Principal Investigator: James S. Chickos, Professor …



James S. Chickos

Professor of Chemistry

314 516 5377

e-mail: JSC@UMSL.EDU

Education

Ph.D. 1966 Cornell University ;

B.S. 1963 S. U. N. Y. at Buffalo

Professional Experience

1992-3 Research Leave, CNRS, Marseille, France; Reading University , Reading UK

1987- Professor, University of Missouri-St. Louis

1985-6 Research Leave, Reading University, UK

1976-85 Associate Professor, Univ. of Mo.-St. Louis

1969-76 Assistant Professor, Univ. of Mo.-St. Louis

1967-69 NIH Postdoctoral Fellow, Univ. of Wisconsin

1966-67 NIH Postdoctoral Fellow, Princeton University

Organizations

Member of the editorial board of "Structural Chemistry", Plenum Press, N. Y.; A. Greenberg and I. Hargittai, edit.; American Chemical Society; Intern Confederation for Thermal Analysis and Calorimetry (ICTAC); IUPAC.

Publications

1. Farnum, D. G.; Chickos, J. S.; Thurston, P. "The Synthesis and Characterization of Phenylhydroxycyclopropenone", J. Amer. Chem. Soc. 1966, 88, 3075.

2. Chickos J.; Mislow, K. "Conformational Flexibility of Thianthrene and Its Oxides", J. Am. Chem. Soc. 1967, 89, 48l5.

3. West, R.; Chickos, J. S.; Osawa, E. "Dichlorocyclopropenone", J. Amer. Chem. Soc. 1968, 90, 3885.

4. Korpiun, O.; Lewis, R.; Chickos, J. S.; Mislow, K. "Synthesis and Absolute Configuration of Optically Active Phosphine Oxides and Phosphinates", J. Amer. Chem. Soc. 1968, 90, 4842.

5. Chickos, J. S. "Methylhydroxycyclobutenedione", J. Amer. Chem. Soc. 1970, 92, 5749.

6. Chickos, J. S.; Larsen, D. W.; Legler, L. E. "A Nuclear Magnetic Resonance Study of the Keto-Enol Equilibrium of 3-Hydroxy-2,4-dimethylcyclobutenone", J. Amer. Chem. Soc. 1972, 94, 4266.

7. Chickos, J. S.; Winter, R. E. K. "Nuclear Magnetic Resonance Studies of the Mechanism of Keto-Enol Tautomerism in 3-Hydroxy-2,4-Dimethylcyclobutenone. II. Solvent and pH Effects", J. Amer. Chem. Soc. 1973, 95, 506.

8. Chickos, J. S.; Garin, D. L.; Rouse, R. A. "Chemistry in Society, A Necessary Chemistry Course for Non- Science Majors", Chemistry in the Two Year College, 1972, (2) 65.

9. Warren, C. B.; Bloomfield, J. J.; Chickos, J. S. "Electrochemical preparation and Retrodiene Reaction of l,4- bis-(Methoxycarbonyl)-bicyclo(2.2.2)octa-2,5-diene", manuscript #2l2l, Monsanto Chemical Co., St. Louis, MO. Chickos, J. S.; Rouse, R. A.; Warren, C. B.; Bloomfield, J. J. "Mechanism of the Retro-Diels Alder Reaction. The Thermal Retro-Diels Alder Reaction of l,4-bis(Methoxycarbonyl)-bicyclo[2.2.2]octa-2,5-diene", J. Org. Chem. 1973, 38, 40ll.

10. Chickos, J. S. "The Synthesis of 3,5-Dicarbethoxy-l,2,4- cyclopentanetrione. A Correction", J. Org. Chem. 1973, 38.

11. Chickos, J. S.; Berndt, A. F.; Clause, A.C. "Crystal Data on Phenylhydroxycyclopropenone", J. Appl. Cryst. 1973, 6, 303.

12. Chickos, J. S.; Patton, E.; West, R. "Aryltrichlorocyclopropenes and Arylhydroxycyclopropenones", J. Org. Chem. 1974, 39, l647.

13. Chickos, J. S. "A Ring Enlargement of Phenylmethoxycyclopropenone. A Regiospecific Mass Spectrometric CO Extrusion in Phenylmethoxycyclobutenedione", J. Org. Chem. 1973, 38, 3642.

14. Chickos, J. S. "A Simple Equilibrium Method for Determining Heats of Sublimation Using the Clausius- Clapeyron Equation", J. Chem. Ed. 1975, 52 l34.

15. Jug, K.; Chickos, J. S. "Pathways of Ketene Dimerization", Theoretica Chimica Acta 1975, 40, 207.

16. Chickos, J. S. "Use of the Kinetic Isotope Effect as a Test for a Homogeneous Unimolecular Gas Phase Reaction in Thermolytic Processes", J. Org. Chem. 1976, 4l, 3l76.

17. Chickos, J. S.; Sherwood, D. W.; Jug, K. "Mechanism of Thermolysis of Diketene in the Gas Phase", J. Org. Chem. 1978, 43, ll46.

18. Jug, K.; Dwivide, C. P. D.; Chickos, J. S. "Reaction Pathways for Various Ketene Dimers", Theoretica Chimica Acta 1978, 49, 249.

19. Sandman, D. J.; Epstein, A. J.; Chickos, J. S.; Ketchum, J.; Fu, J. S.; Scheraga, H. A. "Crystal Lattice and Polarization Energy of Tetrathiafulvalene", J. Chem. Phys. 1979, 70, 305.

20. Chickos, J. S. "The Thermolysis of cis and trans-l,2-Dideuteriocyclobutane, J. Org. Chem. 1979, 44, 780.

21. Chickos, J. S. "The Kinetic Isotope Effect in the Thermolysis of Methylenecyclobutane", J. Org. Chem. 1979, 44, l5l5.

22. Garin, D. L.; Chickos, J. S. "Thermolysis of 6-endo- Carbomethoxy[3.1.0]hexane. Comparison with the Parent Compound, J. Org. Chem. l980, 45, 272l.

23. Chickos, J. S.; Garin, D. L.; Hilt, M.; Schilling, G. "Some Solid State Properties of Enantiomers and Their Racemates", Tetrahedron l98l, 37, 2255.

24. Chickos, J. S.; Alul, R.; Bausch, M. "A Stereospecific Synthesis of Optically Active Dideuteriosuccinic Acid",J. Org. Chem. l98l, 46, 3559.

25. Chickos, J. S.; Hyman, A. S.; Ladon, L. A.; Liebman, J. F. "Measurement and Estimation of the Heats of Vaporization of Hydrocarbons", J. Org. Chem. l98l, 46, 4294.

26. Annamalai, A.; Keiderling, T. A.; Chickos, J. S. "Vibrational Circular Dichroism of trans-1,2- Dideuteriocyclobutane. A Comparison of Fixed Partial Charge and Localized Molecular Orbital Theories with Different Force Field", J. Amer. Chem. Soc. 1984, 106, 6254.

27. Steele W. V.; Gannon B. E.; Smith N. K.; Greenburg A. Chickos, J. S.; Liebman, J.F. "The Standard Enthalpy of Formation of 2,3-Diphenylcycloprop-2-ene-l-one", J. Chem. Thermodyn. 1985, 17, 505.

28. Chickos J. S.; Al-Nawwar K. "A Stereochemical Study of the Thermolysis of Cyclobutane-1,2-dione", Tetrahedron Lett. 1985, 26, 1127.

29. Annamalai A.; Keiderling T. A.; Chickos J. S. "Vibrational Circular Dichroism of trans-l,2- Dideuteriocyclobutane. Experimental and Calculated Results in the Mid Infrared", J. Amer. Chem. Soc. 1985, 107, 2285.

30. Chickos J. S. " A Study of the Catalytic Deuteration of Maleic and Fumaric Acids and Derivatives with Palladium on Carbon", J. Org. Chem. 1986, 51, 553.

31. Chickos, J. S.; Annamalai, A.; Keiderling, T. A. "The Thermolysis of (1R, 2R)-Dideuteriocyclobutane. An Application of Vibrational Circular Dichroism to Kinetic Analysis", J. Amer. Chem. Soc. 1986, 108, 4398.

32. Chickos, J. S.; Annunziata, R.; Ladon, L. H.; Hyman, A. S.; Liebman, J. F. "Estimating Heats of Sublimation of Hydrocarbons. A Semiempircal Approach". J. Org. Chem. 1986, 51, 4311.

33. Chickos, J. S.; Frey, H. M. "The Thermolysis of 2,2-Dimethyl-1-vinylcyclobutane", J. Chem. Soc. Perkin II 1987, 365.

34. Chickos, J. S. "Secondary Deuterium Isotope Effects in the Thermolysis of 2,2-Dimethyl-1-vinylcyclobutane", J. Chem. Soc. Perkin II 1987, 1109.

35. Wang, Y.- S.; Chickos, J. S. "A Stereochemical Study of the Thermolysis of cis-anti- and trans-1,2-Dimethyl- cis-3,4-dideuteriocyclobutane," J. Org. Chem. 1987, 52, 4776-4781.

36. Chickos, J. S.; Hesse, D. G.; Liebman, J. F.; Panshin, S. Y. "Estimations of the Heats of Sublimation of Simple Hydrocarbon Derivatives", J. Org. Chem. 1988, 53, 3424.

37. Hirota, E.; Endo, Y.; Fujitake, M.; Della, E. W.; Pigou, P. E.; Chickos, J. S. "Development of Millimeter and Submillimeter-wave Spectroscopy and Its Applications to Isotopically-Substituted Nonpolar Molecules; Deuterated Cubane and Deuterated Cyclobutanes." J. Molecular Spectroscopy 1988, 190, 235-258.

38. Conlin, R. T.; Namavari, M.; Chickos, J. S.; Walsh, R. "Kinetics and Mechanism of the Thermal Decomposition of E- and Z-1,1,2,3-Tetramethylsiletane." Organometallics 1989, 8, 168-175.

39. Chickos, J. S.; Hesse, D. G.; Liebman, J. F.; Estimating Vaporization Enthalpies of Organic Molecules With Multiple Substitution", J. Org. Chem. 1989, 54, 5250.

40. Chickos, J. S.; Hesse, D. G.; Liebman, J. F. "Estimating Entropies and Enthalpies of Fusion of Hydrocarbons", J. Org. Chem. 1990, 55, 3833.

41. Chickos, J. S. Hesse, D. G.; "An Experimental Test of the Double Solubility Rule." Structural Chemistry 1991, 2, 33.

42. Liebman, J. F.; Chickos, J. S. "The heat of Vaporization of Acyl Derivatives: When Are Carboxylic Acid Esters a-Oxaketones or Acylethers? Struct. Chem. 1990, 1, 501.

43. Chickos, J. S.; Hesse, D. G.; Liebman, J. F. "Estimating Entropies and Enthalpies of Fusion of Organic Compounds", J. Org. Chem. 1991, 56, 927.

44. Chickos, J. S.; Uang, J. "A Study of the Catalytic Deuteration of Butynediol", J. Org. Chem. 1991, 56, 2594.

45. Malon, P.; Keiderling, T. A.; Uang, J.-Y.; Chickos, J. S. "Vibrational Circular Dichroism Study of [3R,4R]- Dideuteriocyclobutane-1,2-dione. Preliminary Comparison of Experiment and Calculations" Chem. Phys. Lett. 1991, 179, 282.

46. Chickos, J. S.; Hesse, D. G.; Panshin, S. Y.; Rogers, D. W.; Saunders, M.; Uffer, P. M.; Liebman, J. F. "Is the Strain Energy of Cyclotetradecane as Large as One Thinks," J. Org. Chem. 1992, 57, 1897.

47. Malon, P.; Mickley, L. J.; Keiderling, T. A.; Uang, J.-Y.; Kamath, S.; Chickos, J. S. "Vibrational Circular Dichroism Study of [2S,3S]-dideuteriobutyrolactone. Synthesis, Characterization and Comparison of Experimental and Calculated Spectra." J. Phys. Chem.1992, 96, 10139.

48. Chickos, J. S.; Hesse, D. G.; Liebman, J. F. "A Group Additivity Approach for the Estimation of Heat Capacities of Organic Liquids and Solids" J. Structural Chem. 1993, 4, 271.

49. Chickos, J. S.; Hosseini, S.; Hesse, D. G.; Liebman, J. F. "Heat Capacity Corrections to a Standard State. A Comparison of Available Methods for Organic Liquids and Solids" J. Structural Chem. 1993, 4, 279.

50. Chickos, J. S.; Hosseini, S. ; Liebman J. F. "A Group Additivity Approach for the Estimation of Vapor Pressures of Liquid Hydrocarbons from 298 to 500 K", J. Org. Chem. 1993, 58, 5345.

51. Sternberg, M. J. E.; Chickos, J. S. "Comparison of Empirical Scale for Estimating Side-Chain Conformational Entropy in Protein Folding", Protein Engineering 1994, 7, 149.

52. "Determination of Vaporization Enthalpies of Simple Organic Molecules by Correlations of Changes in Gas

Chromatographic Net Retention Times", Chickos, J. S.; Hosseini, S.; Hesse, D. G.; Thermochimica Acta 1995, 249, 41.

53. "The enthalpies of formation of iodoethane, 1,2-diiodoethane, 1,3-diiodopropane and 1,4-diiodobutane",

Carson, A. S.; Laye, P. G.; Pedley, J. B.; Welsby, A. M.; Chickos, J. S.; Hosseini, S. J. Chem. Thermodyn. 1994, 26, 1103.

54. "Interrelationships between structure, intermolecular interaction factors and solubility of polyaromatic

hydrocarbons. Toluene solubitiy of polyphenyls." Gagarin, S. Chickos, J. S. Koks i himija 1995, (1), 18-22.

(Coke and Chemistry (English Translation) 1995, 1, 30, Allerton Press, Inc., N. Y.

55. Sternberg, M. J. E.; Chickos, J. S. "A Test of Small Molecule Group Parameters in the Estimation of Fusion Entropies of Macromolecules", Thermochimica Acta 1995, 263, 13.

56. Shaharuzzaman, M.; Chickos, J. S.; Tam, C. N.; Keiderling, T. A. " A convenient synthesis of chiral succinic acid-d2 by catalytic reduction using a ruthenium BINAP catalyst", Tetrahedron: Asymmetry 1995, 6, 2929.

57. Gagarin, S. Chickos, J. S. "Relationships between structure, intermolecular interaction factors and solubility of aromatic compounds. Solubility of Polyphenyls in Toluene,” Coke and Chemistry 1995, (1), 18-22 (English Translation) Allerton Press.

58. Gagarin, S. Chickos, J. S. "Interrelationships between structure, intermolecular interaction factors and solubility of polyaromatic hydrocarbons. The Solubility of Methyl-Substituted Polyphenyls in Toluene,”

Coke and Chemistry 1995, (2), 27-33 (English Translation) Allerton Press.

59. Gagarin, S. G.; Chickos, J. S. “The Relationship between Structure, Intermolecular Interaction Factors and Solubility of Aromatic Compounds, The Solubility of Phenanthrene Derivatives in Toluene,” Coke and Chemistry 1995, 5 24-30.

60. Chickos, J. S.; Hesse, D. G.; Hosseini, S.; Liebman, J. F.; Mendenhall, G. D.; Verevkin, S. P.; Rakus, K.; Beckhaus, H. -D.; Ruchardt, C. "Enthalpies of vaporization of some highly branched hydrocarbons", an invited paper honoring the retirement of Jeffrey Pilcher , J. Chem. Thermodyn. 1995 27, 693-705.

61. "Enthalpies of sublimation and formation of polycyclic aromatic hydrocarbons derived from conformational

force field analysis", Welsh, W. J.; Tong, W.; Collantes, E. R.; Chickos, J. S.; Gargarin, S. G. Thermochimica

Acta 1996, 290, 55-64.

62. Chickos, J. S.; Sabbah, R.; Hosseini, S.; Liebman, J. F.; "The Sublimation Enthalpy of Dimethyl Oxalate", Structural Chemistry 1996, 7, 391.

63. Riberio da Silva, M. A. V.; Riberio da Silva, M. D. A. C.; Monteiro, M. F. B. M.; Gomes, M. L. A. C.; Chickos, J. S.; Smith, A.; Liebman, J. F., "Thermochemical Studies for Determination of Molar Enthalpy of Formation of Aniline Derivatives”, Structural Chemistry 1996, 7, 367.

64. "Enthalpy of Formation of Triphenylphosphine Sulfide", Kirklin, D. R.; Chickos, J. S.; Liebman, J. F. Structural Chemistry 1996, 7, 355.

65. “Vibrational Optical Activity Study of trans-Succinic-d2 Anhydride”, Bour, P.; Tam, C. N.; Shaharuzzaman,

Chickos, J. S.; Keiderling, T. A.; J. Phys. Chem. 1996, 100, 15041.

66 Chickos, J. S.; Wilson, J. A.;"The Vaporization Enthalpies of the n-Alkanes from C21-C28 and C30", J. Chem.

Eng.Data 1997, 42, 190-197.

67.“A Protocol for Correcting Experimental Fusion Enthalpies to 298 K and Its Application in Indirect

Measurements of Sublimation Enthalpy at 298 K”, Chickos, J. S Thermochim. Acta 1998, 313, 19-26

68. "Sublimation enthalpies at 298.15 K using correlation gas chromatography and differential scanning calorimetry measurements", Chickos, J. S.“Hesse, D.; Hosseini, S.; Nichols, G.; Webb, P. Thermochim. Acta 1998, 313, 101-110.

69. “The Regiochemistry of Reduction of Mono-Ethyl Fumarate and Maleate Using A Ruthenium BINAP Catalyst”, Shaharuzzaman, M.; Braddock-Wilking, J.; Chickos, J. S.; Tam, C. N.; Silva, R. A. G. D.; Keiderling, T. K.

Tetrahedron Asymmetry 1998, 9, 1111-4 .

70. “Estimating Solid-Liquid Phase Change Entropies and Enthalpies,” Chickos, J. S.; Acree, Jr.; W.; Liebman, J. F.

J. Chem. Phys. Ref. Data. 1999, 28, 1535-1673.

71. "The vaporization enthalpies of some crown ethers by correlation gas-chromatography", Nichols, G. Orf, J.;

Reiter, S.; Chickos, J. S.; Gokel, G. W. Thermochimica Acta 2000, 346, 15-28.

72. "A thermochemical and theoretical study of the phenylpyridine isomers," Ribeiro da Silva, M. A. V.; Matos, M.

A. R.; Rio, C. A.; Morais, V. M. F.; Wang, J.; Nichols, G.; Chickos, J. S. J. Phys. Chem. 2000, 104, 1774-1778.

73. "Structural characterization of crystalline inclusion complexes formed from 1,3,5-triaroylbenzene derivatives-a

new family of inclusion hosts." Pigge, F. C.; Ghasedi, F.; Zheng, Z.; Rath, N. P.; Nichols, G.; Chickos. J.

J. Chem. Soc. Perkin 2, 2000, 2458-2464.

74. Chickos, J. S.; Nichols, G; "Simple Relationships for the Estimation of Melting Temperatures of Homologous

Series", J. Chem. Eng. Data 2001, 46, 562-573.

75. "Chemical Modification of Cellulose. The Possible Effects of Chemical Cleaning on Fatty Acids Incorporated

in Old Textiles," . Chickos, J. S.; Uang, J. Approfondimento Sindone, 2001, 0000.

76. Determination of Vaporization Enthalpies of Polychlorinated Biphenyls by Correlation Gas Chromatography",

Puri, S.; Chickos, J. S.; Welsh, W. Anal. Chem. 2001, 73, 1480-4.

77. "Integrated comutational and experimental investigation of the thermodynamic properties of polychlorinated

biphenyls", Puri, S.; Welsh, W.; Chickos, J. S. Hazard. Ind. Wastes 2001, 33, 185-192.

78. "Three-Dimensional Quantitative Structure-Property Relationship (3D-QSPR) Models for Prediction of

Thermodynamic Properties of Polychlorinated Biphenyls (PCBs): Enthalpy of Vaporization," Puri, S.; Chickos,

J. S.; Welsh, W. J.,J. Chem. Inf. Computer Sci. 2002, 42, 299-304.

79. "Three-Dimensional Quantitative Structure-Property Relationship (3D-QSPR) Models for Prediction of

Thermodynamic Properties of Polychlorinated Biphenyls (PCBs): Enthalpy of Sublimation," Puri, S.; Chickos, J.

S.; Welsh, W. J.,J. Chem. Inf. Computer Sci. 2002, 42, 106-116.

80. "The Estimation of Melting Points and Fusion Enthalpies Using Experimental Solubilities, Estimated Total Phase

Change Entropies and Mobile Order Theory," Chickos, J. S.; Nichols, G.; Ruelle, P. J. Chem. Inf. Computer Sci.

2002, 42, 368-374.

81. "A Stable Isotope Dilution GC-MS Method for Analysis of 3-Hydroxydodecanedioic Acid for Studies of Fatty

Acid Metabolic Disorders", Chickos, J. S.; Way, B. A.; Wilson, J.; Shaharazzuman, M.; Laird, J.; Landt, M. J. of

Clinical Lab.Anal. 2002, 16, 115 -120.

82. "Enthalpies of Sublimation of Organic and Organometallic Compounds, 1910-2001", Chickos, J. S.; Acree Jr.;

W. E. J. Phys. Chem. Ref. Data 2002, 31, 537-698.

83. "The enthalpy of vaporization and sublimation of corannulene, coronene, and perylene at T = 298.15 K",

Chickos, J. S.; Webb, P.; Nichols, G.; Kiyobayashi, T.; Cheng, P.-C.; Scott, L. J. Chem. Thermodyn. 2002, 34,

1195-1206.

84. The enthalpy of vaporization and sublimation of exo- and endo-tetrahydrodicyclopentadienes at

T = 298.15 K , Chickos, J. S.;Hillesheim, D.; Nichols, G.; Zehe, M. J. Chem Thermodyn. 2002, 34, 1647-

1658.

85. “Total Phase Change Entropies and Enthalpies. An update on Their Estimation and Applications to

the Estimations of Amphiphillic Fluorocarbon-hydrocarbon Molecules.,” Chickos, J. S.; Acree, Jr.; W. E.

Thermochim. Acta. 2003, 395. 59-113.

86. "Three Dimensional Quantitative Structure-Property Relationships (3DQSPR) Models or Prediction of

Thermochemical Properties of Polychlorinatined Biphenyls (PCBs): Enthalpies of Fusion and Their Application

to Estimates of Sublimation and Aqueous Solubilities", Puri, S.; Chickos, J. S.; Welsh, W. J. J. Chem. Inf.

Comput. Sci.2003, 43, 4355-62.

87. "Enthalpies of Vaporization of Organic and Organometallic Compounds, 1880-2002', Chickos, J. S.; Acree, Jr. W. E. J. Phys Chem. Ref Data 2003, 32, 515-878.

88. "Measurement of the Vaporization Enthalpy of Complex Mixtures by Correlation-Gas Chromatography. The

Vaporization Enthalpy of RJ-4, a High-Energy Density Rocket Fuel at T = 298.15K", Chickos, J. S.; Wentz,

A. E.;Hillesheim-Cox, D. Zehe, M. J. Industrial and Engineering Chemistry 2003, 42, 2874-2877.

89. The Enthalpies of Formation of Two Dibenzocyclooctadienones," St. Perisanu, St. Contineanu, J.; Banciu,

M. D.; Liebman, J. F.; Farivar, B. S.; . Mullan, M. A.; Chickos, J. S.; Rath, N.; Hillesheim, D. M.

Thermochim. Acta 2003, 400, 109-120.

90. "The energetics of the isomeric 1- and 2-naphthoic acids: context, quantum mechanical calculations and

thermochemical measurements", Chickos, J. S.; Hillesheim, D. M.; Verevkin, S. P.; Roux, M. V.; Temprado,

M.; Segura, M.; Notario, R.; Demasters, D. E.; Liebman, J. F. Molecular Physics 2003, 101, 1311-1318.

91. "Heat capacities of thiane sulfones and thiane sulfoxide. Refining of Cp group values for organosulfur

compounds and their oxides." Temprado, M.; Roux, M. V.; Jiménez, P.; Guzmán-Mejía, R.; Juaristi, U.;

Chickos, J. S. Thermochim. Acta, 2003, 406, 9-16

Invited Contributions

92. Chickos J. S. "Heats of Sublimation" Chapter 2, in Molecular Structure and Energetics, Physical Measurements Liebman J. F. and Greenberg A.; Editors; VCH Publishers, Inc; New York, 1987; Vol. 2, pp. 67-150.

93. Liebman, J. F.; Chickos, J. S.; Simons, J. "Aspects of the Estimation of Physical Properties of Boron Compounds by the Use of Isoelectronic and Plemeioelectronic Analogies". in Advances in Boron and the Boranes: A volume in honor of Anton B. Burg, Liebman, J.F.; Greenberg, A. Williams, R. E. Editors.; VCH Publishers Inc.: New York, 1988; 491.

94. Chickos, J. S.; Hesse. D. G.; Liebman, J. F.; "Estimating Enthalpies of Sublimation of Hydrocarbons", in Energetics of Organometallic Species, Simoes, M. edit., Kluwer Academic Publishers, Dordrecht: the Netherlands, 1992, pp 159-170.

95. Chickos, J. S.; Acree, Jr. W. Liebman, J. F. “Estimating Phase Change Entropies and Enthalpies”’, Frurip, D.; Irikura, K. (Ed.) ACS Symposium Series 677 Computational Thermochemistry, Prediction and Estimation of Molecular Thermodynamics, ACS: Washington DC, 1998, pp 63-93.

96. Chickos, J. S.; Nichols, G.; Wilson, J.; Orf, J.; Webb, P.; Wang, J. A Protocol for Deriving Values for

DfusHm(298.15 K) and DHm(298.15 K). Applications in Obtaining DsubHm (298.15 K), in Energetics of Stable

Molecules and Reactive Intermediates, Minas da Piedade, M. edit., Kluwer Academic Publishers, Dordrecht:

the Netherlands, 1999, 177-202.

97. Sabbah, R.; Xu-wu, A. Chickos, J. S.; Planas Leitao, M. L.; Roux, M. V.; Torres, L. A. "Reference materials

for calorimetry and differential scanning calorimetry," Thermochimica Acta 1999, 331, 93-204.

98. Chickos, J. S.; "Enthalpies of sublimation after a century of measurement: A view as seen through the eyes of

a collector" Netsu Sokutei 2003, 30, 116-124.

In Press

99. "Vapor pressures and vaporization enthalpies of the n-alkanes from C21-C30 at T = 298.15 by correlation-

gas chromatography, Chickos, J. S.; Hanshaw, W. J. Chem. Eng. Data 2003

Submitted

100. "Hypothetical thermodynamic properties: the boiling and critical temperatures of polyethylene and

polytetrafluoroethylene", Chickos, J. S. J. Chem. Eng. Data.

101. "Vapor pressures and vaporization enthalpies of the n-alkanes from C31-C38 at T = 298.15 by correlation-

gas chromatography, Chickos, J. S.; Hanshaw, W. J. Chem. Eng. Data.

Web Based Materials

1. A compendium of sublimation enthalpies compiled at U. M. St. Louis is currently available at the National Institute of Standards and Technology located at the following address: “webbook.chemistry/”

2. A similar compendium of vaporization enthalpies will be available soon at the same address

3. An interactive instructional text co-authored by Chickos, D’Souza and Garin is available at “umsl.edu/~orglab”

Text Books

1. "Chemistry Its Role in Society", D.C. Heath and Co., March l973, Chickos, J. S.; Garin, D. L.; Rouse, R. . Reviewed in J. Chem. Ed., 1974, 5l (6) A 343 .

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