101. kPa |6.00 L |471. K or 198. (C |

|6 |650. torr | |100. (C |900. torr |225. mL |150. (C |

|7 |850. mmHg |1.50 L |15.0 (C | |2.50 L |30.0 (C |

|8 |125. kPa |125. mL | |100. kPa |100 mL |75.0 (C |

THE IDEAL GAS LAW

|PV = nRT where |

|P = pressure in atmosphere |

|V = volume in liters |

|n = number of moles of gas |

|R = Universal Gas Constant = 0.0821 L(atm/mol(K |

|T = Kelvin temperature |

1. How many moles of oxygen will occupy a volume of 2.50 liters at 1.20 atm and 25 (C?

___________________

2. What volume will 2.00 moles of nitrogen occupy at 720. torr and 20.(C?

__________________

3. What pressure will be exerted by 25.0 g of CO2 at temperature of 25 (C and a volume of 500. mL? _________________

4. At what temperature will 5.00 g of Cl2 exert a pressure of 900. torr at a volume of 750. mL? __________________

5. What is the density of NH3 at 800. torr and 25 (C? ___________________

6. If the density of a gas is 1.2 g/L at 745 torr and 20.(C, what is its molar mass?

__________________

7. How many moles of nitrogen gas will occupy a volume of 347 mL at 6680 torr and 27 (C? ____________________

8. What volume will 454 grams (1 lb) of hydrogen occupy at 1.05 atm and 25 (C?

___________________

9. Find the number of grams of CO2 that exert a pressure of 785 torr at a volume of 32.5 L and a temperature of 32 (C. _______________________

10. An elemental gas has a mass of 10.3 g. If the volume is 58.4 L and the pressure is 758 torr at a temperature of 2.5 (C, what is the gas? _____________________

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