Material Safety Data Sheet



Material Safety Data Sheet | |

|Name UPC01641C ORTHO MALATHION 50 PLUS INSECT SPRA |MSDS bxksz |

|Company SOLARIS GROUP DIV OF AGRICULTU |FSC 8720 |

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MSDS Safety Information

FSC: 8720

MSDS Date: 12/24/1993

MSDS Num: BXKSZ

LIIN: 00F039962

Product ID: UPC01641C ORTHO MALATHION 50 PLUS INSECT SPRAY

MFN: 01

Responsible Party

Cage: SOLAR

Name: SOLARIS GROUP DIV OF AGRICULTURAL GRP OF MONSANTO

Box: 5008

City: SAN RAMON CA 94583-0808

Info Phone Number: 800-225-2883/800-454-2333

Emergency Phone Number: 800-454-2333/800-225-2883

Review Ind: Y

Published: Y

Preparer Co. when other than Responsible Party Co.

Cage: SOLAR

Assigned Ind: Y

Name: SOLARIS GROUP DIV OF AGRICULTURAL GRP OF

Box: 5008

City: SAN RAMON CA 94583-0808

Contractor Summary

Cage: SOLAR

Name: SOLARIS GROUP DIV OF AGRICULTURAL GRP OF

Box: 5008

City: SAN RAMON CA 94583-0808

Phone: 800-225-2883/800-454-2333

Ingredients

Cas: 121-75-5

RTECS #: WM8400000

Name: MALATHION, O,O-DIMETHYL DITHIOPHOSPHATE OF DIETHYL MERCAPTOSUCCINATE

% Wt: 50

OSHA PEL: 15 MG/CUM (SKIN)

ACGIH TLV: 10 MG/CUM

EPA Rpt Qty: 100 LBS

DOT Rpt Qty: 100 LBS

------------------------------

Cas: 1330-20-7

RTECS #: ZE2100000

Name: XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *95-1*

% Wt: ANDlt;1.7

Other REC Limits: 100 PPM

OSHA PEL: 100 PPM

ACGIH TLV: 100 PPM, SKIN

EPA Rpt Qty: 1000 LBS

DOT Rpt Qty: 1000 LBS

------------------------------

Name: AROMATIC PETROLEUM DERIVATIVE SOLVENT

% Wt: ANDlt;32

-----------------------------

Name: INERT INGREDIENTS

% Wt: 17

Health Hazards Data

LD50 LC50 Mixture: ORAL LD50 (MALE RAT): 2.314 G/KG

Route Of Entry Inds - Inhalation: NO

Skin: NO

Ingestion: YES

Carcinogenicity Inds - NTP: NO

IARC: NO

OSHA: NO

Effects of Exposure: EYES: MODERATE IRRITANT, VISION IMPAIRMENT. SKIN:

IRRITATION. INGESTION: SLIGHTLY TOXIC TO INTERNAL ORGANS. CAN DIRECTLY ENTER

LUNGS ANDamp; CAUSE SEVERE INJURY/DEATH.

Explanation Of Carcinogenicity: NONE

Signs And Symptions Of Overexposure: IRRITATION, HEADACHE, DIZZINESS, WEAKNESS,

CONSTRICTION OF PUPIL, BLURED/DARK VISION, EXCESSIVE SALIVATION/NASAL

DISCHARGE, PROFUSE SWEATING, ABDOMINAL CRAMPS, NAUSEA, VOMITING,

INCONTINENCE, UNCONSCI OUSNESS, CONVULSIONS.

First Aid: EYES: IMMEDIATELY FLUSH W/FRESH WATER FOR 15 MINS. REMOVE CONTACT

LENSES. SKIN: WASH THOROUGHLY W/SOAP ANDamp; WATER. INGESTION: GIVE WATER/MILK

TO DRINK. DON'T MAKE VOMIT UNLESS DIRECTED TO DO SO BY MEDICA L PERSONNEL.

OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIANS: MATERIAL MATERIAL

CONTAINS A CHOLINESTERASE INHIBITOR. (SEE SUPP).

Handling and Disposal

Spill Release Procedures: ELIMINATE IGNITION SOURCES. CLEAN UP IMMEDIATELY

COVER W/GENEROUS AMOUNT OF ABSORBENT. USE A STIFF BROOM TO MIX THOROUGHLY.

SWEEP UP/PLACE IN A DISPOSABLE CONTAINER. SCRUB AREA W/DETERGENT ANDamp; WATER.

PI CK UP W/ADDITIONAL ABSORBANT ANDamp; PLACE INCONTAINER.

Waste Disposal Methods: PARTIALLY FILLED CONTAINER MAY BE DISPOSED OF BY

SECURELY WRAPPING ORIGINAL CONTAINER IN SEVERAL LAYERS OF NEWSPAPER ANDamp;

DISCARD IN TRASH. DON'T REUSE EMPTY CONTAINER. RINSE EMPTY CONTAINER

THOROUGHLY B EFORE DISCARDING IN TRASH IAW/FEDERAL, STATE.

Handling And Storage Precautions: DON'T USE/STORE NEAR IGNITION SOURCES. USE IN

WELL VENTILATED AREA. REPLACE CAP/BUNG. EMPTIED CONTAINER CONTAINS

HAZARDOUS/EXPLOSIVE VAPOR.

Other Precautions: DON'T WELD/HEAT/DRILL CONTAINER. KEEP PESTICIDE IN ORIGINAL

CONTAINER. DON'T APPLY DIRECTLY TO WATER/WETLANDS/CONTAMINATE WATER BY

CLEANING OF EQUIPMENT/DISPOSAL OF WASTE. DON'T STORE/TRANSPORT NEAR F OOD.

AVOID EYE/SKIN/CLOTHING CONTACT.

Fire and Explosion Hazard Information

Flash Point Method: TOC

Flash Point Text: 106F

Extinguishing Media: CO2, DRY CHEMICAL, FOAM, WATER FOG

Fire Fighting Procedures: AVOID PERSONNEL ANDamp; EQUIPMENT CONTACT

W/FALLOUT/RUNOFF. MIMIMIZING THE AMOUNT OF WATER USED. USE FULL PROTECTIVE

EQUIPMENT ANDamp; SCBA. CONTAIN/ISOLATE RUNOFF ANDamp; DEBRIS

Unusual Fire/Explosion Hazard: LIQUID EVAPORATES ANDamp; FORMS VAPOR WHICH CAN

CATCH FIRE ANDamp; BURN W/EXPLOSIVE VIOLENCE. INVISIBLE VAPOR SPREADS EASILY

ANDamp; CAN BE SET ON FIRE BY SOURCES OF IGNITION.

Control Measures

Respiratory Protection: NO SPECIAL RESPIRATORY PROTECTION IS NORMALLY REQUIRED.

IF OPERATING CONDITIONS CREATE AIRBORNE CONCENTRATIONS WHICH EXCEED THE

RECOMMENDED EXPOSURE STANDARDS, THE USE OF AN APPROVED RESPIRATOR IS REQ

UIRED.

Ventilation: REQUIRED.

Protective Gloves: REQUIRED

Eye Protection: CHEMICAL GOGGLES/FACE SHIELD

Other Protective Equipment: PROTECTIVE CLOTHING.

Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.

Supplemental Safety and Health: FIRST AID CONT'D: MEASUREMENT OF BLOOD

CHOLINESTERASE ACTIVITY MAY BE USEFUL IN MONITORING EXPOSURE. IF SIGNS

APPEAR, ATROPINE SULFATE IS ANITDOTAL. 2-PAM MAY BE USED IN CONJUNCTION

W/ATROPINE BUT NOT ALONE.

Physical/Chemical Properties

B.P. Text: 300F

M.P/F.P Text: ANDlt;-50F

Vapor Pres: ANDlt;10

Vapor Density: 4.5

Spec Gravity: 1.07

Evaporation Rate ANDamp; Reference: (N-BU AC =1): 0.2

Solubility in Water: MISCIBLE

Appearance and Odor: AMBER LIQUID W/GARLIC LIKE ODOR.

Percent Volatiles by Volume: 35

Reactivity Data

Stability Indicator: YES

Stability Condition To Avoid: TEMP gt;85F, HEAT, SPARKS, HOT SURFACES AND OTHER

IGNITION SOURCES.

Hazardous Decomposition Products: CO, CO2, OXIDES OF SULFUR AND PHOSPHORUS.

Hazardous Polymerization Indicator: NO

Toxicological Information

Ecological Information

MSDS Transport Information

Regulatory Information

Other Information

HAZCOM Label

Product ID: UPC01641C ORTHO MALATHION 50 PLUS INSECT SPRAY

Cage: SOLAR

Assigned IND: Y

Company Name: SOLARIS GROUP DIV OF AGRICULTURAL GRP OF

PO Box: 5008

City: SAN RAMON CA

Zipcode: 94583-0808

Health Emergency Phone: 800-454-2333/800-225-2883

Label Required IND: Y

Date Of Label Review: 12/16/1998

Status Code: C

Label Date: 12/16/1998

Origination Code: G

Hazard And Precautions: EYES: MODERATE IRRITANT, VISION IMPAIRMENT. SKIN:

IRRITATION. INGESTION: SLIGHTLY TOXIC TO INTERNAL ORGANS. CAN DIRECTLY ENTER

LUNGS ANDamp; CAUSE SEVERE INJURY/DEATH.

IRRITATION, HEADACHE, DIZZINESS,

WEAKNESS, CONSTRICTION OF PUPIL, BLURED/DARK VISION, EXCESSIVE

SALIVATION/NASAL DISCHARGE, PROFUSE SWEATING, ABDOMINAL CRAMPS, NAUSEA,

VOMITING, INCONTINENCE, UNCONSCIOUSNESS, CONVULSIONS.

Disclaimer

(provided with this information by the compiling agencies): This

information is formulated for use by elements of the Department of Defense.

The United States of America in no manner whatsoever expressly or implied

warrants, states, or intends said information to have any application, use or

viability by or to any person or persons outside the Department of Defense

nor any person or persons contracting with any instrumentality of the United

States of America and disclaims all liability for such use. Any person

utilizing this instruction who is not a military or civilian employee of the

United States of America should seek competent professional advice to verify

and assume responsibility for the suitability of this information to their

particular situation regardless of similarity to a corresponding Department

of Defense or other government situation.

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