Courtesy copy of Table 1B from 40 CFR

[Pages:23]Courtesy copy of Table 1B from 40 CFR, Part 136

(downloaded and created as PDF on 18-Aug-2011)

Table IB--List of Approved Inorganic Test Procedures

Parameter 1. Acidity, as CaCO3, mg/L 2. Alkalinity, as CaCO3, mg/L 3. Aluminum-- Total,4mg/L

4. Ammonia (as N), mg/L

Methodology58

EPA35,52

Electrometric endpoint or phenolphthalein endpoint

Electrometric or Colorimetric titration to pH 4.5, manual, or

automatic

Digestion4followed by:

310.2 (Rev. 1974)1

AA direct aspiration36

AA furnace

STGFAA

200.9, Rev. 2.2 (1994)

ICP/AES36

200.7, Rev. 4.4 (1994)

ICP/MS

200.8, Rev. 5.4 (1994)

Direct Current Plasma (DCP)36

Colorimetric (Eriochrome cyanine R)

Manual, distillation (at pH 9.5)6followed

by:

350.1, Rev. 2.0 (1993)

Nesslerization

Titration

Reference (method number or page)

Standar d

methods (18th, 19th)

Standar d

methods (20th)

Standar d

methods online

ASTM

USGS/AOAC/othe r

2310 B(4a)

2310 B(4a)

2310 D1067? B(4a)?97 92, 02

I?1020?852

2320 B

2320 B

2320 B? D1067?

97

92, 02

973.433, I?1030?852

I?2030?852

3111 D 3113 B

3111 D? 99

3113 B? 99

I?3051?852

3120 B

3120 B

3120 B? 99

D5673? 03

D4190? 94, 99

I?4471?9750 993.143 See footnote34

3500?Al 3500?Al 3500?Al

D

B

B?01

4500?NH 4500?

B3

NH3 B

4500? NH3 C (18th only)

4500? NH3 C

4500? NH3 C

4500? NH3 B? 97

973.493

D1426? 98, 03 973.493, I?3520?852

(A)

4500? NH3 C?

5. Antimony-- Total,4mg/L

6. Arsenic-- Total,4mg/L

(19th) and 4500? NH3 E (18th)

Electrode

4500?

NH3 D

or E (19th) and 4500?

4500? NH3 D or E

NH3 F or

G (18th)

Automated phenate, or

4500?

NH3 G

350.160, Rev. 2.0 (1993)

(19th) and 4500?

NH3 H

(18th)

4500? NH3 G

Automated electrode

Ion Chromatography

Digestion4followed by:

AA direct aspiration36

3111 B

AA furnace

3113 B

STGFAA

ICP/AES36

ICP/MS Digestion4followed by

200.9, Rev. 2.2 (1994)

200.7, Rev. 4.4 (1994)

3120 B

200.8, Rev. 5.4 (1994)

206.5 (Issued 1978)1

3120 B

AA gaseous hydride

3114 B 4.d

AA furnace STGFAA ICP/AES36

3113 B

200.9, Rev. 2.2 (1994)

200.7, Rev. 4.4 (1994)

3120 B

3120 B

97

4500? D1426? NH3 D 98, 03 or E?97 (B)

4500? NH3 G? 97

I?4523?852

See footnote 7

D6919? 03

3111 B? 99

3113 B? 99

3120 B? 99

D5673? 03

993.143

3114 B 4.d?97

D2972? 97, 03 (B)

3113 B? 99

D2972? 97, 03 (C)

I?3062?852 I?4063?9849

3120 B? 99

7. Barium-- Total,4mg/L

8. Beryllium-- Total,4mg/L

9. Biochemical oxygen demand (BOD5), mg/L 10. Boron-- Total,37mg/L

11. Bromide, mg/L

ICP/MS

200.8, Rev. 5.4 (1994)

Colorimetric (SDDC)

Digestion4followed by:

AA direct aspiration36

AA furnace

ICP/AES36

ICP/MS DCP36 Digestion4followed by:

200.7, Rev. 4.4 (1994)

200.8, Rev. 5.4 (1994)

AA direct aspiration

AA furnace

STGFAA

ICP/AES

ICP/MS

DCP, or Colorimetric (aluminon) Dissolved Oxygen Depletion Colorimetric (curcumin) ICP/AES, or

DCP

200.9, Rev. 2.2 (1994) 200.7, Rev. 4.4 (1994) 200.8, Rev. 5.4 (1994)

200.7, Rev. 4.4 (1994)

Titrimetric

D5673? 03

3500?As C

3500?As B

3500?As B?97

D2972? 97, 03 (A)

3111 D 3113 B 3120 B

3120 B

3111 D? 99

3113 B? D4382?

99

95, 02

3120 B? 99

D5673? 03

3111 D 3113 B

3111 D? 99

D3645? 93 (88), 03 (A)

3113 B? 99

D3645? 93 (88), 03 (B)

3120 B 3120 B

3500?Be D

3120 B? 99

D5673? 03

D4190? 94, 99

5210 B

5210 B

5210 B? 01

4500?B 4500?B 4500?B

B

B

B?00

3120 B 3120 B 3120 B99

D4190? 94, 99

D1246? 95, 99 (C)

993.143 I?3060?85

I?3084?852

993.143 See footnote34

I?3095?852

I?4471?9750 993.143 See footnote34

973.44,3p. 17.9, I? 1578?788 I?3112?852 I?4471?9750 See footnote 34 p. S44.10

12. Cadmium-- Total,4mg/L

13. Calcium-- Total,4mg/L

14. Carbonaceous biochemical oxygen demand (CBOD5), mg/L12 15. Chemical

300.0, Rev 2.1 (1993) Ion Chromatography and 300.1, Rev 1.0 (1997)

CIE/UV Digestion4followed by:

AA direct aspiration36

AA furnace

STGFAA ICP/AES36 ICP/MS DCP36

200.9, Rev. 2.2 (1994)

200.7, Rev. 4.4 (1994)

200.8, Rev. 5.4 (1994)

Voltametry11, or

Colorimetric (Dithizone) Digestion4followed by:

AA direct aspiration

ICP/AES DCP, or

200.7, Rev. 4.4 (1994)

Titrimetric (EDTA)

Ion Chromatography

Dissolved Oxygen Depletion with nitrification inhibitor

Titrimetric

410.3 (Rev.

I?1125?852

4110 B

4110 B

4110 B? D4327?

00

97, 03

993.303

D6508, Rev. 254

3111 B or C

3113 B

3111 B or C?99

D3557? 974.27,3p. 37.9, I? 95, 02 (A 3135?852or I?3136? or B) 852

3113 B? 99

D3557? 95, 02 (D)

I?4138?8951

3120 B 3120 B

3500?Cd D

3120 B? 99

D5673? 03

D4190? 94, 99

D3557? 95, 02 (C)

I?1472?852or I? 4471?9750 993.143

See footnote34

3111 B

3111 B? 99

D511? 93, 03(B)

I?3152?852

3120 B

3120 B

3120 B? 99

I?4471?9750 See footnote34

3500?Ca 3500?Ca 3500?Ca D511?

D

B

B?97 93, 03(A)

D6919? 03

5210 B

5210 B

5210 B? 01

5220 C 5220 C 5220 C? D1252? 973.463, p. 179I?

oxygen demand (COD), mg/L 16. Chloride, mg/L

17. Chlorine-- Total residual, mg/L; Titrimetric

18. Chromium VI dissolved, mg/L

1978)1

Spectrophotometric, 410.4, Rev. manual or automatic 2.0 (1993)

Titrimetric: (silver nitrate) or

(Mercuric nitrate)

Colorimetric: manual or Automated (Ferricyanide) Potentiometric Titration

Ion Selective Electrode

300.0, Rev 2.1 (1993) Ion Chromatography and 300.1, Rev 1.0 (1997) CIE/UV

Amperometric direct, or

Amperometric direct (low level)

Iodometric direct

Back titration ether end-point15or

DPD?FAS

Spectrophotometric, DPD or Electrode 0.45?micron Filtration followed by: AA chelationextraction or Ion Chromatography 218.6, Rev.

97

95, 00 3560?852

(A)

5220 D

5220 D

5220 D? 97

D1252? 95, 00 (B)

See footnotes13,14. I? 3561?852

4500?Cl? B

4500?Cl? B

4500?Cl? B?97

D512? 89(99) (B)

I?1183?852

4500?Cl? 4500?Cl? 4500?Cl? D512?89

C

C

C?97 (99) (A)

973.513, I?1184?852

I?1187?852

4500?Cl? 4500?Cl? 4500?Cl?

E

E

E?97

I?2187?852

4500?Cl? 4500?Cl? 4500?Cl?

D

D

D?97

D512? 89(99)(C )

4110 B

4110 B

4110 B? D4327?

00

97, 03

993.303

D6508, Rev. 254

4500?Cl D

4500?Cl D

4500?Cl D?00

D1253? 86 (96), 03

4500?Cl 4500?Cl 4500?Cl

E

E

E?00

4500?Cl 4500?Cl 4500?Cl

B

B

B?00

4500?Cl 4500?Cl 4500?Cl

C

C

C?00

4500?Cl 4500?Cl 4500?Cl

F

F

F?00

4500?Cl 4500?Cl 4500?Cl

G

G

G?00

See footnote16

3111 C

3111 C? 99

I?1232?85

3500?Cr 3500?Cr 3500?Cr D5257? 993.23

3.3 (1994)

Colorimetric (Diphenyl-carbazide)

19. Chromium-- Digestion4followed

Total,4mg/L

by:

AA direct aspiration36

AA chelationextraction

AA furnace

20. Cobalt-- Total,4mg/L

STGFAA ICP/AES36 ICP/MS DCP,36or

200.9, Rev. 2.2 (1994)

200.7, Rev. 4.4 (1994)

200.8, Rev. 5.4 (1994)

Colorimetric (Diphenyl-carbazide) Digestion4followed by:

AA direct aspiration

AA furnace

STGFAA

ICP/AES

ICP/MS

DCP

21. Color,

platinum cobalt

units or

Colorimetric

dominant

(ADMI), or

wavelength, hue,

luminance purity

200.9, Rev. 2.2 (1994)

200.7, Rev. 4.4 (1994)

200.8, Rev. 5.4 (1994)

E

C

C?01 97

3500?Cr D

3500?Cr B

3500?Cr B?01

D1687? 92, 02 (A)

I?1230?85

3111 B 3111 C 3113 B

3111 B? 99

D1687? 92, 02 (B)

3111 C? 99

3113 B? 99

D1687? 92, 02 (C)

974.273, I?3236?852 I?3233?9346

3120 B

3120 B

3120 B? 99

D5673? 03

D4190? 94, 99

3500?Cr 3500?Cr 3500?Cr

D

B

B?01

993.143 See footnote34

3111 B or C

3113 B

3111 B or C?99

D3558? 94, 03 (A p. 379, I?3239?852

or B)

3113 B? 99

D3558? 94, 03 (C)

I?4243?8951

3120 B

3120 B

3120 B? 99

D5673? 03

D4190? 94, 99

I?4471?9750 993.143 See footnote34

2120 E 2120 E

See footnote18

22. Copper-- Total,4mg/L

23. Cyanide-- Total, mg/L

24. Available Cyanide, mg/L

(Platinum cobalt), or

2120 B

2120 B

2120 B? 01

I?1250?852

Spectrophotometric Digestion4followed by:

AA direct aspiration36

2120 C 2120 C

3111 B or C

3111 B or C?99

D1688? 974.273p. 379I? 95, 02 (A 3270?852or I?3271? or B) 852

AA furnace

3113 B

3113 B? 99

D1688? 95, 02 (C)

I?4274?8951

STGFAA

200.9, Rev. 2.2 (1994)

ICP/AES36

200.7, Rev. 4.4 (1994)

3120 B

3120 B

3120 B? 99

I?4471?9750

ICP/MS

200.8, Rev. 5.4 (1994)

D5673? 03

993.143

DCP36or

D4190? 94, 99

See footnote34

Colorimetric (Neocuproine) or

3500?Cu 3500?Cu 3500?Cu

D

B

B?99

(Bicinchoninate)

3500?Cu 3500?Cu 3500?Cu

E

C

C?99

See footnote19

Automated Distillation and Colorimetry, or

Kelada?0155

Manual distillation with MgCl2 followed by:

335.4, Rev. 4500? 1.0 (1993)57 CN?C

4500? CN?C

D2036? 98(A)

10?204?00?1?X56

Titrimetric or

4500? 4500? 4500? CN?D CN?D CN?D?99

p. 229

Spectrophotometric, manual or

Automated20or

335.4, Rev. 1.0 (1993)57

4500? CN?E

4500? CN?E

4500? D2036? CN?E?99 98(A)

I?3300?85

10?204?00?1?X56, I?4302?852

Ion Selective Electrode

4500? 4500? 4500? D2036? CN?F CN?F CN?F?99 98(A)

Cyanide Amenable to Chlorination (CATC); Manual distillation with MgCl2 followed by Titrimetric or Spectrophotometric

4500? 4500? 4500? D2036? CN?G CN?G CN?G?99 98(B)

Flow injection and ligand exchange,

D6888? 04

OIA?167744

followed by amperometry61

Automated Distillation and Colorimetry

Kelada?0155

25. Fluoride-- Total, mg/L

Manual distillation6followed

by:

4500?F? 4500?F? 4500?F?

B

B

B?97

Electrode, manual or Automated

4500?F? B

4500?F? B

4500?F? C?97

D1179? 93, 99 (B)

I?4327?852

Colorimetric, (SPADNS) or

Automated complexone

4500?F? D

4500?F? E

4500?F? D

4500?F? E

4500?F? D?97

4500?F? E?97

D1179? 93, 99 (A)

26. Gold-- Total,4mg/L

300.0, Rev 2.1 (1993) Ion Chromatography and 300.1, Rev 1.0 (1997)

CIE/UV Digestion4followed by:

4110 B

4110 B

4110 B? D4327?

00

97,03

993.303

D6508, Rev. 254

AA direct aspiration, or

3111 B

3111 B? 99

AA furnace, or DCP

231.2 (Rev. 1978)1

See footnote34

27. Hardness-- Total, as CaCO3, mg/L

Automated colorimetric,

130.1 (Issued 1971)1

Titrimetric (EDTA) or

2340 B or C

2340 B or C

2340 B or C?97

D1126? 86(92), 02

973.5 2B3, I?1338? 852

Ca plus Mg as their

carbonates, by

inductively coupled

plasma or AA direct aspiration. (See

c

Parameters 13 and

33).

28. Hydrogen ion (pH), pH units

Electrometric measurement or

4500? H+B

4500? H+B

4500? H+B?00

D1293? 84 (90), 99 (A or B)

973.41.3, I?1586? 852

 ................
................

In order to avoid copyright disputes, this page is only a partial summary.

Google Online Preview   Download