Geometry of Crystals
Geometry of Crystals
Crystal is a solid composed of atoms, ions or molecules that demonstrate long range periodic order in three dimensions
The Crystalline State
State of Matter
Fixed Fixed Volume Shape
Order
Properties
Gas
No
No
No
Isotropic
Liquid
Yes
Solid (amorphous)
Yes
Solid (crystalline)
Yes
No
Short-range Isotropic
Yes
Short-range Isotropic
Yes
Long-range Anisotropic
Crystal Lattice
Not only atom, ion or molecule positions are repetitious ? there are certain symmetry relationships in their arrangement.
b a
Lattice constants a, b
Atoms
A B C
Crystalline structure
=
Basis +
Lattice
Crystal Lattice
a a
One-dimensional lattice with lattice parameter a
a a b
r ua
r ua b
b
Two-dimensional lattice with lattice parameters a, b and
Crystal Lattice
r ua b wc
................
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