Molar Volume of a Gas
Molar Volume of a Gas
When magnesium metal reacts with hydrochloric acid, hydrogen gas is produced. The volume of this gas can be measured by using a eudiometer. Knowing the number of moles of magnesium used, we can calculate the volume of hydrogen produced per mole of magnesium consumed. The balanced equation for this reaction allows us to determine the volume that one mole of gas occupies at a specified temperature and pressure.
Purpose
After completing this experiment, you should be able to compare the volume of gas generated in lab to the accepted value of 22.414 liters per mole at STP.
Apparatus
Beakers, 400 mL, thermometer, 100 mL graduated cylinder ring stand, thread, centimeter ruler, rubber stopper (one-hole, #00)
Eudiometer, 50 mL Buret clamp
Materials
Magnesium ribbon, untarnished
Hydrochloric acid, 6 M
Safety
Take the necessary safety precautions before beginning this experiment. Wear safety goggles, apron, and gloves. Read all safety cautions in your procedures and discuss them with your teacher. It is important to use good safety techniques while conducting experiments.
Recording Your Observations
Make a copy of the procedure in your notebook. Prepare a data table before starting the lab.
Procedures
1. Fill a 400 mL beaker two-thirds full of water. If possible, use water that has adjusted to room temperature. Obtain a piece of magnesium ribbon from your instructor. Determine the mass of the ribbon using a laboratory balance. Be careful not to touch the magnesium with your hands until you have massed it.
2. Roll the length of magnesium ribbon into a loose coil. Tie it with one end of a piece of thread, approximately 25 cm in length, in such a manner that all the loops of the coil are tied together.
3. This next procedure requires the use of 6 M hydrochloric acid. You may want to practice procedures 4 to 6 by using water in place of the acid. When you have mastered the technique using water, proceed to use the acid.
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CAUTION
Hydrochloric acid is caustic and corrosive. Avoid contact with skin and eyes. Avoid breathing the vapor. Make certain that you are wearing safety goggles, apron, and gloves when working with the acid. If any acid should splash on you, immediately flush the area with water and then report the incident to your teacher. If you should spill any on the counter top or floor, ask your teacher for the appropriate spill package to be used in the clean-up.
4. Carefully pour approximately 10 mL of 6 M hydrochloric acid into a 50 mL beaker. Then pour the 10 mL of 6 M hydrochloric acid into the eudiometer
5. While holding the eudiometer in a slightly tipped position, very slowly pour water from the 400 mL beaker into the eudiometer, being careful to layer the water over the acid so that they do not mix. Add enough water to fill the eudiometer completely.
6. Lower the magnesium coil into the water in the eudiometer to a depth of about 5 cm. Insert the rubber stopper into the open end of the eudiometer to hold the thread in position. See Figure 1. The stopper should displace some water from the eudiometer. This ensures that no air is left inside the.
7. Cover the hole of the stopper with your finger, and invert the eudiometer in the 400 mL beaker of water. Clamp the eudiometer into position on the ring stand, as shown in Figure 11-2. The acid flows down the eudiometer (why?) and reacts with the magnesium. Is the acid now more concentrated or more diluted? Write your observations in your Data Table.
8. When the magnesium has disappeared entirely and the reaction has stopped, cover the stopper hole with a finger and carefully transfer the eudiometer to a 100 mL graduated cylinder or other tall vessel that has been filled with water. Adjust the level of the eudiometer in the water so that the levels of the liquids inside the eudiometer and the cylinder are the same. See Figure 11-3. Read as accurately as possible the volume of hydrogen liberated.
9. Record the room temperature and pressure in your Data Table. These will be recorded on the board.
10. Obtain the vapor pressure of the water at the observed temperature from your text. Record it in your Data Table
|Date Table |
|Mass of Mg used | | |
|Moles of Mg consumed | | |
|Moles of H2 produced | | |
|Temperature | | |
|Barometeric Pressure | | |
|Partial Pressure of H2O | | |
|Partial Pressure of H2 | | |
|Volume of dry H2 | | |
| | | |
Calculations
Show your computations in your lab report.
1. Write the balanced equation for the reaction, include the phases.
2. Find the mass of the magnesium.
3. Calculate the moles of magnesium reacted from the mass reacted.
4. Calculate the partial pressure of the hydrogen collected by subtracting the vapor pressure of water from the air pressure.
Ptot = pp1 + pp2 + ….ppn
5. Calculate the moles of hydrogen produced using the balanced equation.
.
6.Determine the volume of hydrogen produced. Be sure to place the eudiometer in a water to equalize the pressure.
7. Determine the volume of gas that would be generated at STP.
P1V1/T1 = P2V2/T2
8. Determine the liters of gas generated per mole of gas produced at STP.
Error Analysis Compare the volume of hydrogen you produced to the amount of hydrogen you should have produced.
Questions;
1.If oils from your hands were transferred to the metal before massing explain how this might effect your results.
2. If more HCl were added to the eudiometer explain how this might effect your results.
3. If some of the Mg failed to react in the tube explain how this might effect your results.
4. Since the 1930’s aluminum/magnesium alloys have been used in the manufacture of pots and pans. An answered question is whether the small addition of these metals to our food supply is benefirial, harmful, or of no consequence. What are some examples of food that will react with magnesium/aluminum pans?
5.What happened to the other product in this reaction?
Conclusion Summarize the result of this experiment
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