List of publications by C Eaborn et. al on compounds ...



List of publications by C Eaborn et. al on compounds containing the trisyl and related ligands.

1 A. R. Bassindale, C. Eaborn, D. R. M. Walton, and D. J. Young .The electron-releasing effects of mono-, bis-, and tris-(trimethylsilyl)methyl groups. The importance of hyperconjugation in the electronic effects of (-metalloalkyl groups. J. Organomet. Chem., 1969, 20, 49-56.

2 A. R. Bassindale, A. J. Bowles, M. A. Cook, C. Eaborn, A. Hudson, R. A. Jackson, and A. E. Jukes .Tris(trimethylsilyl)methyl - a relatively stable saturated organic radical. J. Chem Soc., Chem., Chem. Commun., 1970, 559.

3 A. R. Bassindale, C. Eaborn, and D. R. M. Walton. Electronic effects of mono-, bis-, and tris-(trimethylsilyl)methyl groups. The 19F nuclear magnetic resonance spectra of m- and p-[(Me3Si)xCH(3-x)]C6H4F compounds (x = 0-3). J. Organomet. Chem., 1970, 21, 91-94.

4 M. A. Cook, C. Eaborn, and D. R. M. Walton .Organosilicon compounds. Part XLVII. The substituent effects and leaving group abilities of mono-, bis-, and tris-(trimethylsilyl)silyl groups in electrophilic aromatic substitution. J. Organomet. Chem., 1970, 23, 85-90.

5 M. A. Cook, C. Eaborn, and D. R. M. Walton. Substituent effects of mono-, bis-, and tris(trimethylsilyl)methyl groups: determination of (- and (+-constants. J. Organomet. Chem., 1970, 24, 293-299.

6 M. A. Cook, C. Eaborn, and D. R. M. Walton. The mechanism of solvolysis of (2-bromoethyl)trimethylsilane. Evidence for the migration of the trimethylsilyl group .J. Organomet. Chem., 1970, 24, 301-306.

7 M. A. Cook, C. Eaborn, A. E. Jukes, and D. R. M. Walton. [Tris(trimethylsilyl)methyl]lithium: an alkyllithium compound of unusual stability. J. Organomet. Chem., 1970, 24, 529-535.

8 C. Eaborn, D. A. R. Happer, S. P. Hopper, and S. D. Safa. Novel rearrangements in reactions of tris(trimethylsilyl)methylsilicon iodides and hydrides with electrophilic reagents, and the possibility of cationic intermediates. J. Organomet. Chem., 1979, 170, C9-C12.

9 C. Eaborn and S. P. Hopper. Anchimeric assistance in solvolysis of an organosilicon chloride and acetate. J. Organomet. Chem., 1979, 170, C51-C52.

10 S. S. Dua, C. Eaborn, D. A. R. Happer, S. P. Hopper, K. D. Safa, and D. R. M. Walton. Preparation of tris(trimethylsilyl)methyl ("trisyl") derivatives of silicon. J. Organomet. Chem., 1979, 178, 75-82.

11 C. Eaborn, D. A. R. Happer, P. B. Hitchcock, S. P. Hopper, K. D. Safa, S. S. Washburne, and D. R. M. Walton. Thermolysis of [tris(trimethylsilyl)methyl](diphenyl)fluorosilane. Isomerization of a sila-olefin intermediate. J. Organomet. Chem., 1980, 186, 309-323.

12 C. Eaborn, D. A. R. Happer, S. P. Hopper, and K .D. Safa. The reactions of [tris(trimethylsilyl)methyl]silicon halides and hydrides with electrophilic reagents. J. Organomet. Chem., 1980, 188, 179-192.

13 C. Eaborn, N. Retta, and J. D. Smith. Di[tris(trimethylsilyl)methyl]-zinc and -cadmium. J. Organomet. Chem., 1980, 190, 101-106.

14 C. Eaborn, D. A. R. Happer, and K. D. Safa. Reaction of tris(trimethylsilyl)methylsilicon halides with methanolic sodium methoxide. Probability of sila-olefin intermediates. J. Organomet. Chem., 1980, 191, 355-362.

15 C. Eaborn and S. P. Hopper. The reactions of tris(trimethylsilyl)silicon iodides and hydrides with iodine monochloride. J. Organomet. Chem., 1980, 192, 27-32.

16 S. S. Dua, C. Eaborn, and F. M. S. Mahmoud. A unimolecular solvolysis of an organosilicon perchlorate. J. Organomet. Chem., 1980, 192, 293-295.

17 C. Eaborn and N. P. Y. Siew. Tris(trimethylsilyl)methyl germanium halides. J. Organomet. Chem., 1980, 202, 157-162.

18 S. S. Dua and C. Eaborn. Sterically-hindered organosilicon perchlorates. J. Organomet. Chem., 1981, 204, 21-26.

19 C. Eaborn and K. D. Safa. Pyrolysis of the "trisyl" compounds (Me3Si)3CSiPh2I and (Me3Si)3CSiPhMeI. J. Organomet. Chem., 1981, 204, 169-179.

20 C. Eaborn and F. M. S. Mahmoud. Rate-determining ionization in methanolysis of an organosilicon halide. J. Chem. Soc.,, Chem. Commun., 1981, 63-64.

21 C. Eaborn, K. D. Safa, A. Ritter, and W. Binder. Photo-induced reactions of an organosilicon iodide. J. Chem. Soc.,, Chem. Commun., 1981, 175-176.

22 B. Beagley, R. G. Pritchard, C. Eaborn, and S. S. Washburne. A gas-phase electron diffraction study of tris(trimethylsilyl)methane. A C-H bond of high p-character. J. Chem. Soc.,, Chem. Commun., 1981, 710-711.

23 C. Eaborn and F. M. S. Mahmoud. Unimolecular solvolysis of some organosilicon perchlorates and iodides. J. Chem. Soc., Perkin Trans.2, 1981, 1309-1315.

24 C. Eaborn and F. M. S. Mahmoud. Some properties of the sterically-hindered aminosilane (Me3Si)3CSiMe2NH2. J. Organomet. Chem., 1981, 220, 139-143.

25 C. Eaborn, P. B. Hitchcock and P. D. Lickiss. The molecular structure of [dimethyl(phenyl)silyl]tris(trimethylsilyl)methane. J. Organomet. Chem., 1981, 221, 13-17.

26 C. Eaborn, P. B. Hitchcock and K. D. Safa. An unusual bicyclic tetrasiloxane. J. Organomet. Chem., 1981, 222, 187-194.

27 S. A. I. Al-Shali, C. Eaborn, and F. M. S. Mahmoud. The SN1 methanolysis of a tertiary organosilicon iodide, (Me3Si)3CSiMe2I. J. Organomet. Chem., 1982, 232, 215-218.

28 C. Eaborn and K. D. Safa. Some highly sterically hindered organo-silanols and -siloxanes. J. Organomet. Chem., 1982, 234, 7-14.

29 C. Eaborn, N. Retta, J. D. Smith, and P. B. Hitchcock. The preparation and molecular structure of the highly sterically hindered tris(trimethylsilyl)methylboron compound (Me3Si)3CB(Ph)[O(CH2)4C(SiMe3)3]. J. Organomet. Chem., 1982, 235, 265-271.

30 C. Eaborn, K. D. Safa, A. Ritter, and W. Binder. Photoinduced ionic and free-radical reactions of some organosilicon iodides. J. Chem. Soc., Perkin Trans. 2, 1982, 1397-1401.

31 C. Eaborn. Novel properties of some highly sterically hindered organosilicon compounds. J. Organomet. Chem., 1982, 239, 93-103.

32 C. Eaborn, P. D. Lickiss, G. Marquina-Chidsey, and E. Y. Thorli. (Dimethyl)[tris(trimethylsilyl)methyl]silyl cyanate and related species: the first silicon cyanate. J. Chem. Soc.,, Chem. Commun., 1982, 1326.

33 R. Damrauer, C. Eaborn, D. A. R. Happer and A. I. Mansour. A novel 1,3-migration of a silyl group from carbon to oxygen in a silanolate ion. J. Chem. Soc., Chem. Commun., 1983, 348.

34 S. A. I. Al-Shali and C. Eaborn. Bimolecular displacements of iodine in reactions of dimethyl[tris(trimethylsilyl)methyl]silyl iodide with salts. J. Organomet. Chem., 1983, 246, C34-36.

35 C. Eaborn, N. Retta, and J. D. Smith. Some [tris(trimethylsilyl)-methyl]phosphorus derivatives. J. Chem. Soc., Dalton Trans., 1983, 905-909.

36 C. Eaborn, N. M. El-Kheli, N. Retta, and J. D. Smith. Some tris(trimethylsilyl)methyl derivatives of boron, aluminium and gallium. J. Organomet. Chem., 1983, 249, 23-31.

37 Z. Aiube, J. Chojnowski, C. Eaborn, and W. A. Stanczyk. Internal nucleophilic displacements within silanolate ions. A new mechanism of substitution at silicon. J. Chem. Soc.,, Chem. Commun., 1983, 493-495.

38 C. Eaborn and D. E. Reed. Anchimeric assistance in methanolysis of some organosilicon halides, perchlorates, and trifluoromethanesulphates. J. Chem. Soc.,, Chem. Commun., 1983, 495-496.

39 C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. Some derivatives of tris(dimethylsilyl)methane. A novel bicyclic tris(disiloxane) with a manxane structure. J. Organomet. Chem., 1983, 252, 281-288.

40 C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. Crystal structure of the tetrahydrofuran adduct of tris(trimethylsilyl)methyl-lithium, [Li(thf)4][Li{C(SiMe3)}2], an ate derivative of lithium. J. Chem. Soc.,, Chem. Commun., 1983, 827-828.

41 A. I. Al-Wassil, C. Eaborn, and A. K. Saxena. Oxidatively assisted nucleophilic substitution of organosilicon iodides. J. Chem. Soc.,, Chem. Commun., 1983, 974-975.

42 C. Eaborn and A. I. Mansour. Reactions of some sterically-hindered organosilicon hydrides and iodides with halogens. J. Organomet. Chem., 1983, 254, 273-282.

43 C. Eaborn, Y. Y. El-Kaddar, and P. D. Lickiss. [Tris(trimethylsilyl)methyl]-(dimethyl)silyl cyanate. The cyanate to isocyanate isomerization, and the high activity of cyanate as a leaving group in solvolysis. J. Chem. Soc.,, Chem. Commun., 1983, 1450-1451.

44 C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. A novel monomeric alkyl-lithium compound. Crystal structure of [Li{C(SiMe2Ph)3}(tetrahydrofuran)].

J. Chem. Soc., Chem. Commun., 1983, 1390-1391.

45 C. Eaborn, P. D. Lickiss, and N. A. Ramadan. Cleavages of silicon-carbon bonds in tris(trimethylsilyl)methylsilicon compounds by trifluoroacetic acid. Rearrangements and anchimeric assistance.J. Chem. Soc., Perkin 2, 1984, 267-270.

46 A. I. Al-Wassil, C. Eaborn, A. Hudson, and R. A. Jackson. An electron spin resonance study of some silicon-centred free radicals with a tris(trimethylsilyl)methyl substituent. J. Organomet. Chem. 1983, 258, 271-275.

47 .S. A. I. Al-Shali, C. Eaborn, F. A. Fattah, and S. T. Najim. An SN2 (intermediate) mechanism for solvolysis of organosilicon iodides. J. Chem. Soc., Chem. Commun., 1984, 318-319.

48 C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. Preparation and crystal structure of the tetrahydrofuran adduct of lithium bis[tris(trimethylsilyl)methyl]cuprate, [Li(THF)4][Cu{C(SiMe3)3}2].The first structural characterization of a Gilman reagent. J. Organomet. Chem. 1984, 263, C23-C25.

49 C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. Tetrakis(hydroxymethylsilyl)methane and its dehydration with rearrangement. Crystal structure of 2,2,4,4,6,6-hexamethyl-5-hydroxydimethylsilyl)1,3-dioxa-2,4,6-trisilacyclohexane. J. Organomet. Chem. 1984, 264, 119-126.

50 Z. H. Aiube and C. Eaborn. Improvements in the preparation and use of [tris(trimethylsilyl)methyl]lithium. J. Organomet. Chem. 1984, 269, 217-218.

51 C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. The crystal structure of tris(phenyldimethylsilyl)methane. J. Organomet. Chem. 1984, 269, 235-238.

52 C. Eaborn and A. K. Saxena. Comparisons of the reactivities of the tri-t-butyl- and tris(trimethylsilyl)methyl-silicon compounds. J. Organomet. Chem. 1984, 271, 33-46.

53 C. Eaborn, M. N. A. El-Kheli, P. B. Hitchcock, and J. D. Smith. Preparation and crystal structure of [tris(trimethylsilyl)methyl]diphenylborane. J. Organomet. Chem. 1984, 272, 1-9.

54 C. Eaborn, P. B. Hitchcock, P. D. Lickiss, A. Pidcock, and K. D. Safa. Crystal stucture and variable-temperature hydrogen-1 nuclear magnetic resonance spectrum of (dimethylnitratosilyl)[methyldiphenylsilyl]bis(trimethylsilyl)methane, C(SiMe3)2(SiMePh2)(SiMe2ONO2).J. Chem. Soc., Dalton Trans., 1984, 2015-2017.

55 C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. Preparation and crystal structure of the argentate complex [Li(tetrahydrofuran)4][Ag{C(SiMe3)3}2]. J. Chem. Soc., Chem. Commun., 1984, 870-871.

5 C. Eaborn and A. K. Saxena. .1,3-methyl migration from germanium to silicon in reactions of (Me3Si)2(Me3Ge)C(SiMe2Br) with silver salts. J. Chem. Soc., Chem. Commun., 1984, 1482-1483.

57 C. Eaborn and M. N. Romanelli. The first silicon thiocyanate. J. Chem. Soc., Chem. Commun., 1984, 1616-1617.

58 .C. Eaborn, M. N. A. El-Kheli, P. B. Hitchcock, and J. D. Smith. The crystal structure of the alkyltrihydroborate (thf)3Li(µ-H)3BC(SiMe2Ph)3. (thf = tetrahydrofuran). J. Chem. Soc., Chem. Commun., 1984, 1673-1674.

59 R. I. Damja, C. Eaborn, and A. K. Saxena. Acyl-oxygen fission in reactions of organosilicon carboxylates with sodium methoxide in methanol. J. Chem. Soc., Perkin 2, 1985, 597-598.

60 C. Eaborn and A. I. Mansour. Reactions of silicon centres bearing the bulky tris(phenyldimethylsilyl)methyl ligand. J. Chem. Soc., Perkin 2, 1985, 729-735,

61 C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. Novel anionic cages from 'alkylmanganese chloride' and 'alkylcobalt chloride' solutions. Crystal and molecular structure of [Li(thf)4][{(Me3Si)3C}3Mn3Cl4(thf)] (thf - tetrahydrofuran). J. Chem. Soc., Chem. Commun., 1985, 534-535.

62 C. Eaborn. .Highly sterically hindered organosilicon compounds, in ‘Organosilicon and Bioorganosilicon Chemistry’. (ed. H. Sakurai). Ellis Horwood. Chichester. 1985, 123-130.

63 R. I. Damja and C. Eaborn. Preparation and reactions of some sterically hindered silanols, including [tris(trimethylsilyl)methyl]silanetriol. J. Organomet. Chem. 1985, 290, 267-275.

64 R. I. Damja, C. Eaborn, and W.-C. Sham. .Reactions of (Me3Si)3CSiMe2R compounds (R = CH=CH2, CH2CH=CH2, C(CPh, Ph, and CH2Ph) with electrophiles. J. Organomet. Chem. 1985, 291, 25-33.

65 Z. H. Aiube, N. H. Buttrus, C. Eaborn, P. B. Hitchcock, and J. A. Zora. .The preparation and crystal structures of [(Me3Si)3C]PhSi(OH)2 and [(Me3Si)3PhSi(OMe)OH. J. Organomet. Chem. 1985, 292, 177-188.

66 C. Eaborn and D. E. Reed. Preparation and reactions of difunctional sterically hindered organosilicon compounds of the type (Me3Si)2C(SiMe2X)(SiMe2Y). J. Chem. Soc., Perkin Trans. 2, 1985, 1687-1693.

67 C. Eaborn and D. E. Reed. Absence of rearrangement in reactions of the compounds (Me3Si)3CSiMe(OMe)I, (Me3Si)3CSi(OMe)2I with electrophilic reagents. J. Chem. Soc., Perkin Trans. 2, 1985, 1695-1697.

68 J. L. Atwood, S. G. Bott, C. Eaborn, M. N. A. El-Kheli, and J. D. Smith. The crystal and molecular structure of fluoro(hydroxy){tris-(dimethylphenylsilyl)methyl}borane. J. Organomet. Chem. 1985, 294, 23-30.

69 C. Eaborn and P. D. Lickiss. Some tetrasilylmethane derivatives. J. Organomet. Chem. 1985, 294, 305-313.

70 N. H. Buttrus, C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. Preparation and crystal structure of a two-coordinate manganese compound, bis[tris(trimethyl)silylmethyl]manganese. J. Chem. Soc., Chem. Commun., 1985, 1380-1381.

71 N. H. Buttrus, R. I. Damja, C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. The crystal structure of [tris(trimethylsilyl)methyl]silanetriol. A novel and remarkably stable hydrogen-bonded cage structure. J. Chem. Soc., Chem. Commun., 1985, 1385-1386.

72 C. Eaborn, P. D. Lickiss, S. T. Najim, and M. N. Romanelli. Unimolecular alcoholysis of organosilicon halides of the type (Me3Si)2C(SiMe2OMe)(SiR'2X). Anchimeric assistance by and migration of the OMe group. J. Chem. Soc., Chem. Commun., 1985, 1754-1755.

73 G. A. Ayoko and C. Eaborn. Neighbouring group participation by the vinyl group in reactions of sterically-hindered organosilicon compounds. J. Chem. Soc., Chem. Commun., 1986, 630-631.

74 A. G. Avent, C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. An electron-deficient indium hydride. Crystal structure and N.M.R. spectrum of (Me3Si)3CIn(H)(µ-H)In(µ-H)(H)C(SiMe3)3 (thf = tetrahydrofuran). J. Chem. Soc., Chem. Commun., 1986, 988-989.

75 N. H. Buttrus, C. Eaborn, S. H. Gupta, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. Preparation and crystal structure of the novel internally solvated dimeric organolithium compound [{LiC(SiMe2OMe)3}2]. J. Chem. Soc., Chem. Commun., 1986, 1043-1044.

76 N. H. Buttrus, C. Eaborn, P. B. Hitchcock, J. D. Smith, J. G. Stamper, and A. C. Sullivan. The crystal structure of [(pmdeta)Li(µ-Cl)Li(pmdeta)][Li{C(SiMe3)3}2] {pmdeta = Me2N(CH2)2NMe(CH2)2NMe2}. A novel linear chlorine-centred cation. J. Chem. Soc., Chem. Commun., 1986, 969-970.

77 S. Al-Juaid, N. H. Buttrus, C. Eaborn, P. B. Hitchcock, T. L. Roberts, J. D. Smith, and A. C. Sullivan. Novel alkylmetal hydroxides. The crystal and molecular structures of bis(µ-hydroxy)bis{tris(dimethyl-phenylsilyl)methylzinc}, [{Me2PhSi)3CZnOH}2], and µ4-oxohexa(µ-hydroxy) tetrakis{tris(trimethylsilyl)methylindium}, [O{Me3Si)3CIn}4(OH)6. J. Chem. Soc., Chem. Commun., 1986, 908-909.

78 N. H. Buttrus, C. Eaborn, P. B. Hitchcock, P. D. Lickiss, and A. D. Taylor. Hydrogen bonding in organosilicon hydroxides: crystal structures of dichlorohexylsilanediol and bis(hydroxydimethylsilyl)bis(trimethylsilyl)methane. J. Organomet. Chem. 1986, 309, 25-33.

79 G. A. Ayoko and C. Eaborn. The effects of the vinyl groups in reactions of the highly sterically hindered compound [tris(trimethylsilyl)methyl]divinylsilyl chloride. J. Chem. Soc., Perkin Trans. 2, 1986, 1289-1293.

80 G. A. Ayoko and C. Eaborn. Silicon-oxygen and acyl-oxygen bond cleavage in reactions of sterically hindered organosilicon carboxylates. J. Chem. Soc., Perkin Trans. 2, 1986, 1357-1361.

81 A.G. Avent, C. Eaborn, M.N.A. El-Kheli, M.E., Molla, J.D. Smith, and A.C. Sullivan. Utilization of the 6Li{1H} nuclear Overhauser effect. The structures of hydro[tris(trimethylsilyl)methyl]-metallates of boron, aluminium, and indium in solution. J. Am. Chem. Soc., 1986, 108, 3584-3585.

82 A.I. Al-Wasssil, C. Eaborn, and M.N. Romanelli. Peparation and some reactions of compounds of the type (Me3Si)2C(SiMe2OMe)(SiMe2X). Anchimeric assistance by the methoxy group. J. Chem. Soc., Perkin Trans. 2, 1986, 1363-1365

83 C. Eaborn, P.D. Lickiss, S.T. Najim, and M.N. Romanelli. 1,3-Migration of chloride and azide substituents within organosilicon cations, and anchimeric assistance by the azido group. J. Organomet. Chem. 1986, 315, C5-C8.

84 G.A. Ayoko and C. Eaborn. Preparation and some reactions of the compounds HgVsi2, CdVsi2, and Hg(Vsi)Br [Vsi = (Me3Si)2(CH2=CHMe2Si)C]. J. Chem. Soc., Perkin Trans. 2, 1987, 381-383.

85 G.A. Ayoko and C. Eaborn. Reactions of bis[dimethyl(vinyl)silyl]bis(trimethylsilyl)-methane, (Me3Si)2(SiMe2CH=CH2)2. J. Chem. Soc., Perkin Trans. 2, 1987, 657-662.

86 C. Eaborn and M.N. Romanelli. Anchimeric assistance by the methoxy group in solvolysis of the compounds (Me3Si)2C(SiMe2OMe)-(SiMe2X). J. Chem. Soc., Perkin Trans. 2, 1987, 657-662.

87 S.A. Al-Juaid, S.M. Dhaher, C. Eaborn, P.B. Hitchcock, and J.D. Smith. Preparation and crystal structures of the crowded organotin fluorides (PhMe2Si)3CSnMe2F, (Me3Si)3CSiMe2F, and (Me3Si)3CSnPh2F. J. Organomet. Chem. 1987, 325, 117-127.

88 C. Eaborn and A.K. Saxena. 1,3-Migration of a methyl group from germanium to silicon in reactions of (Me3Si)2C(GeMe3)(SiMe2Br) with silver salts. J. Chem. Soc., Perkin Trans. 2, 1987, 779-782.

89 C. Eaborn and A.K. Saxena. The effect of the _(-OMe group on the reactivity of the germanium chloride (Me3Si)2C(SiMe2OMe)(GeMe2Cl). J. Chem. Soc., Perkin Trans. 2, 1987, 775-778.

90 N.H. Buttrus, C. Eaborn, P.B. Hitchcock, P.D. Lickiss, and S.T. Najim. Migration of the methoxy group in an organosilicon cation. Reactions of (bromodiphenylsilyl)-(methoxydimethylsilyl)bis(trimethylsilyl)methane with silver borofluoride and silver chloride. Crystal structure of (chlorodiphenylsilyl)(methoxydimethylsilyl)-bis(trimethyl-silylmethane). J. Chem. Soc., Perkin Trans. 2, 1987, 891-894.

91 G.A. Ayoko and C. Eaborn. Assistance by and migration of the vinyl group in reactions of the sterically hindered compounds of the type (Me3Si)2C(SiMe2 CH=CH2)(SiR2X). J. Chem. Soc., Perkin Trans. 2, 1987, 1047-1058.

92 D.B. Azarian, C. Eaborn, and P.D. Lickiss. Effects of the substituents Y in reactions of compounds of the type (Me3Si)3CSiH(C6H4Y-p)I. Evidence against the SN2(intermediate) mechanism for methanolysis of (328, Me3Si)3CSiMe2I and (Me3Si)3CSiHPhI. J. Organomet. Chem. 1987, 328, 256-262.

93 D.B. Azarian, C. Eaborn, and P.D. Lickiss. Reactions of tris(trimethylsilyl)methylsilicon compounds with organolithium reagents. J. Organomet . Chem., 1987, 330, 1-7.

94 S.M. Dhaher, C. Eaborn, and J.D. Smith. 1,3-Migration of a methyl group from tin to silicon via a cationic intermediate. J. Chem. Soc., Chem. Commun., 1987, 1337-1388.

95 C. Eaborn, P.D. Lickiss, S.T. Najim, and W.A. Stanczyk. 1,3-Migrations of a phenyl group via a silicocation. J. Chem. Soc., Chem. Commun., 1987, 1183-1184.

96 N.H. Butruss, C. Eaborn, P.B. Hitchcock, P.D. Lickiss, and S.T. Najim. 1,3 Silicon to silicon migration of the methoxy group in solvolysis of (bromodiphenyl)(methoxydimethylsilyl)bis(trimethylsilyl)-methane. Crystal structure of (ethoxydimethylsilyl)(methoxydiphenyl-silyl)bis(trimethylsilyl)methane and (methoxydimethylsilyl)(methoxy-diphenylsilyl)bis(trimethylsilyl)methane. J. Chem. Soc., Perkin Trans. 2, 1987, 1753-1757.

97 C. Eaborn, P.D. Lickiss, and A.D. Taylor. Reactions of the sterically hindered organosilicon diol (Me3Si)2C(SiMe2OH)2 and some of its derivatives. J. Organomet. Chem. 1988, 340, 283-292.

98 J. A. Atwood, S.G. Bott, P.B. Hitchcock, C. Eaborn, R.S. Shariffudin, J.D. Smith, and A.C. Sullivan. The chemistry of trichloro[tris-(dimethylphenylsilyl)methyl] complexes of gallium, indium, and thallium. Crystal and molecular structures of [Li(thf)2(µ-Cl)2GaCl{C(SiMe2Ph)3}].thf, [Li(thf)3(µ-Cl)InCl2{C(SiMe3)3}], and [{(Me3Si)3C}In(µ-Cl)2{µ-Fe(CO)4}In{C(SiMe3)3}] (thf = tetrahydrofuran). J. Chem. Soc., Dalton Trans.,1987, 747-755.

99 C. Eaborn, P.D.Lickiss, and A.D. Taylor. The nature of the anchimeric assistance by the acetoxy group in solvolysis of (Me3Si)2C(SiMe2OCOMe)(SiMe2Cl). J. Organomet. Chem. 1988, 338, C27-C29.

100 N.H. Buttrus, C. Eaborn, M.N.A. El-Kheli, P.B. Hitchcock, J.D. Smith, A.C. Sullivan, and K. Tavakkoli. Some sterically hindered lithium alkylbromo- and alkylchloro-magnesates. Crystal and molecular structures of [Li(thf)2(µ-Br)2Mg{C(SiMe3)3}(thf), [Li(thf)4][{Cd[C(SiMe3)3]}3(µ-Br)(µ-Br)3].0.5C6H12, [{Li(thf)3}(µ-Br)3Br)(µ-OSiMe3)Cd{C(SiMe3)}3], and [Li(thf)4][Mn[C(SiMe3)3]}3(µ-Cl)4(thf). J. Chem. Soc., Dalton Trans., 381-391.

101 N.H. Buttrus, C. Eaborn, M.E. Molla, P.B. Hitchcock, and J.D. Smith. The The synthesis and crystal structure of µ{di-_6-phenyl(trimethylsilyl)methane}bis(tricarbonyl)chromium. J. Organomet. Chem.,1988, 344, 313-319.

102 S.S. Al-Juaid, N.H. Buttrus, C. Eaborn, P.B. Hitchcock, J.D. Smith,and K. Tavakkoli. The preparation and crystal structure of the sterically hindered lithium alkylchlorocadmate [Li(thf)4][Li(thf)2(µ-Cl)4{CdC(SiMe3)3}2].thf (thf = tetrahydrofuran), the alkylcadmium halides [{Cd[C(SiMe3]Cl4] and [{Cd[C(SiMe2Ph)3]Br}2], and the hydrate [{Cd[C(SiMe2Ph)3]Br}(H2O)]2.(thf). J. Chem. Soc., Chem. Commun., 1988, 1389-1391.

103 A. Alvanipour, N.H. Buttrus, C. Eaborn, P.B. Hitchcock, A. I. Mansour, and A.K. Saxena. Formation of a tetraazole from (PhMe2Si)3CSiMe2I. Crystal structure of (PhMe2Si)3CSiMe2N-N=C(Me)-N=N. J. Organomet. Chem. 1988, 349, 29-36.

104 S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, and P.D. Lickiss, The crystal structure of tetrakis(hydroxydimethylsilyl)methane. A remarkable three-dimensional network. J. Organomet. Chem.; 1988, 353, 297-305.

105 S.M. Dhaher, C.Eaborn, and J.D. Smith. Synthesis and properties of some crowded organotin compounds. J. Organomet. Chem. 1988, 355, 33-44.

106 S.S. Al-Juaid, S.M. Dhaher, C. Eaborn, P.B. Hitchcock, C.A McGeary, and J.D. Smith, Some [(tris(trimethyl)- and [tris(dimethylphenyl)silyl])methyl derivatives of phosphorus. The crystal structure of [tris(dimethylphenylsilyl)]methylphosphonous dichloride. J. Organomet. Chem.,1989, 366, 39-51.

of metasilicate intermediates. J. Chem. Soc., Perkin Trans. 2, 1989, 865-871.

107 S.S. Al-Juaid, N.H. Buttrus, R.I. Damja, Y. Derouiche, C. Eaborn, P.B. Hitchcock, and P.D. Lickiss. Hydrogen bonding in organosilanetriols. The crystal structures of tris(trimethylsilyl)silyl- and tris(trimethylsilyl)methylsilanetriol. J. Organomet. Chem. 1989, 371, 287-295.

108 S.S. Al-Juaid, C. Eaborn, M.N.A. El-Kheli, P.B. Hitchcock, P.D. Lickiss, M.E. Molla, J.D. Smith, and J.A. Zora. Tris(trimethyl)methyl and tris(dimethylphenyl)silyl)methyl derivatives of boron. Crystal structures of dihydroxy[tris(trimethyllsilyl)methyl]borane and the lithium-boron complex [(MeOH)2Li(µ-OMe)B(OMe)2]. J. Chem. Soc, Dalton Trans.,1989, 447-452.

109 S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, C.A. McGeary, and J.D. Smith. The crystal structure of [tris(trimethylsilyl)methyl]magnesium: an example of two-coordinate magnesium in the solid state. J. Chem. Soc., Chem. Commun., 1989, 273-274.

110 C. Eaborn, K.L. Jones, and P.D. Lickiss. Anchimeric assistance by (-aryl groups in solvolysis of organosilicon iodides. Some remarkably large remote substituent effects. J. Chem. Soc., Chem. Commun.,1989, 595-596.

111 C. Eaborn, K.L. Jones, J.D. Smith, and K. Tavakkoli. The remarkable thermal stability of benzyl[tris(dimethylphenylsilyl)methyl]mercury. How can a bulky ligand stabilize an organometallic compound towards unimolecular dissociation? J. Chem. Soc., Chem. Commun., 1989, 1202-1202.

112 S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, P.D. Lickiss, A. Möhrke, and P. Jutzi. Hydrogen-bonding in organosilanediols. The crystal structure of bis(pentamethylcyclopentadienyl)silanediol. J. Organomet. Chem. 1990, 384, 33-40.

113 S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, K Kundu, M.E. Molla, and J.D. Smith. Novel tris(trimethylsilyl)methylboron compounds. Crystal structures of the diborane {(Me3Si)3C}HB(µ-H)2BH{C(SiMe3)3} and the bis(aminoboryl)amine {(Me3Si)3C(NH2)B}2NH, J. Organomet. Chem. 1990, 385, 13.

114 S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, and J.D. Smith, and L. Zanotto. Desilylation and cyclometallation reactions of diphenyl{tris(trimethylsilyl)methyl}phosphine with platinum(II) compounds. Crystal structure of trans-[PtClPPh2C(SiMe3)2SiMe2CH2{PPh2CH(SiMe3)2]. J. Organomet. Chem. 1990, 394, 69-75.

115 A.I Al-Mansour, M.A.M.R. Al-Guarashi, C. E.Eaborn, F.A. Fatttah, and P.D. Lickiss. 1,3-Migration of triorganosilyl groups from carbon to oxygen in highly crowded organosilanols. J. Organomet. Chem. 1989, 393, 27-32.

116 C. Eaborn and F.A. Fattah. Miscellaneous reactions of tris(trimethylsilyl)methylsilicon compounds. J. Organomet. Chem. 1990, 396, 1-8.

117 C. Eaborn, P.D. Hitchcock, P.D. Lickiss, and A.D. Taylor. The synthesis and crystal structure of the crowded disiloxane [(Me3Si)3Cl2Si]2O. J. Organomet. Chem. 1990, 398, 59-64

118 C. Eaborn, A. Habtemariam, F Aigbirhio, C. Eaborn, and J.D. Smith, J. Chem. Soc., Chem. Commun, 1990, 1471-1472.

119 F.I Aigbirhio, S.S. Al-Juaid, C. Eaborn, A. Habtamariam, P.B. Hitchcock, and J.D. Smith. Some unusual organo-zinc and -mercury compounds. The crystal structures of the compounds [(HOMe2Si)(Me3Si)2C]2Zn, [(MeOMe2Si)(Me3Si)2C]2Zn, and [(MeOMe2Si)(Me3Si)2C]2Zn, J. Organomet. Chem. 1991, 405, 149-165.

120 C. Eaborn. A contribution to the silicenium ion debate. J. Organomet. Chem., 1991, 405, 141-148.

121 F.I. Aigbirhio, S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, and P.D.Lickiss. Comparison of the Reactivities of the Compounds (Me3Si)2C(SiMe2OMe)(SiMe2Cl) and (MeOMe2Si)3C(SiMe2Cl). Crystal Structure of (MeOMe2Si)3CSiPh2H. J. Chem. Soc., Perkin Trans. 2, 1991, 1407-1410.

122 S. S Al-Juaid, A. K. A. Al-Nasr, C. Eaborn, and P. B. Hitchcock. Hydrogen bonding interaction between a hydroxy group and the (-electrons of an aryl group. Crystal structure of [tris(dimethylphenylsilyl)methyl]methylsilanol. J. Chem. Soc., Chem. Commun, 1991, 1482-1484.

123 C. Eaborn and D.A.R Happer. A novel mode of reaction of a substituted alkyl halide. Reduction of tris(trimethylsilyl)methyl iodide by methanol. J. Chem. Soc., Chem. Commun, 1991, 1608-1609.

124 Z. H. Aiube and C. Eaborn, Reactions at highly sterically hindered centres. Chemistry of (Me3Si)3CPhHI, (Me3Si)3CPh(OMe)I, and related species. J. Organomet. Chem. 1991, 421, 159-169.

125 S. S. Al-Juaid, C. Eaborn, and P.B. Hitchcock. The crystal structure of (Me3Si)3CSi(OH)2(OCOCF3). J. Organomet. Chem. 1992, 423, 5-12.

126 F.I. Aigbirhio, N.H. Buttrus, C. Eaborn, S.H Gupta, P.B. Hitchcock, J.D. Smith., and A.C. Sullivan. Synthesis, crystal structure and reactions of the dimeric organolithium compound [{(MeO)Me2Si]3CLi. J. Chem. Soc., Dalton Trans.,1992, 1015-1018.

127 C Eaborn, K.L. Jones, and P.D. Lickiss. Anchimeric assistance by (-aryl groups in reactions of organosilicon iodides. J. Chem. Soc., Perkin Trans. 2, 1992, 489-495.

128 C. Eaborn, Y.Y. El-Kaddar, and P.D. Lickiss. Preparation and reactions of some organosilicon cyanates. Inorg. Chim. Acta., 1992, 200, 337-344.

129 S. S Al-Juaid, A. K. A. Al-Nasr, C. Eaborn, and P. B. Hitchcock. Crystallographic Evidence for Intermolecular Interaction Between Aryl Groups and OH Groups in Silanols. J. Organomet. Chem., 1992, 429, C9-C13.

130 S.S. Al-Juaid, C. Eaborn, A. Habtamariam, P.B. Hitchcock, and J.D. Smith. Reactions of sterically hindered organozinc and organocadmium compounds containing functional silicon centres. Crystal structures of Zn[C(SiMe3)2(SiMe2OCOCF3)]2 and Cd[C(SiMe3)2(SiMe2OMe)]2. J. Organomet. Chem. 1992, 437, 41-45.

131 Y.Y. El-Kaddar, C. Eaborn, P.D. Lickiss, and D.E. Reed. The methanolysis of the highly strerically hindered organosilicon compounds (Me3Si)3CSiMe2X with X = OSO2CF3, OCN, or OClO3. A mechanistic enigma. J. Chem. Soc., Perkin Trans. 2, 1992, 1753-1759.

132 C. Eaborn, P.D. Lickiss, S.T. Najim, and W.A. Stanczyk. Reaction of (Me3Si)2C(SiMe2Ph)(SiMe2I) with AgBF4. 1,3-Migration of the phenyl group. J. Chem. Soc., Perkin Trans. 2, 1993, 59-62.

133 C. Eaborn, P. D. Lickiss, and S. T. Najim. 1,3-Migration of chloride and azide ligands in reactions of highly sterically hindered organosilicon halides. J. Chem. Soc., Perkin Trans. 2, 1993, 391-394.

134 C. Eaborn, K. L. Jones, P. D. Lickiss and W. A. Stanczyk. Proportion of 1,3-phenyl migration in the trifluoroethanolysis, methanolysis, and hydrolysis of (Me3Si)2C(SiMe2Ph)(SiEt2I), J. Chem. Soc., Perkin Trans. 2, 1993, 395-397.

135 S.S. Al-Juaid, M. Al-Rawi, C. Eaborn, P.B. Hitchcock, and J.D. Smith. Preparation and crystal structures of the crowded triorganotin isothiocyanate (PhMe2Si)3CSnMe2NCS and nitrate (PhMe2Si)3CSnMe2ONO2. J. Organomet. Chem. 1993, 446, 161-166.

136 C. Eaborn and N M. Romanelli. Anchimeric assistance by the (-N3 and (-NCS groups in solvolysis of (Me3Si)2C(SiMe2N3)(SiMe2Br) and (Me3Si)2C(SiMe2NCS)(SiMe2Br). J. Organomet. Chem. 1993, 451, 45-52.

137 S.S. Al-Juaid, A.K. Al-Nasr, C. Eaborn and P.B. Hitchcock.The crystal structure of the oganosilicon p-toluenesulfonate (Me3Si)3SiPh(H)(OSO2C6H4Me-p). J. Organomet. Chem. 1993, 455, 57-60.

138 Y. Y. El-Kaddar, C. Eaborn, and P. D. Lickiss. Reactions of the highly sterically hindered compounds (Me3Si)3CSiMe2X (X = Cl, Br, I, or ONO2) with NaN3, CsF, KSCN, and KOCN in MeOH. J. Organomet. Chem. 1993, 460, 7-13.

139 A. G. Avent, C. Eaborn, P. B. Hitchcock, G. A. Lawless, P. D. Lickiss, M. Mallien, J. D. Smith, A. D. Webb, and B Wrackmeyer. Crystal structure of [Li(tmeda)2][Li{C(SiMe3)2]. A multinuclear magnetic resonance study of tris(trimethylsilyl)methyl-lithium-tetrahydrofuran (thf) and -tetramethylenediamine (tmeda). J. Chem. Soc., Dalton Trans.,1993, 3259-3264.

140 C. Eaborn, K. L. Jones, and P. D. Lickiss. Reactions of compounds of the type (Me3Si)2C(SiMe2C6H4Y)(SiMe2X) with trifluoroacetic acid. J. Organomet. Chem. 1993, 461, 7-13.

141 S. S. Al-Juaid, C. Eaborn, A. Habtemariam, P. B. Hitchcock, J. D. Smith, K. Tavakkoli, and A. D. Webb. The preparation and crystal structures of the compounds (Ph2MeSi)3CMCl (M = Zn, Cd, or Hg). J. Organomet. Chem. 1993, 462, 45-55.

142 B. M. Clark, C. Eaborn, and D. A. R. Happer. Light catalysed reduction of tris(trimethylsilyl)methyl iodide. A radical chain process showing a large kinetic hydrogen isotope effect. J. Chem. Soc., Perkin Trans. 2, 1994, 341-345.

143 C. Eaborn, K. L. Jones, and P. D. Lickiss. Preparation of the iodides (Me3Si)2C(SiMe2C6H4Y)(SiMe2I) and some related compounds. J. Organomet. Chem. 1994, 466, 35-42.

144 S. S. Al-Juaid, C. Eaborn, P. B. Hitchcock, A. J. Jaggar, and J. D. Smith. The reaction of (Me3Si)3CBr with Mg in tetrahydrofuran or diethyl ether. Crystal structure of (Me3Si)3CMg(µ-Br)3Mg(THF)3. J. Organomet. Chem. 1994, 469, 129-133.

145 (a) S. S. Al-Juaid, C. Eaborn, P.B. Hitchcock, K. Izod, M. Mallien and

J.D. Smith. Metallation of tris(trimethylsilyl)- and tris(dimethylphenylsilyl)methane with methylsodium: the first diakylsodate. Angew. Chem. Int. Ed. Engl., 1994, 33, 1268-1270; (b) Angew. Chem., 1994, 106, 1336-1338.

146 S. S. Al-Juaid, C. Eaborn, P. B. Hitchcock, A. J. Jaggar, and J. D. Smith. Crystal stuctures of tris(trimethylsilyl)methyl- and tris(dimethylphenylsilyl)methyl)-potassium, Organometallics, 1994, 13, 753-754.

147 A. I. Al-Mansour, S. S. Al-Juaid, C. Eaborn and P. B. Hitchcock. Crystal structure.of the crowded silanol (Me3Si)3SiPh2OH. J. Organomet. Chem., 1994, 480, 139-143.

201. S. S. Al-Juaid, C. Eaborn, P. B. Hitchcock, K. Kundu, C. A. McGeary and J. D. Smith. Preparation, crystal structure and reactivity of bis{tris(trimethylsilyl)methyl}magnesium, J. Organomet. Chem., 1994, 480, 199-203.

201. C. Eaborn, P. D. Lickiss and A. D. Taylor .Anchimeric assistance by the acetoxy group in solvolysis of the compounds (Me3)2C(SiMe2OCOMe)(SiMe2X), X = Cl, NCS, or N3 .J. Chem. Soc., Perkin Trans 2, 1994, 1089-1813.

201. C. Eaborn, P. B. Hitchcock, K. Izod and J. D. Smith. A monomeric solvent-free bent lanthanide dialkyl and a lanthanide analogue of a Grignard reagent. Crystal structures of Yb{C(SiMe3)3}2 and [Yb{C(SiMe3)3I.OH4]2 .J. Am. Chem. Soc., 1994, 116, 12071-12072.

151 C. Eaborn, I. B. Gorrell, P. B. Hitchcock, J. D. Smith and K. Tavakkoli. Preparation of new lithium organotrihydroaluminates: crystal structure of {(C4H8O)2Li(µ-H)2AlH[C(SiMe2Ph)3]}2. Organometallics. 1994, 13, 4143-4144.

152 S. S. Al-Juaid, A. A. K. Al-Nasr, G. A. Ayoko, C. Eaborn and P. B. Hitchcock. The geometry of SiOCN and SiNCO linkages. The crystal structures of (Me3Si)2(Ph2MeSi)CSiMe2OCN and (PhMe2Si)3CSiMe2NCO. J. Organomet. Chem., 1995, 488, 155-160.

153 P. T. Brain, M. Mehta, D. W. H. Rankin, H. E. Robertson, C. Eaborn, J. D. Smith and A. D. Webb. Determination by electron diffraction of the molecular structures of chloro- and bromo-tris(trimethylsilyl)methane in the gas phase. J. Chem. Soc., Dalton Trans., 1995, 349-354.

201. A. I. Almansour and C. Eaborn. Preparation of (iPrMe2Si)3CH and its use as a source of the bulky ligand (iPrMe2Si)3C. J. Organomet.Chem., 1995, 489, 181-183.

201. A. I. Almansour, J. R. Black, C. Eaborn, P. M. Garrity and D. A. R. Happer .Predominance of unrearranged products in the reactions of the iodide.(Me3Si)3C(CD3)2I with silver salts, and its mechanistic implications. J. Chem. Soc., Perkin Trans. 2, 1995, 705-706.

156 P. T. Brain, M. Mehta, D. W. H. Rankin, H. E. Robertson, C. Eaborn, J. D. Smith and A. D. Webb. Determination by electron diffraction of the molecular structure of bromotris(methoxydimethylsilyl)methanein the gas phase. J. Chem. Soc., Dalton Trans., 1995, 975-978.

157 M. A. M. R. Al-Guarashi, G. A. Ayoko, C. Eaborn and P. D. Lickiss.

Rates of solvolysis of the compounds (Me3)2(Ph2MeSi)CSiMe2X, X = I, OSO2CF3 and OCN. Mechanistic implications. J. Organomet. Chem., 1995, 499, 57-62.

158 (a) C. Eaborn, P. B. Hitchcock, K. Izod and J. D. Smith, Synthesis and structure of RbC(SiMe3)3 and CsC(SiMe3)3.3.5C6H6: a one-dimensional ionic and a molecular festkorper. Angew. Chem. Int. Ed. Engl., 1995, 14, 687-688. (b) Synthesen und Struckturen von RbC(SiMe3)3 and CsC(SiMe3)3.3.5C6H6: Ein eindimensionaler ionischer und ein molekular Festkörper, Angew. Chem., 1995, 107, 756-757.

159 M. A. M. R. Al-Gurashi, G, A. Ayoko, C. Eaborn and P. D. Lickiss, Anchimeric assistance in the reactions of the crowded organosilicon iodide (Me3Si)2(Ph2MeSi)CSiMe2I with electrophiles. Bull Soc. Chim. Fr., 1995, 132, 517-521.

160 C. Eaborn and J. D. Smith, Synthesis, structure and reactions of organometallic compounds of Groups 1-3 containing bulky silicon-substituted alkyl groups, J. Organomet. Chem., 1995, 500, 89-99.

161 C. Eaborn, K. Izod, P. B. Hitchcock, S. E. Sözerli and J. D. Smith, The first monorganolead(II) derivative, [{Pb(µ-Cl)}2] where R = C(SiMe2Ph)3. J. Chem. Soc., Chem. Commun., 1995, 1829-1830.

162 G. A. Ayoko, C. Eaborn and P. B. Hitchcock, Geometry of the SiOCN Linkage. Crystal Structure of (Me3Si)2(PhMe2Si)CSiMe2OCN, .Organometallics, 1995, 14, 4960-4961.

163 C. Eaborn, K. Izod, P.B. Hitchcock, and J.D. Smith, Two diorganopotassates: Crystal stucture of [K(C6H6)][K{C(SiMe3)2(SiMe2Ph)}2. Angew. Chem. Int. Ed. Engl, 1995, 34, 2679-2890.

164 S. S. Al-Juaid, C. Eaborn, P. D. Lickiss, J. D. Smith, K. Tavakkoli, and A. D. Webb, Preparation, spectroscopic properties, and thermal stabilities of organomercury compounds containing the bulky ligand (Me3Si)3C or (PhMe2Si)3C. J. Organomet. Chem., 1996, 510, 143-151.

165 A.G. Davies, C. Eaborn, P.D. Lickiss and A.G. Neville, EPR spectra of tris(trimethylsilyl)methyl(hydroxy)silyl radicals, (Me3Si)3SiROH., and tris(trimethylsilyl)methylsilanone radical anions (Me3Si)3SiR=O.- (R = H, Me, Et, Bu, Ph, F). J. Chem. Soc., Perkin Trans. 2, 1996, 163-169.

166 F. Adam, C. Eaborn, P. B. Hitchcock, and J.D. Smith. The novel linear-polymeric organolithium compound {(Me2NMe2Si)3CLi}n. J. Chem. Soc., Chem. Commun., 1996, 741-742.

167 C. Eaborn, Z.-R. Lu, P. B. Hitchcock, and J. D. Smith. The novel chelated diorganolithate ion [CH2SiMe2C(SiMe3)2LiC(SiMe3)2SiMe2CH2]– and the highly crowded chelated organomercury compound [CH2SiMe2C(SiMe3)2HgC(SiMe3)2SiMe2CH2]. Organometallics. 1996, 15, 1651-1655.

168 A.I. Almansour, G. A. Ayoko and C. Eaborn. The mechanism of the isomerization of organosilicon cyanates to isocyanates. J. Organomet. Chem., 1996, 514, 277-280.

169 C. Eaborn and J. D. Smith. Compounds of elements of Groups 11-13 containing (Me3Si)3C, (PhMe2Si)3C, or related ligands. Coord. Chem. Rev., 1996, 154, 125-149.

170 D. A. Antonov, C. Eaborn, J. D Smith, P. B. Hitchcock, E. Molla, V. I. Rozenberg, W. A. Stancyk, and A. Kowaleska. A bulky tris(trisilylmethyl) ligand incorporating a donor sulfur atom. Some (Me3Si)2(PhSMe2Si)CSnMe2X compounds. J. Organomet. Chem., 1996, 521, 109-112.

171 C. Eaborn, P.B. Hitchcock, A. Kowalewska, Z.-R. Lu, J.D. Smith and W.A. Stanczyk. Iodo(methoxydimethylsilyl)bis(trimethylsilylmethane:a reagent for the preparation of novel organometallic compounds. Crystal structures of Mg{C(SiMe3)2(SiMe2OMe)}2 and MgI2(OH4)2. J. Organomet. Chem., 1996, 521, 113-120.

172 A.G. Avent, W.-Y. Chen, C. Eaborn, I.B. Gorrell, P.B. Hitchcock and J.D. Smith. Organotrialkoxy- and Organotrifluoroaluminates. Crystal structures of Li[(Me3Si)3CAlX3].OC4H8 (X = OBut, F). Organometallics, 1996, 15, 4343-4345.

173 C. Eaborn, P.B. Hitchcock, K. Izod, Z.-R. Lu and J.D. Smith. Alkyl derivatives of europium(+2) and ytterbium(+2). Crystal structures of Eu{C(SiMe3)3}2, Yb{CC(SiMe3)2(SiMe2CH=CH2)}I.OH4 and Yb{CC(SiMe3)2(SiMe2OMe)}I.OH4. Organometallics, 1996, 15 4783-4790.

A. I. Almansour, H. A. Abubishait, and C. Eaborn. 1,3-Si-toSi migration of a methyl group. Ratio of rearranged and unrearranged products in the reactions of the iodide (Me3Si)3C(Si(CD3)2I with ICl. J. Organomet. Chem., 1997, 531, 171-174.

175 C. Eaborn, Adam Farook, P.B. Hitchcock, and J.D. Smith. Tris{dimethylamino)dimethylsilyl}methylmagnesium iodide. A Grignard reagent without a carbon-magnesium bond? Organometallics, 1997, 16. 503-504.

176 Organometallic Compounds of the alkali metals with phenylsilyl substituents at the carbanionic center. Crystal structure of LiC(SiMe3)2(SiMe2Ph).Et2O, Na(SiMe3)2(SiMe2Ph).TMEDA, Na(SiMe3)(SiMe2Ph)2.TMEDA, {LiCH(SiMe2Ph)2}2, RbC(SiMe2Ph)2}3, CsC(SiMe2Ph)2}3, (TMEDA = tetramethylethylenediamine). C. Eaborn, W. Clegg, P. B. Hitchcock, M Hopman, K. Izod, P. N. O’Shaughnessy and J. D. Smith, Organometallics, 1997, 16, 4728-4736.

177 C. Eaborn, S. A Hawkes, P. B. Hitchcock and J. D. Smith. The first structurally characterised solvent-free (-bonded diorganocalcium, Ca[C(SiMe3)3]2. Chem. Communs., 1997, 1961-1962.

178 C. Eaborn, Adam Farook, P. B. Hitchcock and J. D. Smith. catena-Poly[[(1,4-dioxane-O1)iodolithium]-(-(1,4-dioxane-O1:O4)], Acta Cryst. Sect.C, 1997, 1387-1388.

179 J. R. Black, C. Eaborn, P. M. Garrity and D. A. R. Happer. The proportion of 1,3-migration of a methyl group in the reactions of the iodide (Me3Si)3C(Si(CD3)2I with silver salts in alcohols. Mechanistic implications. J. Chem. Soc., Perkin Trans. 2, 1997, 1633-1639.

180 C. Eaborn, T. Ganicz, P. B. Hitchcock, J. D. Smith, and S. E. Sözerli. Novel

Organolead(II) Species, the Plumbacycloalkane Derivative

[CH2SiMe2C(SiMe3)2PbC(SiMe3)2SiMe2CH2. Organometallics, 1997, 16, 5621-5622.

201. C. Eaborn, P. B. Hitchcock, J. D. Smith, and S. E. Sözerli. Synthesis and crystal structures of the compounds [Sn{C(SiMe2Ph)3}Cl]2, [Pb{C(SiMe3)3}Cl]3 and [M{C(SiMe3)2(SiMe2OMe)}Cl]2, M = Sn or Pb. Organometallics, 1997, 16, 5653-5658.

182 A. I. Almansour, C. Eaborn, S. A Hawkes, P. B. Hitchcock and J. D. Smith. An alkyllithium compound with a free planar carbanion. The crystal structure of [Li(THF)4][(C(SiMe2C6H4Me-o)3]. Organometallics, 1997, 16, 6035-6037.

183 W.-Y. Chen, C. Eaborn, I. B. Gorrell, P.B. Hitchcock, M. Hopman, and J.D. Smith. Lithium trialkoxyo[tris(trimethylsilyl)methyl]aluminates, analogues of intermediates in reductions of carbonyl compounds. Crystal structures of [Li(thf)2][AlR(OEt)3] and {Li[AlR(OPri)2(OH))]}2, R = C(SiMe3)3 and thf = tetrahydrofuran. J. Chem. Soc., Dalton Trans., 1997, 4689-4693.

184 W Clegg,., C Eaborn,., K Izod, P. N O’Shaughnessy and J. D. Smith. The first structurally authenticated alkyl compound of samarium(II) and its reaction with benzophenone. Crystal structures of {(Me3Si)2(Me2MeOSi)C}2Sm(THF) and {(Me3Si)2(Me2MeOSi)C}2Sm(OCPh2). Angew. Chem. Int. Ed Engl.1997, 36, 2815-2817.

185 A novel molecular species incorporating a cyclic organolithate anion and a disiloxane-solvated lithium cation. C. Eaborn, S. M. El-Hamruni, P. B. Hitchcock and J. D. Smith. Chem. Commun., 1998, 1277-1278.

186 C. Eaborn, A. Farook, P. B. Hitchcock, and J. D. Smith A novel zwitterionic species

containing an Al(III) cation and a planar carbanion. Crystal structure of

[Et3AlNMe2SiMe2C(SiMe2NMe2)2AlEt2](C6H6 . Organometallics, 1998, 17, 3135.

187 C. Eaborn, J. D. Smith, P. B. Hitchcock and S. E. Sözerli Crystal Structure of the

1,3-Disilacyclobutane Derivative (Me3Si)2CSiMe2C(SiMe3)2SiMe2. J. Chem Res.(S). 1998, 566-567.

188 S. S.Al-Juaid, C. Eaborn, I. B. Gorrell, S. A. Hawkes, P. B. Hitchcock, and J. D. Smith. Reactions of the alkylhydroaluminate {Li(thf)2[AlH3C(SiMe3)3]}2.Crystal structures of [Li(tmen)2] [AlH3C(SiMe3)3], [AlBr2C(SiMe3)3.thf] [AlI2C(SiMe3)3.thf], [Li(thf)2((-NHPh)2AlHC(SiMe3)3] and [Li(thf)4][Al(NHPh)3C(SiMe3)3] (thf = tetrahydrofuran) J. Chem. Soc. Dalton Trans., 1998, 2411-2415.

189 S. S. Al-Juaid, C. Eaborn, M. Al-Rawi, P. B. Hitchcock, and J. D. Smith. Organotin compounds containing a bulky (Me3Si)3C or related ligand. Crystal Structures of {(Me3Si)3CMe(O2NO)Sn}2O, (PhMe2Si)3CSnMeCl2 and (PhMe2Si)3CSnCl3. J. Organomet. Chem . 1998, 564, 215-226.

190 C Eaborn, P. B. Hitchcock, J. D. Smith, and S. E. Sözerli. An Unusual Alkyltrihydroaluminate. Crystal Structures of

[AlH2{C(SiMe3)2(SiMe2OMe)}((-H)Li(THF)], [AlCl2{C(SiMe2OMe)(SiMe3)2}(THF)],

and [Li{C(SiMe2OMe)(SiMe3)2}(THF)2] (THF = tetrahydrofuran). Organometallics, 1998, 17, 4322-4325.

191 C. Eaborn, A. Kowalewska and W. A Stanczyk, 1,3-Migration of a phenyl group in the conversion of (Me3Si)2(PhMe2Si)CSiMePhX into (Me3Si)2(Ph2MeSi)CSiMe2X species, J. Organomet. Chem., 1998, 560, 41-46.

192 S. S. Al-Juaid, C. Eaborn, S.M. El-Hamruni, P. B. Hitchcock and J. D. Smith. Attachment of the New Bulky Ligand (Me3Si)2(Me2NMe2Si)C to Li, Hg, Al, Ga and Sn. Crystal Structures of [Li{C(SiMe3)2(SiMe2NMe2)}(THF)2], [Hg{C(SiMe3)2(SiMe2NMe2)}2], [Al{C(SiMe3)2(SiMe2NMe2)}X2], X = Cl or Ph, and [Ga{C(SiMe3)2(SiMe2NMe2)}C12]. Organometallics, 1999, 18, 45-52.

193 C Eaborn, M S Hill, P. B. Hitchcock, J. D. Smith, S Zhang, and T Ganicz. Attachment of the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C to K, Zn, Sn, and Yb. Crystal structures of LnM C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CMLn (MLn = K(C6H6)2, K(THF)2, SnCl3,or SnMe2Cl) and

CH2SiMe2C(SiMe3)2Zn C(SiMe3)2 SiMe2CH2 (THF = tetrahydrofuran), Organometallics, 1999, 18, 2342-2348.

194 A G Avent, D Bonafoux, C. Eaborn, S K Gupta, P B Hitchcock, and J D Smith. Reaction of tris[(diphenylphosphino)dimethtylsilyl]methane with molybdenum hexacarbonyl and deprotonation to give a salt with a planar carbanion. Crystal structures of (Ph2Me2Si)3CH and [Li(tmen)2][C(SiMe3)2PPh2)3], tmen = N,N,N'',N''-tetramethylethane-1,2-diamine. J. Chem. Soc., Dalton Trans., 1999, 831-834.

195 S S Al-Juaid, C Eaborn, S El-Hamruni, A Farook, P B Hitchcock, M Hopman, J D Smith, W Clegg, K O Izod and P O'Shaughnessy. Tris(triorganosilyl)methyl derivatives of potassium and lithium bearing dimethylamino or methoxy substituents at silicon Crystal structures of KC(SiMe3)2(SiMe2NMe2), KC(SiMe2NMe2)3, and [LiC(SiMe3)2(SiMe2OMe)2]2. J. Chem. Soc., Dalton Trans., 1999, 3267- 3273.

196 C. Eaborn, M. S. Hill, P. B. Hitchcock, D. Patel, J. D. Smith, and S. Zhang. Oxidative addition to a monmeric stannylene to give four-coordinate tin compounds coataining the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C. Crystal

structures of CH2SiMe2C(SiMe3)2SnC(SiMe3)2 SiMe2CH2,

CH2SiMe2C(SiMe3)2SnMe(OCOCF3)C(SiMe3)2 SiMe2CH2, and

(CF3COO)2MeSnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CSnMeOCOCF3)2. Organometallics 2000, 19, 49-53.

197 C. Eaborn, S. M. El-Hamruni, M. S. Hill, P. B. Hitchcock, M. Hopman, A.Le Gouic and J. D. Smith, Synthesis of some bulky alkylalanes and alkyltrihydroaluminates: crystal structures of [Li(THF)2AlH3C(SiMe3)3}2, (Me3Si)3CAlH2.THF and the pyrazolato derivative [LiAlH(C3H3N2)2C(SiMe3)3]2 (THF = Tetrahydrofuran). J. Organomet. Chem.2000, 597, 3-9.

198 C. Eaborn, P. B. Hitchcock, J. D. Smith, S. Zhang, W. Clegg, K Izod and P. O’Shaughnessy, Manganese and cesium derivatives of the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C. Crystal structures of

Li(THF)2.75(Et2O)0.25((-Cl)MnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C and (C6H6)3C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CCs(C6H6)3 Organometallics,2000, 19, 1190-1193.

199 C. Eaborn, M. S. Hill, P. B. Hitchcock and J. D. Smith,. ‘The first structurally characterised

(- bonded organonickel(I) compound. Crystal structures of Ni{C(SiMe3)2(SiMe2C5H4N-2}(PPh3)],

[Ni{C(SiMe3)(SiMe2C5H4N-2)(SiMe2O)}]2 and [Pd((-Cl){C(SiMe3)2(SiMe2C5H4N-2)}]2. Chem. Commun. 2000, 691-692.

200 A. G. Avent, D Bonafoux, C. Eaborn, M. S. Hill, P. B. Hitchcock and J. D. Smith,Crowded organometallic compounds of the alkali metals with diphenyphosphino substituents in the organic group. J. Chem. Soc., Dalton Trans., 2000, 2183-2190.

201. Y. Chen, C. Eaborn, I. B. Gorrell, P. B. Hitchcock and J. D. Smith, Syntheses and crystal structures of some lithium di- and tri-(thiolato)[tris(trimethysilyl)methyl]aluminates. J. Chem. Soc., Dalton Trans., 2000, 2313 -2317.

202 C. Eaborn, M. S. Hill, P. B. Hitchcock and J. D. Smith. Structural diversity in organolithium, -sodium, and –potassium cyanocuprates. Organometallics, 2000, 19, 5780.

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