MATERIAL SAFETY DATA SHEET



MATERIAL SAFETY DATA SHEET

Penn Valley Paint 8000 Bristol Pike Levittown, PA 19057 215-949-0800

24 Hour Emergency Phone Number Chemtel 800-255-3924

SECTION 1: PRODUCT IDENTIFICATION Date Prepared: January 15, 2003

HEALTH 1

FIRE 0

REACTIVITY 0

PPE X

Product: Calbar Metal Siding Paint

Code: 18-400 series This form covers all stock colors and bases

.

Hazard summary (as defined by OSHA Hazard Communication Standard, 29 CFR 1900.1200):

Physical Hazards: None

Health Hazards: Based on nuisance particulate, ammonia, ethylene glycol, inhalation (TLV/PEL).

Based on ammonia, ethylene glycol, acrylic emulsion, irritant (eye, skin, mucous membranes).

Based on ethylene glycol, harmful (CNS depression, kidney damage.)

Read the entire MSDS for a more thorough evaluation of the hazards.

SECTION 2: INGREDIENTS ACGIH OSHA

CAS NUMBER % Wt. TLV (a) PEL

Water 7732-18-5 10.0-15.0 NR NR

Acrylic Polymer Proprietary 55.0-60.0 N/E N/E

Silica 14808-60-7 10.0-15.0 N/E N/E

Propylene Glycol 57-55-6 2.0-7.0 50 ppm(c) 50 ppm(c)

Ammonia 7664-41-7 > 5.0 25 ppm 50 ppm

Titanium Dioxide 13463-67-7 10 mg/m3 10 mg/m3

Texanol Ester 25265.77.4 > 5.0 N/E N/E

Ingredients not precisely identified are proprietary or non hazardous. Values are not product specifications. gt = greater than, lt = less than, ca = approximately, NE = not established, NR = not required, C = ceiling.

SECTION 3: PHYSICAL DATA

Boiling Point: No data on this mixture. Approximately 212 °F (water).

Vapor Pressure (mmHg at 20 C): No data on this mixture.

Vapor Density (air = 1): No data on this mixture.

pH: 9.5 - 10.0

Specific gravity: Approximately 1.10

% Volatile by volume: Approximately 45

Appearance: Viscous opaque liquid. Color dependent on specific formulation.

Solubility in water: Dilutable.

Characteristic odor: Slightly sweet, hint of ammonia

SECTION 4: FIRE AND EXPLOSION HAZARD DATA

Flash point (and method): Non-combustible.

Auto ignition temperature.: Not applicable.

Flammable limits (STP): Not applicable.

Extinguishing media: Not applicable.

Special fire fighting protective equipment: Self contained breathing apparatus for fire conditions.

Unusual fire and explosion hazards: Monomer vapors may be evolved at elevated temperatures. Dried polymer films are capable of burning yielding oxides of carbon.

SECTION 5: REACTIVITY DATA

Stability: Stable

Incompatibility (Materials to avoid): None

Hazardous decomposition products: None

Hazardous polymerization: Will not occur.

MSDS Metal Siding ~ page two

SECTION 6: HEALTH HAZARD ASSESSMENT

General: No toxicity information is available on this specific preparation; this health hazard assessment is based on information that is available on its components.

Ingestion: The principal toxic effect of this product, when swallowed, is likely to be due to the ethylene glycol content that causes kidney damage. Symptoms of ingestion may include abdominal discomfort and pain, dizziness, malaise, lumbar pain, central nervous system depression and other symptoms related to ethylene glycol ingestion. Severe kidney damage accompanies gross overexposure.

Eye contact: This product will probably irritate eyes upon direct contact. The dispersed dusts may cause corneal abrasions.

Skin contact: Direct, prolonged contact with skin may cause irritation.

Skin absorption: This material is known to be absorbed through the skin and no systematically toxic effects are known via this route.

Inhalation: Inhalation of dusts, mists and vapors from this product may irritate the nose, throat and lungs. High vapor concentrations caused by heating in confined spaced without adequate ventilation may result in severe irritation, headache, dizziness, nausea and vomiting. Use appropriate respiratory protection when spraying this product (Section 8).

Other effects of overexposure: None known.

First Aid Procedures:

Skin: Wash thoroughly with soap and water.

Eyes: Rinse with plenty of water and consult a physician if burning, redness, itching, pain or other symptoms persist or develop.

Ingestion: No specific recommendation. Seek medical attention immediately.

Inhalation: Remove subject to fresh air. If respiratory symptoms persist (irritation, cough, nausea, dizziness, ect). consult a physician

SECTION 7: SPILL OR LEAK PROCEDURES

Steps to be taken in case material is spilled or released: Keep unnecessary people away. Surfaces may be slippery, use caution. Dike and contain spill with inert material (sand, absorbent, earth, etc.). Transfer liquid to containers for recovery or disposal. Transfer solid diking/absorbent material to separate containers for disposal. Keep spills and runoff out of sewers and bodies of water.

Disposal Method: Discarded product is a non-hazardous waste under RCRA criteria (40 DFR, part 261). However, even small amounts of emulsion will discolor bodies of water. Reuse uncontaminated material when possible. Landfill or incinerate solids and contaminated diking material in accordance with local, state and federal regulations.

Container Disposal: Drain containers completely. Empty containers may retain small amounts of residual product. Observe all hazard precautions when handling empty containers. Puncture or otherwise destroy container and dispose of as non-hazardous waste in accordance with local, state and federal regulations.

SECTION 8: SPECIAL PROTECTION INFORMATION

TLV or Suggested control Value: No TLV assigned to this mixture. Minimize exposure in accordance with good hygiene practice.

Ventilation: Use local exhaust to keep exposures to a minimum.

Respiratory protection (specify type): Not normally required under normal conditions of use. If OSHA PEL's for components may be exceeded then use MSHA-NIOSH approved respirator for the applicable hazard. Refer to OSHA standards in 29 CFR, 1910.134.

Protective clothing: Use adequate clothing to minimize skin contact. Clean clothing on a regular basis.

Eye Protection: Chemical tight goggles or face shield recommended to avoid eye contact.

Other Protective Equipment: Provide eyewash station.

SECTION 9: SPECIAL PRECAUTIONS OR OTHER COMMENTS

Precautions to be taken in handling or storing: Keep from freezing. Product may coagulate. If frozen, thaw slowly at room temperature. Avoid breathing mists, vapors or aerosols. Avoid skin and eye contact.

ABBREVIATIONS USED:

ACGIH - American Conference of Governmental Industrial Hygienists N / E -Not Established

CAS -Chemical Abstracts Service NIOSH -National Institute of Occupational Safety and Health

IARC - International Agency for Research on Cancer PEL -Permissible Exposure Level

LEL -Lower Explosive Limits PPM -Parts per Million

MG CU M -Milligram per Cubic Meter OSHA -Occupational Safety and Health Administration

MM -Millimeters RECM -Recommended

MPPCF -Millions of Particles per Cubic Foot TCC / PM -Tag – Closed Cap / Pensky - Martin

MSHA -Mines Safety and Health Administration TLV -Threshold Limit Values

NA -Not Applicable UEL -Upper Explosive Limits

DISCLAIMER SECTION.

The information contained herein is based on data considered to be accurate. Penn Valley Paint makes no warranties express or implied and assumes no responsibility for the accuracy or completeness of the data. Penn Valley Paint further assumes no responsibility for personal injury or property damage to customers, users, or third parties caused by this material. Such customers or users assume all risks associated with the use of this material.

MSDS/MetalSiding03

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