SAFETY DATA SHEET: BARIUM NITRATE - Integra Chem

SAFETY DATA SHEET: BARIUM NITRATE

1. IDENTIFICATION

Product Name: Synonyms: Formula and Formula Weight: Integra numbers beginning with: Recommended Use: Restrictions on Use:

BARIUM NITRATE Barium (II) nitrate; Barium dinitrate; Nitric acid barium salt

Ba(NO3)2 261.35 B154.10 Commercial/industrial use No information available

INTEGRA Chemical Company 1216 6th Ave N Kent WA 98032 Phone: 253-479-7000

2. HAZARDS IDENTIFICATION OSHA Classification: Acute Toxicity - Oral Acute Toxicity - Inhalation Eye Damage/Irritation Oxidizing Solids

Signal Word:

DANGER

24 Hour Emergency Response: CHEMTREC 800-424-9300 (Outside USA 703-527-3887)

Hazard Category: 4 4 2A 2

Hazard Statement: Harmful if swallowed. Harmful if inhaled. Causes serious eye irritation. May intensify fire; oxidizer.

Precautionary Statements Prevention: Keep away from heat. Keep and store away from clothing, combustible materials. Take any precaution to avoid mixing with combustibles. Use only outdoors or in a well-ventilated area. Avoid breathing dust, fume, gas, mist, vapors, spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves, eye protection, face protection. Response Rinse mouth. If swallowed: Call a poison center, doctor if you feel unwell. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice, attention. Call a poison center, doctor if you feel unwell. In case of fire: Use use dry sand, chemical or alcohol-resistant foam to extinguish. Disposal Dispose of contents, container in accordance with all governmental regulations.

Hazards Not Otherwise Classified: No information available

3. COMPOSITION/INFORMATION ON INGREDIENTS

Component Barium Nitrate

Synonyms

Barium (II) nitrate; Barium dinitrate; Nitric acid barium salt

CAS # 10022-31-8

% Weight 100

4. FIRST AID MEASURES

Inhalation: Eye Contact:

Skin Contact: Ingestion:

Additional notes:

Call a poison center or doctor if you feel unwell.

Remove person to fresh air and keep comfortable for breathing.

Flush eyes with plenty of water. Remove contact lenses, if present and easy to do. If irritation persists, seek medical attention. Flush skin with plenty of water. Seek medical attention. Rinse mouth and give victim large quantities of water. Never give anything by mouth to an unconscious person. Seek immediate medical attention. Symptoms and effects include serious eye irritation; skin, respiratory irritation; vomiting, severe abdominal pain, slow and irregular pulse, muscle twitchings progressing to convulsions and/or paralysis, dilated pupils, confusion, death.

5. FIRE-FIGHTING MEASURES Extinguishing Media:

Use use dry sand, chemical or alcohol-resistant foam to extinguish.

OSHA SDS #: 25197 rev 101 3/27/2015 BARIUM NITRATE

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Special Equipment and Precautions:

Specific Hazards: Hazardous combustion products:

Use water to cool nearby containers and structures. Wear full protective equipment, including suitable respiratory protection. Strong oxidizer. Contact with combustible or flammable materials can cause fire or explosion. Oxides of nitrogen.

6. ACCIDENTAL RELEASE MEASURES

Spill Procedures:

Prevent spread of spill. Wear suitable protective equipment. Sweep or scoop into clean, dry disposal container. Flush spill area with water. Wear full protective equipment including respiratory protection. Keep combustible or flammable materials away from spill area.

7. HANDLING AND STORAGE

Incompatible Materials:

Incompatible with strong bases.Reducing agents, acids, organic or combustible materials.

Storage and Handling:

Store in a cool, dry, well-ventilated area dedicated to the storage of oxidizers. Keep away from incompatible materials, especially flammable or combustible materials. Keep containers tightly closed and protect them from physical damage. Protect material from exposure to air and moisture. Toxic material.

Keep away from heat. Keep and store away from clothing, combustible materials. Take any precaution to avoid mixing with combustibles. Use only outdoors or in a well-ventilated area. Avoid breathing dust, fume, gas, mist, vapors, spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves, eye protection, face protection.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION OSHA & ACGIH Exposure Limits:

Barium Nitrate

OSHA TWA: 0.5 mg/m3 (as Ba) ACGIH TWA: 0.5 mg/m3 (as Ba)

Engineering Controls:

Use general or local exhaust ventilation to meet TLV and PEL requirements.

Respiratory Protection:

Respiratory protection required if airborne concentrations exceed PEL or TLV. Use a NIOSH approved respirator with a particulate filter.

Skin/Eye Protective Equipment: Safety goggles, protective clothing and gloves appropriate for the risk of exposure. Butyl rubber gloves are recommended.

Facilities storing or utilizing this material should have readily accessible eyewash stations and safety showers. Select respirators and other safety equipment in accordance with regulations and based upon the particular conditions of use and risk of exposure. Always use safe chemical-handling and good industrial hygiene practices.

9. PHYSICAL AND CHEMICAL PROPERTIES

Apearance:

White crystalline powder

Odor:

Odorless

Odor Threshold:

Not available

pH:

Not available

Melting/Freezing Point:

Not available

Initial Boiling Point and Boiling Range: Not available

Flash Point:

Not available

Evaporation Rate:

Not available

Flammability:

Not available

Flammable or Explosive

Upper: Not available

Limits (% by volume in air)

Lower: Not available

Vapor Pressure:

Not available

Vapor Density:

9.0

Relative Density:

3.24 g/cc

Solubility:

Moderately soluble in water.

Partition Coefficient: n-octanol/water Not available

Auto-Ignition Temperature:

Not available

Decomposition Temperature:

592

Viscosity:

Not available

10. STABILITY AND REACTIVITY

Reactivity:

No information available

Stability:

Stable

Possibility of Hazardous Reactions: Hazardous polymerization will not occur

Conditions to Avoid:

Heat and moisture.

Incompatibles:

Incompatible with strong bases.Reducing agents, acids, organic or combustible materials.

Decomposition Products:

Oxides of nitrogen.

11. TOXICOLOGICAL INFORMATION

Effects of Over Exposure:

Inhalation:

Harmful if inhaled. Irritating to the upper respiratory tract and mucous membranes. Dust may be absorbed with systematic toxic effects similar to ingestion.

OSHA SDS #: 25197 rev 101 3/27/2015 BARIUM NITRATE

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Skin Contact: Eye Contact: Ingestion:

Chronic Effects: Target Organs: Additional Effects: Reproductive Effects: Carcinogenicity:

Contact may cause skin irritation. Contact may cause serious eye irritation. Harmful or fatal if swallowed. Symptoms of poisoning include vomiting, severe abdominal pain, slow and irregular pulse, muscle twitchings progressing to convulsions and/or paralysis, dilated pupils, confusion, possibly death. Central nervous system damage; irritation of the respiratory system; damage to spleen, liver and bone marrow. None identified None identified None identified

Barium Nitrate is listed by the IARC as Group 2A, Probable Human Carcinogen [as Nitrate or nitrite (ingested) unde conditions that result in endogenous nitrosation].

Toxicity Data:

Barium Nitrate

LD50 (oral, rat)

355 mg/kg

12. ECOLOGICAL INFORMATION

Aquatic Toxicity Data:

Terrestrial Toxicity Data:

Barium Nitrate

No information available

No information available

Persistence and degradability: Bioaccumulative potential: Mobility in soil: Other adverse effects:

No information available No information available No information available No information available

13. DISPOSAL CONSIDERATIONS Disposal Procedures: Dispose of material and containers in accordance with all local, state and federal regulations. 14. TRANSPORTATION INFORMATION This product is a regulated material for domestic ground transporation, per CFR Title 49.

UN Number: Proper Shipping Name: Packing Group: Hazard Class: Subsidiary Risk:

UN1446 Barium nitrate II 5.1 6.1

Environmental hazards: Special precautions: Bulk transport:

No information available No information available No information available

15. REGULATORY INFORMATION

Barium Nitrate is listed in the TSCA inventory and in SARA 313 (as barium compounds, nitrate compounds).

16. OTHER INFORMATION

OSHA SDS #: 25197 rev 101 3/27/2015

NE = Not established, NA = Not applicable or Not available The information presented above is offered for informational purposes only. This SDS, and the associated product, is intended for use only by technically qualified persons, and at their own discretion and risk. Since conditions and manner of use are outside the control of Integra Chemical Company, we make no warranties, either

expressed or implied, and assume no liability in connection with any use of this information. ***** END OF SDS *****

OSHA SDS #: 25197 rev 101 3/27/2015 BARIUM NITRATE

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