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I.COURSE TITLE: Organic Chemistry ICOURSE NUMBER: 2201CATALOG PREFIX: CHEMII.PREREQUISITE(S): CHEM 1161 & 1162 COREQUISITE: CHEM 2211III.CREDIT HOURS:4LECTURE HOURS: 4LABORATORY HOURS:0OBSERVATION HOURS: 0IV.COURSE DESCRIPTION:This course is designed to give the student extensive background in bonding, nomenclature, and reactions of alkanes, cycloalkanes, alkenes, alkynes, alcohols, alkyl halides, conjugated alkadienes, allylic systems and arenes. Addition, elimination, nucleophilic substitution, and electrophilic aromatic substitution reactions are covered including their mechanisms. Spectroscopy of organic compounds is introduced.V.ADOPTED TEXT(S):Organic Chemistry10th EditionCarey and Giuliano, 2016McGraw-HillISBN: 978-0-07-351121-4VI.COURSE OBJECTIVES:At the end of the course, the student should be able to:Understand the covalent bond in hydrocarbons and related organic compounds and how it differs in ionic bonds.Draw Lewis structures for organic compounds.Determine IUPAC names for alkanes, alkenes, alkynes, alcohols, alkyl halides and arene compounds, and give traditional names for the most common of these types of compounds.Describe the difference between substitution and elimination reactions and between unimolecular and bimolecular mechanisms of these reaction.Distinguish between conformations, constitutional isomers and stereoisomers.Determine IUPAC names for stereoisomers of alkenes, cycloalkanes and organic compounds with chiral centers.Understand the importance of conjugation and aromaticity in organic compounds.Predict the product of electrophilic substitution of aromatic rings and understand its mechanism.Determine the identity of simple compounds from their infrared, mass spectroscopy, UV/visible, and 1H and 13C NMR spectra, and understand the basis and applicability of each technique.VII.COURSE METHODOLOGY:Lecture room with computer with PowerPoint and projector, internet connection for the computer and projector to access review and discussion materials on the McGraw-Hill web site that accompanies the text. Molecular models foe hands-on demonstration of the structure of organic chemicals. Student-accessible computer equipment adequate to run the molecular modeling CD-ROM that accompanies the text.VIII.GRADINGA90–100B80–89C70–79D60–69F0–59IX.COURSE OUTLINE:Bonding, structure and properties of organic and inorganic compounds.Structure of the atom including electron configuration and wave functions.Types of bonds including ionic, covalent and polar covalent and determination of dipole moment.Drawing Lewis structures including the determination of formal charges.Structural isomers and stereoisomers including resonance.Writing organic structures including line and wedge designs.Acid and bases theory including Arrhenius, Bronsted and Lewis and determination of acid strength.Introduction to hydrocarbons: alkanes and cycloalkanes.Types of hydrocarbons including aliphatic and aromatic.Valence bond model and molecular orbital model of bonding hydrocarbonsHybridization of orbitals.Naming alkanes including IUPAC rules.Physical properties of alkanes and combustion reactions.Conformations and stereoisomers of alkanes and cycloalkanes.Conformational analysis of alkanes using butane as an exampleStereoisomers of cycloalkanes and axial and equatorial bond positions using cyclohexane as an example.Alcohols and alkyl halides.Naming and characterization including substitutive and functional class nomenclature.Physical properties including water solubility.Introduction to organic reaction mechanisms including elementary steps, intermediates, transitions states and molecularity.Introduction to electrophiles and nucleophiles.Potential energy diagrams for SN1 and SN2 reaction mechanisms.Structure and stability of carbocations.Alkene structure, preparations and reactions.Nomenclature, structure and bonding including Cahn-Ingold-Prelog naming system.Physical properties and stability.Introduction to E1 and E2 mechanisms including regioselectivity and Zaitsev’s rule.Additions reactions including both syn and anti addition and an introduction to Markovnikov’s rule.Discussion of vicinal and geminal products and epoxidation.Stereochemistry.Introduction to chiral compounds, achiral compounds, enantiomers, diastereomers and optical isomers.Definitions for planes of symmetry, centers of symmetry, specific rotation, absolute configuration and relative configuration.Introduction to Fisher Projections, how to make them and how to read them.Reactions that create chirality centers.Explanation of chiral and achiral compounds having two chiral centers.Nucleophilic substitution.Reactions of alkyls halides with common nucleophiles.Order of reactivity for the substitution reaction.Reaction conditions that favor substitution and those that favor elimination.Alkyne chemistry.Nomenclature, hybridization, bond angles and introduction to carbanions.Preparation of alkynes.Reactions of alkynes.Alkadienes and allylic systemsDefinition of conjugation, allylic carbons and allylic carbocations.SN1, SN2 and free radical reactions of alkyl halides.Preparation, reactions and naming of dienes.Introduction to Diels-Alder reactions.Arenes.Nomenclature and structure including the Huckel Rule.Reactions including electrophilic aromatic substitution, Birch reduction and attack at the benzylic carbon.Induction and resonance effects for electrophilic aromatic substitution is explained.Spectroscopy.Introduction and physics.NMR, IR, UV-VIS and mass spectroscopy are explained.X.OTHER REQUIRED TEXTS, SOFTWARE, AND MATERIALS:The molecular modeling CD-ROM bundled with the text is required and will be used with College supplied computer resources. Other books and materials will be supplied in the class.XI.EVALUATION:Student evaluation is by quizzes and examinations. Additional homework or a paper may be required or may be permitted for remedial work or extra credit.XII.SPECIFIC MANAGEMENT REQUIREMENTS:At the discrestion of the instructorXIII.OTHER INFORMATION:FERPA: Students need to understand that your work may be seen by others. Others may see your work when being distributed, during group project work, or if it is chosen for demonstration purposes. Students also need to know that there is a strong possibility that your work may be submitted to other entities for the purpose of plagiarism checks. DISABILITIES: Students with disabilities may contact the Disabilities Service Office, Central Campus, at 800-628-7722 or 937-393-3431. ................
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