Encyclopedia of Chemistry - Internet Archive
[Pages:353]ENCYCLOPEDIA OF
chemistry
don rittner
and
ronald A. Bailey, Ph.D.
To Nancy, Christopher, Kevin, Jackson, Jennifer, and Jason
Encyclopedia of Chemistry
Copyright ? 2005 by Don Rittner
All rights reserved. No part of this book may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying, recording, or by any information stor-
age or retrieval systems, without permission in writing from the publisher. For information contact:
Facts On File, Inc. 132 West 31st Street New York NY 10001
Library of Congress Cataloging-in-Publication Data
Rittner, Don.
Encyclopedia of chemistry / Don Rittner and Ronald A. Bailey.
p. cm.
Includes bibliographical references and index.
ISBN 0-8160-4894-0
1. Chemistry--Encyclopedias. I. Bailey, R. A. (Ronald Albert), 1933 ?
II. Title.
QD4.R57 2005
540.3--dc22
2004011242
Facts On File books are available at special discounts when purchased in bulk quantities for businesses, associations, institutions, or sales promotions. Please call our Special Sales Department in
New York at (212) 967-8800 or (800) 322-8755.
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Text design by Joan M. Toro Cover design by Cathy Rincon Illustrations by Richard Garratt
Printed in the United States of America
VB Hermitage 10 9 8 7 6 5 4 3 2 1
This book is printed on acid-free paper.
CONTENTS
Acknowledgments v
Preface vii
Introduction ix
A-to-Z Entries 1
Feature Essays:
"The Power of Chemistry: Natural versus Synthetic Compounds" by Theresa Beaty, Ph.D.
57
"What a Crime Lab Does, It Does with Chemistry" by Harry K. Garber
81
"Molecular Modeling" by Karl F. Moschner, Ph.D.
183
"The Role of Chemistry" by Karl F. Moschner, Ph.D.
248
Appendixes: Appendix I Bibliography
289
Appendix II Chemistry-Related Web Sites
311
Appendix III Chemistry Software Sources
313
Appendix IV Nobel Laureates Relating to Chemistry
315
Appendix V Periodic Table of Elements
321
Appendix VI Chemical Reaction Types
323
Appendix VII Metals and Alloys
325
Index 326
ACKNOWLEDGMENTS
I would like to thank the following for their generosity in helping to make this book as complete as possible, especially in the use of images, biographies, definitions, essays, and encouragement: Kristina Fallenias, Nobel Foundation; Fabienne Meyers, International Union of Pure and Applied Chemistry; Daryl Leja, NHGRI, and National Institutes of Health; essayists Harry K. Garber, Karl F. Moschner, and Theresa Beaty; the many chemistry Webmasters; and Nancy, Chris, Kevin, Jack, Jennifer, and Jason.
I also wish to thank Frank K. Darmstadt, executive editor, Sara Hov and Melissa Cullen-DuPont, editorial assistants, and the rest of the staff at Facts On File, Inc., and my colleague Ron Bailey. I apologize to anyone left out due to error.
v
PREFACE
Students beginning their study of chemistry are faced with understanding many terms that are puzzling and unrelated to contexts that make them understandable. Others may seem familiar, but in chemistry they have meanings that are not quite the same as when used in popular discourse. In science, terms need to have definite and specific meanings. One of the purposes of the Encyclopedia of Chemistry is to provide definitions for many of these terms in a manner and at a level that will make their meanings clear to those with limited backgrounds in chemistry, and to those in other fields who need to deal with chemistry. The International Union of Pure and Applied Chemistry (IUPAC), an international organization of chemists and national chemistry societies, makes the final determination of terminology and nomenclature in chemistry. Among other things, this organization decides the names for new elements and sets up systematic rules for naming compounds so that a given structure can be defined uniquely. Compounds are frequently called by common or trade names, often because their IUPAC names may be long and complex, but the IUPAC name permits a chemist to know the structure of any compound based on the rules of the terminology, while the common name requires remembering what structure goes with what name.
Chemistry has been called "the central science" because it relates to and bridges all of the physical and biological sciences. For example, biology, as it focuses more and more on processes at the cellular and molecular level, depends heavily on chemistry. There is great overlap within the fields in biochemistry, the study of the chemical processes that take place in biological systems, and in chemical biology, the latter term being used to describe the broader area of the application of chemical techniques and principles to biology-related problems. Because of this overlap, this encyclopedia has many entries that relate to biological sciences as well as to chemistry. Similarly, there is overlap with geology, some areas of physics, and any field related to the environment, among others.
While we can define chemistry, it is more difficult to describe what a chemist actually does. The comic book image of a chemist as someone in a white coat surrounded by test tubes and beakers, if it ever had any basis in reality, is far from accurate now. Nowadays, while the white coat may still be in style, a chemist is more likely to be surrounded by complicated instruments such as spectrometers and chromatographs. The type of work
vii
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