Appendix D: Reference Standards and Data for Water

Appendix D: Reference Standards and Data for Water

Annual Site Environmental Report

Table D.1. Reference standards for radionuclides in water (pCi/L)

Parametera

National primary drinking water standardb

4% of DCGc

DCGd

241Am 214Bi 109Cd 143Ce 60Co 51Cr 137Cs 155Eu Gross alphae

Gross beta (mrem/yr) 3H 131I 40K 237Np 234mPa 238Pu 239/240Pu 226Ra 228Ra 106Ru 90Sr 99Tc 228Th 230Th 232Th 234Th

Thorium, natural 234U 235U 236U 238U

Uranium, natural Uranium, totalh

15 4

20,000f

5g 5g 8f

1.2 24,000

400 1,200

200 40,000

120 4,000

30 600,000 10,000 30,000

5,000 1,000,000

3,000 100,000

80,000 120 280 1.2

2,800 1.6 1.2 4 4

240 40 4,000 16 12

2 400

2 20 24 20 24 24 20

2,000,000 3,000 7,000 30

70,000 40 30 100 100

6,000 1,000 100,000

400 300 50 10,000

50 500 600 500 600 600 500

aOnly the radionuclides sought on the Oak Ridge Reservation are listed. b40 CFR Part 141 National Primary Drinking Water Regulations Subparts B and G. cFour percent of the DCG represents the DOE criterion of 4 mrem effective dose

equivalent from ingestion of drinking water. dU.S. DOE Order 5400.5 Chapter III Derived Concentration Guides for Air and Water. eExcludes radon and uranium. fThese values are not MCLs, but are concentrations that result in the effective dose

equivalent (EDE) of the MCL for gross beta emissions, which is 4 mrem/year. gApplies to combined 226Ra and 228Ra. hMinimum of uranium isotopes.

Appendix D: Reference Standards and Data for Water D-3

Oak Ridge Reservation

Table D.2. Reference standards for chemicals and metals in water

National drinking water standards

Tennessee water quality criteriac

Parameter

Primarya

Secondaryb

Domestic water supply

Fish and aquatic life CMC

Recreation

Organisms

Water and organismsd

Anions (mg/L)

Chloride Fluoride Nitrate Nitrite Sulfate, as SO4

250

4

2

10

1

250

Base/neutral/acid extractable organics (?g/L)

1,2-Dichlorobenzene (ortho)

600

1,2,4-Trichlorobenzene

70

1,3-Dichlorobenzene (meta)

1,4-Dichlorobenzene (para)

75

2,4-Dinitrophenol

2,4-Dinitrotoluene

2,4,6-Trichlorophenol

2-Methyl-4,6-Dinitrophenol

3,4-Benzo(b)fluoranthene

Benzo(k)fluoranthene

Acenaphthylene

Anthracene

Benzo(a)anthracene

Benzo(a)pyrene

0.2

bis-(2-chloroethyl)ether

bis-(2-ethylhexyl)phthalate

6

6

Di-n-butyl phthalate

Diethyl phthalate

Dimethyl phthalate

Fluoranthene

Fluorene

Hexachlorobenzene

1

Hexachlorocyclopentadiene

50

Hexachloroethane

Nitrobenzene

Pentachlorophenol (pH 7.8)

1

Pyrene

600 70

75

0.2

1 50

1

20

17,000

2,700

2,600 2,600 14,000

91 65 765

0.49 0.49 2,700 110,000 0.49 0.49 14 59 12,000 120,000 2,900,000 370 14,000 0.0077 17,000 89 1,900 82 11,000

400 400

70 1.1

21 13.4

0.044 0.044 1,200 9,600 0.044 0.044 0.31 18 2,700 23,000 313,000 300 1,300 0.0075 240 19 17 2.8 960

Field measurements

Chlorine, mg/L Dissolved oxygen, mg/L Temperature, C Turbidity, JTUe pH, standard units

19

5

30.5

30.5

30.5

1

(6.5, 8.5)

(6.0, 9.0) (6.5, 8.5)

(6.0, 9.0)

(6.0,9.0)

D-4 Appendix D: Reference Standards and Data for Water

Parameter

Aluminum Antimony Arsenic Barium Beryllium Cadmium Chromium, total Chromium (hexavalent) Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc

Asbestos (fibers/L) Coliform bacteriah Color (color units) Cyanide (mg/L) Odor (T.O.N.) Total dissolved solids

(mg/L)

2,3,7,8-TCDD (Dioxin) 2,4-D 2,4,5-TP (Silvex) 4,4'-DDT 4,4'-DDE 4,4'-DDD Alachlor Aldrin Atrazine Carbofuran Chlordane Dalapon

Annual Site Environmental Report

Table D.2 (continued)

National drinking water standards

Tennessee water quality criteriac

Primarya

Secondaryb

Domestic water supply

Fish and aquatic

life

Recreation

Organisms

Water and organismsd

Metals (mg/L)

0.006 0.05 2 0.004 0.005 0.1

0.05-0.2

1.3g

1

0.3

0.015g

0.05

0.002

0.05 0.1

0.002 5

0.006 0.05 2 0.004 0.005 0.1

360 (III)

0.0039f 0.016 0.0177f

0.005

0.0817f

0.002 0.1 0.050

0.002

0.0024 1.418f 0.02 0.0041f

0.117f

4.30 0.0014

0.014 0.00018

0.00015 4.6

0.00014 0.61

0.0063

0.0017

Others

7,000,000

15

0.2

0.2

0.022

220

0.7

3

500

500

Pesticides/herbicides/PCBs (?g/L)

0.00003 70 50

0.00003 70 50

1.1

2

2

3

3

3

40

40

2

2

2.4

200

200

0.000001

0.000001

0.0059 0.0059 0.0084

0.0014

0.0059 0.0059 0.0083

0.0013

0.0059

0.0057

Appendix D: Reference Standards and Data for Water D-5

Oak Ridge Reservation

Parameter

1,2-Dibromo-3-chloropropane Di(ethylhexyl)adipate Di(ethylhexyl)phthalatei Dinoseb Diquat a-Endosulfan b-Endosulfan Endothall Endrin Ethylene dibromide Glyphosate Heptachlor Heptachlor epoxide g-BHC (Lindane) Methoxychlor Oxamyl (Vydate) PCB-1242 PCB-1254 PCB-1221 PCB-1232 PCB-1248 PCB-1260 PCB-1016 PCB, total Picloram Simazine Toxaphene

1,1,1-Trichloroethane 1,1-Dichloroethene 1,1,2-Trichloroethane 1,1,2,2-Tetrachloroethane 1,2-Dichloroethane 1,2-Dichloroethenej cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene

Table D.2 (continued)

National drinking water standards

Tennessee water quality criteriac

Primarya Secondaryb

0.2 400

Domestic water supply

0.2 400

Fish and aquatic

life

Recreation

Organisms

Water and organismsd

7 20

100 2 0.05

700 0.4 0.2 0.2

40 200

7

20

0.22

0.22

100

2

0.18

0.05

700

0.4

0.52

0.2

0.52

0.2

2

40

200

0.5 500

4 3

200 7 5

5

0.5

500

4

3

0.73

Volatile organics (?g/L)

200 7 5

5

159 159

0.81

74 74

0.76

0.0021 0.0011 0.63

0.0021 0.001 0.19

0.00045 0.00045 0.00045 0.00045 0.00045 0.00045 0.00045 0.00045

0.00044 0.00044 0.00044 0.00044 0.00044 0.00044 0.00044 0.00044

0.0075

0.0073

32

0.57

420

6

110

1.7

990

3.8

70

70

100

100

700

5

5

39

0.52

1,700

10

1,700

10

D-6 Appendix D: Reference Standards and Data for Water

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