SAFETY DATA SHEET: AMMONIUM CHLORIDE - AMMONIUM …
SAFETY DATA SHEET: AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS
1. IDENTIFICATION
Product Name:
Synonyms:
AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS
Formula and Formula Weight:
Integra numbers beginning with:
Recommended Use:
Restrictions on Use:
Mixture NA
A631.7A
Commercial/industrial use
No information available
INTEGRA Chemical Company
1216 6th Ave N
Kent WA 98032
Phone: 253-479-7000
24 Hour Emergency Response: CHEMTREC 800-424-9300 (Outside USA 703-527-3887)
2. HAZARDS IDENTIFICATION
OSHA Classification:
Hazard Category:
Acute Toxicity - Oral
Skin Corrosion/Irritation
Eye Damage/Irritation
Signal Word:
4
1A
1
Hazard Statement:
Harmful if swallowed.
Causes severe skin burns and eye damage.
Causes serious eye damage.
DANGER
Precautionary Statements
Prevention:
Do not breathe mists.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves, protective clothing, eye protection, face protection.
Response
If swallowed: Rinse mouth. Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water, shower.
If inhaled: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
Immediately call a poison center, doctor.
Specific treatment (see first aid section on this label)
Wash contaminated clothing before reuse.
Storage
Store locked up.
Disposal
Dispose of contents, container in accordance with all governmental regulations.
Hazards Not Otherwise Classified:
No information available
3. COMPOSITION/INFORMATION ON INGREDIENTS
Component
Water
Ammonium chloride
Ammonia
Synonyms
Sal ammoniac; Ammonium muriate
CAS #
07732-18-5
12125-02-9
07664-41-7
% Weight
78.3
6.8
14.9
4. FIRST AID MEASURES
Inhalation:
Eye Contact:
Skin Contact:
Ingestion:
Additional notes:
Remove person to fresh air and keep comfortable for breathing.
Immediately flush eyes with large amounts of water, holding lids apart to ensure rinsing of entire surface. Continue
rinsing for at least 15 minutes. Remove contact lenses, if present and easy to do. Washing eyes within several seconds
of contact is essential to achieve maximum effectiveness. Get immediate medical attention.
Immediately remove contaminated clothing. Flush skin with water for at least 15 minutes. Seek immediate medical
attention.
Do not induce vomiting. If victim is conscious, rinse mouth, give water. Never give anything by mouth to an unconscious
person. Seek immediate medical attention.
Symptoms and effects include burns, cough, shortness of breath, abdominal pains, chest pains, pulmonary edema.
5. FIRE-FIGHTING MEASURES
OSHA SDS #: 25107 rev 101 3/27/2015
AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS
Page 1
Extinguishing Media:
Special Equipment and Precautions:
Material is not flammable. Use extinguishing media suitable to surrounding materials.
Use water to cool nearby containers and structures. Wear full protective equipment, including suitable
respiratory protection.
Fire conditions may liberate toxic and noxious fumes.
Oxides of nitrogen. Ammonia fumes, hydrogen chloride.
Specific Hazards:
Hazardous combustion products:
6. ACCIDENTAL RELEASE MEASURES
Spill Procedures:
Prevent spread of spill. Wear full protective equipment, including a complete protective suit and an appropriate
respirator depending upon the size of the spill. Absorb with sand or inert material. Sweep or scoop into a
disposal container. Carefully neutralize residue with a dilute, inorganic acid solution. Flush spill area with water.
7. HANDLING AND STORAGE
Incompatible Materials:
Storage and Handling:
Incompatible with strong acids and strong oxidizers. Hypochlorite, bromine, chlorine, fluorine, iodine, aluminum,
copper, brass and bronze. Forms explosive compounds with many heavy metals (silver, lead, zinc) and halide
salts
Store locked up in a cool, dry, well-ventilated corrosive materials storage area out of direct sunlight. Do not store
near incompatible materials - especially acids. Keep containers tightly closed and protect them from physical
damage.
Do not breathe mists.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves, protective clothing, eye protection, face protection.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
OSHA & ACGIH Exposure Limits:
Water
None identified
Ammonium chloride
ACGIH TWA: 10 mg/m3 (as fume) ACGIH STEL: 20 mg/m3 (as fume)
Ammonia
Engineering Controls:
Respiratory Protection:
Skin/Eye Protective Equipment:
OSHA TWA: 50 ppm; 35 mg/m3 ACGIH TWA: 25 ppm; 17 mg/m3 ACGIH STEL: 35 ppm; 24 mg/m3
Use general or local exhaust ventilation to meet TLV and PEL requirements.
Respiratory protection required if airborne concentrations exceed PEL or TLV. Use a NIOSH approved chemical
cartridge respirator with an ammonia/methylamine cartridge.
Safety goggles, face shield, chemical-resistant gloves and protective clothing appropriate for the risk of
exposure.
Facilities storing or utilizing this material should have readily accessible eyewash stations and safety showers.
Select respirators and other safety equipment in accordance with regulations and based upon the particular
conditions of use and risk of exposure. Always use safe chemical-handling and good industrial hygiene practices.
9. PHYSICAL AND CHEMICAL PROPERTIES
Apearance:
Odor:
Odor Threshold:
pH:
Melting/Freezing Point:
Initial Boiling Point and Boiling Range:
Flash Point:
Evaporation Rate:
Flammability:
Flammable or Explosive
Limits (% by volume in air)
Vapor Pressure:
Vapor Density:
Relative Density:
Solubility:
Partition Coefficient: n-octanol/water
Auto-Ignition Temperature:
Decomposition Temperature:
Viscosity:
10. STABILITY AND REACTIVITY
Reactivity:
Stability:
Possibility of Hazardous Reactions:
Conditions to Avoid:
Incompatibles:
Decomposition Products:
OSHA SDS #: 25107 rev 101 3/27/2015
Clear, colorless liquid.
Not available
Not available
Not available
Not available
Not available
Not available
Not available
Not flammable
Upper: Not applicable
Lower: Not applicable
Not available
Not available
Not available
Miscible with water.
Not available
Not available
Not available
Not available
No information available
Stable
Hazardous polymerization will not occur
Excessive heat and exposure to light.
Incompatible with strong acids and strong oxidizers. Hypochlorite, bromine, chlorine, fluorine, iodine,
aluminum, copper, brass and bronze. Forms explosive compounds with many heavy metals (silver, lead,
zinc) and halide salts
Oxides of nitrogen. Ammonia fumes, hydrogen chloride.
AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS
Page 2
11. TOXICOLOGICAL INFORMATION
Effects of Over Exposure:
Inhalation:
Skin Contact:
Eye Contact:
Ingestion:
Chronic Effects:
Target Organs:
Additional Effects:
Reproductive Effects:
Carcinogenicity:
Harmful if inhaled. Irritating to the nose and throat, severely irritating to the respiratory system. Overxposure may cause
coughing, difficulty in breathing, chest pains and pulmonary edema.
Corrosive material. Contact may cause severe burns.
Contact may cause severe irritation or burns.
Harmful if swallowed. Ingestion may cause nausea, vomiting and gastrointestinal irritation and burns to the mouth and
throat.
Damage to mucous membranes, respiratory tract, eyes, skin.
Eyes, skin, respiratory system.
May aggravate pre-existing skin disorders, eye disorders, respiratory system disease
No information available
None identified
Toxicity Data:
Water
Ammonium chloride
No information available
LDlo (skin, mouse)
LD50 (oral, rat)
LC50 (inhalation, mouse)
LClo (inhalation, human)
Ammonia
500
1650
4230
5000
mg/kg
mg/kg
ppm/1hr
ppm/5 min
12. ECOLOGICAL INFORMATION
Aquatic Toxicity Data:
Terrestrial Toxicity Data:
Water
No information available
No information available
Ammonium chloride
LC50 Cyprinus carpio: 209 mg/L - 96h; LC No information available
Ammonia
No information available
Persistence and degradability:
Bioaccumulative potential:
Mobility in soil:
Other adverse effects:
No information available
No information available
No information available
No information available
No information available
13. DISPOSAL CONSIDERATIONS
Disposal Procedures: Dispose of material and containers in accordance with all local, state and federal regulations.
14. TRANSPORTATION INFORMATION
This product is a regulated material for domestic ground transporation, per CFR Title 49.
UN Number:
Proper Shipping Name:
Packing Group:
Hazard Class:
UN2672
Ammonia solution
III
8
Environmental hazards:
Special precautions:
No information available
No information available
Bulk transport:
No information available
15. REGULATORY INFORMATION
Ammonium chloride is listed in the TSCA inventory.
Ammonia is listed in the TSCA inventory, in SARA 302, and in SARA 313.
16. OTHER INFORMATION
OSHA SDS #: 25107 rev 101 3/27/2015
NE = Not established, NA = Not applicable or Not available
The information presented above is offered for informational purposes only. This SDS, and the associated product, is intended for use only by technically qualified
persons, and at their own discretion and risk. Since conditions and manner of use are outside the control of Integra Chemical Company, we make no warranties, either
expressed or implied, and assume no liability in connection with any use of this information.
***** END OF SDS *****
OSHA SDS #: 25107 rev 101 3/27/2015
AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS
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