Concrete - Princeton University
[Pages:42]Concrete
? What is it ?
? Ancient history
? Recent history
? Portland cement ? Reinforced concrete ? Pre-stressed concrete
? Properties of concrete
? Heat of hydration ? Creep ? Strength ? Durability
? New structures
? Bridges ? Shells ? Dams
What is Cement?
? Cement is a material capable of binding particles together
? Portland cement is a mixture of calcium silicates and aluminum silicates that react with water to form a binder
? Portland cement is a generic name , not a trade name , and has nothing to do with Portland
? Modern Portland cement was invented in the 19th century , but related materials have been used in construction since Roman times
? Mortar is a mixture of cement and sand
? Concrete is a mixture of mortar and aggregate ( i.e., stones larger than ~5 mm and usually smaller than 7 cm )
Ancient History
? Lime ( CaO ) is made by heating limestone ( calcium carbonate ) above ~900?C to drive off the carbon dioxide
CaCO3 CaO + CO2
? Lime reacts with water to form calcium hydroxide ( slaked lime )
CaO + H2O Ca(OH)2
? Lime plaster is made by compacting slaked lime on a surface ( such as a wall or floor ) and allowing it to react with CO2 in the atmosphere to form CaCO3
? This material was in use 8000 yrs ago
? The ancient Egyptians used gypsum plaster ( aka plaster of Paris )
? The ancient Greeks reacted slaked lime with volcanic ash ( mostly SiO2 glass ) to make a cement to line cisterns
? This material is the precursor of modern cement
Ancient History
? From about 200 BC , the Romans developed cement technology based on slaked lime and volcanic ash from Mt. Vesuvius
? The preferred deposits were near Pozzuoli , so the cement is called pozzolanic cement
? The ash is nearly pure silica glass , which is much more reactive than crystalline silica ( i.e., quartz sand )
? The reaction produces calcium silicate hydrate gel called C-S-H with the approximate composition
C - S - H 3 CaO ? 2 SiO2 ? 3H2O
? By the first century AD , concrete was used for major construction projects , such as the Pantheon
Roman Concrete
? As in modern construction , the Romans used wooden forms and cast the concrete into them
? In tall structures , dense stone was used as aggregate at the bottom and light stone was used higher up
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