MATERIAL SAFETY DATA SHEET

MATERIAL SAFETY DATA SHEET

1. Product and Company Identification

Material name

Advanced Polymer Adhesive

Revision date

7-29-2013

Version #

00

CAS#

Mixture

Manufacturer for

Crane Composites Inc 23525 W. Eames Street | Channahon, IL 60410-3220 US

Telephone number

800-435-0080

In case of emergency

800-424-9300

Product code

R53829

Chemical family

Adhesive.

2. Hazards Identification

EMERGENCY OVERVIEW Physical state Color Odor Signal word Hazard statements

Precautionary measures OSHA/HCS status

Liquid. [Paste]. Tan. Ester. [Slight] WARNING! HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. Product releases methanol during cure. Do not ingest. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

POTENTIAL ACUTE HEALTH EFFECTS

Inhalation

Exposure to decomposition products may cause a health hazard.

Serious effects may be delayed following exposure.

Ingestion

Toxic if swallowed

Skin

Slightly irritating to the skin.

Eyes

Severely irritating to eyes. Risk of serious damage to eyes.

POTENTIAL ACUTE HEALTH EFFECTS

Chronic effects

No known significant effects or critical hazards.

Carcinogenicity

No known significant effects or critical hazards.

Mutagenicity

No known significant effects or critical hazards.

Teratogenicity

No known significant effects or critical hazards.

Development effects

No known significant effects or critical hazards.

Fertility effects

No known significant effects or critical hazards.

Target organs

May cause damage to the following organs: skin, eyes.

Crane Composites | Advanced Polymer Adhesive Form # 7655 | Rev. 01 | 07.13 (6738)

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OVER-EXPOSURE SIGNS/SYMPTOMS

Inhalation

No specific data.

Ingestion

No specific data.

Skin

Adverse symptoms may include the following: irritation, redness

Eyes

Adverse symptoms may include the following: pain or irritation, watering, redness

Medical conditions aggravated None known. by over-exposure

see toxicological information in section 11

3. Composition / Information on Ingredients

United States

Name N-(3-(trimethoxysilyl)propyl)ethylenediamine

CAS number 1760-24-3

% 1 - 5

Canada

Name N-(3-(trimethoxysilyl)propyl)ethylenediamine

CAS number 1760-24-3

% 1 - 5

Mexico

Name

CAS

UN number %

IDLH Classification

number

H F R Special

N-(3-(trimethoxysilyl)propyl)ethylenediamine 1760-24-3 Not available. 1 - 5 -

3 0 0 -

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations

applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

4. First Aid Measure

Eye contact Skin contact Inhalation Ingestion Protection of first-aiders

Notes to physician

Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.

No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Crane Composites | Advanced Polymer Adhesive Form # 7655 | Rev. 01 | 07.13 (6738)

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5. Fire-Fighting Measures

Flammability of the product

In a fire or if heated, a pressure increase will occur and the container may burst.

EXTINGUISHING MEDIA Suitable Not suitable Special exposure hazards

Special protective equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

None known.

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

6. Accidental Release Measures

Personal precautions

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Small spill

Stop leak if without risk. Move containers from spill area. Dispose of via a licensed waste disposal contractor. Absorb with an inert material.

Large spill

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal.

7. Handling and Storage

Handling

Storage

Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Store between the following temperatures: 10 to 32.222?C (50 to 90?F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Contains moisture-sensitive material. Store in a dry place.

Crane Composites | Advanced Polymer Adhesive Form # 7655 | Rev. 01 | 07.13 (6738)

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8. Exposure Controls / Personal Protection

United States

Ingredient

Exposure limits

methanol

ACGIH TLV (United States, 1/2011). Absorbed through skin.

TWA: 200 ppm 8 hour(s).

TWA: 262 mg/m? 8 hour(s).

STEL: 250 ppm 15 minute(s).

STEL: 328 mg/m? 15 minute(s).

OSHA PEL 1989 (United States, 3/1989). Absorbed through skin.

TWA: 200 ppm 8 hour(s).

TWA: 260 mg/m? 8 hour(s).

STEL: 250 ppm 15 minute(s).

STEL: 325 mg/m? 15 minute(s).

NIOSH REL (United States, 6/2009). Absorbed through skin.

TWA: 200 ppm 10 hour(s).

TWA: 260 mg/m? 10 hour(s).

STEL: 250 ppm 15 minute(s).

STEL: 325 mg/m? 15 minute(s).

OSHA PEL (United States, 6/2010).

TWA: 200 ppm 8 hour(s).

TWA: 260 mg/m? 8 hour(s).

Canada

Occupational exposure limits Ingredient List name methanol US ACGIH 1/2011

AB 4/2009 BC 9/2011 ON 7/2010 QC 9/2011

[1] Absorbed through skin.

TWA (8 hours)

ppm mg/m? Other

200 262 -

200 262 -

200 -

-

200 262 -

200 262 -

STEL (15 mins)

ppm mg/m? Other

250 328 -

250 328 -

250 -

-

250 328 -

250 328 -

Ceiling ppm mg/m? - - - - - -

Other -

Notations [1] [1] [1] [1] [1]

Mexico

Ingredient

Exposure limits

Methanol

NOM-010-STPS (Mexico, 9/2000). Absorbed through skin.

LMPE-PPT: 200 ppm 8 hour(s).

LMPE-PPT: 260 mg/m? 8 hour(s).

LMPE-CT: 310 mg/m? 15 minute(s).

LMPE-CT: 250 ppm 15 minute(s).

Consult local authorities for acceptable exposure limits.

Recommended monitoring procedures Engineering measures

Hygiene measures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.

No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

PERSONAL PROTECTION Respiratory

Hands

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Crane Composites | Advanced Polymer Adhesive Form # 7655 | Rev. 01 | 07.13 (6738)

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Eyes

Skin

Environmental exposure controls

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

9. Physical and Chemical Properties

Physical state

Liquid. [Paste.]

Flash point

Closed cup: >93.333?C (>200?F) [Setaflash.]

Color

Tan.

Odor

Ester. [Slight]

Relative density

1.6

Volatility

0% (w/w)

Evaporation rate

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