SAFETY DATA SHEET .au

SAFETY DATA SHEET

Advocate for Dogs

Date of Issue: 17 February 2016

SDS NUMBER A941097/5 NZ

1. Identification of the Substance/Mixture and Supplier.

Product name: Other Product Names: Application:

Advocate for Dogs Imidacloprid 10%/Moxidectin 2.5%, Advantage Multi for Dogs Endoectocide for ectoparasite and endoparasite control on dogs

Company:

Telephone: Facsimile: Emergency telephone: National Poisons Centre:

Bayer New Zealand Limited, 3 Argus Place, Hillcrest, Auckland, 0627 New Zealand. 0800 652 488 0800 229 838 0800 734 607 Ixom SH&E Shared services (24hr) 0800 POISON (0800 764766)

2. Hazards Identification.

Hazardous Status:

HSNO CLASSIFICATION 6.1D (oral)

Classified as hazardous according to the criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001.

GHS HAZARD STATEMENTS

H302 Harmful if swallowed.

6.1D (inhalation ? vapours, dusts, mists) 6.1E (dermal)

H332 Harmful if inhaled. H313 May be harmful in contact with skin.

6.4A 6.5B

H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.

6.8C

H362 May cause harm to breast-fed children.

6.9A (repeated exposure)

H372 Causes damage to organs through prolonged or repeated exposure.

9.1A

H410 Very toxic to aquatic life with long lasting effects.

9.2C

H423 Harmful to the soil environment.

9.3B 9.4A

H432 Toxic to terrestrial vertebrates. H441 Very toxic to terrestrial invertebrates.

Signal Word:

DANGER

PREVENTION STATEMENTS

P102

Keep out of reach of children.

P103

Read label before use.

P201

Obtain special instructions before use.

P260

Do not breathe mist/vapours/spray.

P263

Avoid contact during pregnancy/while nursing.

P264

Wash thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P271

Use only outdoors or in a well-ventilated area.

P272

Contaminated work clothing should not be allowed out of the workplace.

P273

Avoid release to the environment.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

Page 1 of 6

SAFETY DATA SHEET

Advocate for Dogs

Date of Issue: 17 February 2016

SDS NUMBER A941097/5 NZ

RESPONSE STATEMENTS

P101

If medical advice is needed, have product container or label at hand.

P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P330

Rinse mouth.

P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.

P312

Call a POISON CENTER or doctor/physician if you feel unwell.

P305 + P351 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

+ P338

present and easy to do. Continue rinsing.

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

P363

Wash contaminated clothing before reuse.

P308 + P313 IF exposed or concerned: Get medical advice/attention.

P391

Collect spillage.

STORAGE STATEMENTS ? N/A

DISPOSAL STATEMENTS

P501

Do not let this product enter the environment. Do not dispose of in waterways or sewers.

Dispose of this material and its container as hazardous waste, via a licensed facility. See

local council for disposal/recycling information.

GHS DIAMONDS

3. Composition/Information on Ingredients.

Chemical Entity

CAS No

Proportion

Imidacloprid Moxidectin Benzyl alcohol Propylene carbonate; 1,3Dioxolan-2-one, 4-methyl-

138264-41-3 113507-06-5 100-51-6 108-32-7

10% 2.5% >70% 100?C 415?C The product is packaged in individual, single dose tubes of 0.4 ? 4.0 mL capacity. The tubes are packed in blister pack trays of 4 or 6 tubes per tray. The product is therefore well protected from accidental release.

10. Stability and Reactivity

Hazardous decomposition products: Hazardous reactions: Conditions to avoid:

Thermal decomposition products include hydrogen chloride, hydrogen cyanide, carbon monoxide and nitrogen oxides. No hazardous reactions. Avoid strong oxidising agents

11. Toxicological Information

Acute toxicity: Moxidectin:

Imidacloprid: Skin irritation: Eye irritation: Sensitization: Further information:

LD50 oral, rat 106 mg/kg LD50 dermal, rabbit >2000mg/kg LD50 inhalation rat, >5323, aerosol, 4 hr exposure Irritant Irritant Sensitizer Possible effects via lactation and target organ toxicity. Chemical-pharmacological effect: Anthelmintics and Antiparasitic.

12. Ecological Information

Acute fish toxicity: Imidacloprid:

Benzyl alcohol:

Acute daphnia toxicity: Imidacloprid:

Benzyl alcohol: Acute algal toxicity: Imidacloprid:

Benzyl alcohol: Acute bacterial toxicity: Imidacloprid: Bezylalcohol: EEL water, Imidacloprid:

LC50 (96hr) 237mg/L Golden orfe (Leuciscus idus) LC50 (96hr) 211 mg/L Rainbow trout (oncorhynchus mykiss) LC50 (48hr) 646mg/L Golden orfe (Leuciscus idus) LC50 (96hr) 460mg/L Pimephales promelas

EC50 (96hr) 0.055mg/L Hyalella azteca EC50 (48hr) 85mg/L Water flea (daphnia magna) 400mgL Water flea (Daphnia magna) IC50 (72hr) >10mg/L Green algae (Desmodesmus subspicatus) IC50 (72hr) >100mg/L Green alga (Psuedokirchnerilla subcapitata) EC50 (96hr) 640mg/L Green algae (Desmodesmus subspicatus)

EC50 >10 000mg/L Actived sludge EC10 658 mg/L Pseudomonas putida 0.000038mg/L

Page 4 of 6

SAFETY DATA SHEET

Advocate for Dogs

Date of Issue: 17 February 2016

SDS NUMBER A941097/5 NZ

Moxidectin Butylhydroxytoluene: EEL soil/sediment: Imidacloprid:

0.0000006mg/L 0.00014mg/L 1?g/kg dry weight

13. Disposal Considerations.

Disposal: Empty Container precautions:

Dispose of unused product in sealed containers at an approved local waste disposal company. Dispose of used applicators by wrapping in paper and placing in garbage

14. Transportation Information.

Proper Shipping Name:

UN Number: Hazard Class: Hazchem Code: Packing Group: Flashpoint ?C Marine pollutant Hazardous substance regulations:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Imidacloprid, Moxidectin) 3082 9 3Z III >100?C Yes Maximum quantity per package permitted on passenger services vehicle 0.1L

15. Regulatory Information.

ACVM Number A009118 HSNO Approval Number: HSR000060 HSNO Classification: 6.1D(oral/inhal), 6.1E(dermal), 6.4A, 6.5B, 6.8C, 6.9A, 9.1A, 9.2C, 9.3B, 9.4A

Controls for hazardous substances: This product is exempt from approved handler and tracking requirements. Level 2 Emergency Management Information required when >0.1L present in a workplace. Level 3 Emergency Management Plans required when>100L present in a workplace. Where an excess of 10 000L is store, signage is required for toxic substance. Where an excess of 100L is stored, signage is required for ecotoxic substance.

Controls of hazardous substances are based upon current knowledge. Where multiple chemicals are stored, controls will take into account aggregate quantities. Contact a WorkSafe NZ Approved Test Certifier for further information and guidance.

16. Other Information.

HSNO = Hazardous Substances and New Organisms Act. EPA = Environmental Protection Authority DFG MAK = Federal Republic of Germany maximum Workplace Concentration Values in the workplace.

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