SAFETY DATA SHEET NALCO® EC6359A - ASCO

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 NALCO? EC6359A

Section: 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: Substance type:

NALCO? EC6359A CLP Mixture

1.2 Relevant identified uses of the substance or mixture and uses advised against:

Use of the Substance/Mixture

: SCALE INHIBITOR

Recommended restrictions on use : Reserved for industrial and professional use.

1.3 Details of the supplier of the safety data sheet:

COMPANY IDENTIFICATION NALCO EUROPE B.V. Postbus 627

2300 AP Leiden, The Netherlands TEL: 0031 71 5241100

LOCAL COMPANY IDENTIFICATION Nalco Ltd.

P.O. BOX 11, WINNINGTON AVENUE NORTHWICH, CHESHIRE, U.K. CW8 4DX

TEL: +44 (0)1606 74488

For Product Safety information please contact: msdseame@

1.4 Emergency telephone number:

+32-(0)3-575-5555 Trans-European

Date of Compilation/Revision: Version Number:

03.08.2015 3.0

Section: 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Not a hazardous substance or mixture. Classification (67/548/EEC, 1999/45/EC)

R52/53

For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements Labelling (REGULATION (EC) No 1272/2008)

Not a hazardous substance or mixture.

Precautionary Statements

: Prevention: P264 Response: P322 Storage:

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Wash hands thoroughly after handling. Specific measures: consult SDS Section 4.

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 NALCO? EC6359A

P401

Store in accordance with local regulations.

Special labelling of certain mixtures

2.3 Other hazards

None known.

: Safety data sheet available on request.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

Hazardous components

Chemical Name

Sodium 2hydroxyethylamino bis(methylenephosphon

ate) Ethylene Glycol

CAS-No. EC-No. REACH No. 22036-78-8 244-743-0 01-2119972938-15

107-21-1 203-473-3 01-2119456816-28

Classification (67/548/EEC)

R52/53

Classification (REGULATION (EC) No

1272/2008) Chronic aquatic toxicity

Category 3; H412

Concentration: [%]

30 - < 50

Xn; R22-R48/22

Acute toxicity Category 4; H302

Specific target organ toxicity repeated exposure Category

2; H373

2.5 - < 5

For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16.

Section: 4. FIRST AID MEASURES

4.1 Description of first aid measures

If inhaled

: Get medical attention if symptoms occur.

In case of skin contact

: Wash off with soap and plenty of water. Get medical attention if symptoms occur.

In case of eye contact

: Rinse with plenty of water. Get medical attention if symptoms occur.

If swallowed

: Rinse mouth. Get medical attention if symptoms occur.

Protection of first-aiders

: In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders.Use personal protective equipment as required.

4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.

4.3 Indication of immediate medical attention and special treatment needed

Treatment

: No specific measures identified.

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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 NALCO? EC6359A

Section: 5. FIREFIGHTING MEASURES

5.1 Extinguishing media Suitable extinguishing media

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

: Do not use water unless flooding amounts are available.

5.2 Special hazards arising from the substance or mixture

Specific hazards during firefighting

: Not flammable or combustible.

Hazardous combustion products

: Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus

5.3 Advice for firefighters

Special protective equipment for firefighters

: Use personal protective equipment.

Further information

: Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Section: 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel Advice for emergency responders

: Refer to protective measures listed in sections 7 and 8.

: If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials.

6.2 Environmental precautions Environmental precautions

: No special environmental precautions required.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up

: Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.

6.4 Reference to other sections

See Section 1 for emergency contact information. For personal protection see section 8.

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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 NALCO? EC6359A

See Section 13 for additional waste treatment information.

Section: 7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling

: For personal protection see section 8. Wash hands after handling.

Hygiene measures

: Wash hands before breaks and immediately after handling the product.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers.

Suitable material

: The following compatibility data is suggested based on similar product data and/or industry experience: Viton, Neoprene, Stainless Steel 304, Stainless Steel 316L, Nitrile, EPDM, FEP (encapsulated), HDPE (high density polyethylene), MDPE (medium density polyethylene)

Unsuitable material

: The following compatibility data is suggested based on similar product data and/or industry experience: Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use., Carbon Steel C1018

7.3 Specific end uses Specific use(s)

: SCALE INHIBITOR

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters OCCUPATIONAL EXPOSURE LIMITS

Components

Ethylene Glycol

CAS-No. 107-21-1

107-21-1

107-21-1

Value type (Form of exposure) TWA (Vapour.)

Control parameters 20 ppm 52 mg/m3

STEL (Vapour.)

40 ppm 104 mg/m3

TWA (particles)

10 mg/m3

Update 2011-12-01

2011-12-01

2011-12-01

Basis UKCOSSTD

UKCOSSTD

UKCOSSTD

MONITORING MEASURES

A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which

can then be desorbed or removed and analyzed as referenced below:

Substance(s)

Method

Analysis

Absorbant

Ethylene Glycol

US NIOSH: 5523

Gas chromatography

XAD-7 / Glass

fibre filter OVS

tube

DNEL

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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 NALCO? EC6359A

Sodium 2-hydroxyethylamino bis(methylenephosphonate)

Ethylene Glycol

: End Use: Workers Exposure routes: Inhalation Potential health effects: Long-term systemic effects Value: 9.4 mg/m3

End Use: Workers Exposure routes: Inhalation Potential health effects: Acute systemic effects Value: 9.4 mg/m3

End Use: Workers Exposure routes: Dermal Potential health effects: Long-term systemic effects Value: 2.7 mg/cm2

End Use: Workers Exposure routes: Dermal Potential health effects: Acute systemic effects Value: 2.7 mg/cm2

End Use: Workers Exposure routes: Ingestion Potential health effects: Long-term systemic effects Value: 2.7 ppm

End Use: Workers Exposure routes: Ingestion Potential health effects: Acute systemic effects Value: 2.7 ppm

End Use: Consumers Exposure routes: Inhalation Potential health effects: Long-term systemic effects Value: 2.3 mg/m3

End Use: Consumers Exposure routes: Inhalation Potential health effects: Acute systemic effects Value: 2.3 mg/m3

End Use: Consumers Exposure routes: Dermal Potential health effects: Long-term systemic effects Value: 1.3 mg/cm2

End Use: Consumers Exposure routes: Dermal Potential health effects: Acute systemic effects Value: 1.3 mg/cm2

End Use: Consumers Exposure routes: Ingestion Potential health effects: Long-term systemic effects Value: 1.3 ppm

End Use: Consumers Exposure routes: Ingestion Potential health effects: Acute systemic effects Value: 1.3 ppm

: End Use: Workers Exposure routes: Skin contact Potential health effects: Long-term systemic effects Value: 106 mg/cm2

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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

NALCO? EC6359A

End Use: Workers Exposure routes: Dermal Potential health effects: long term - systemic

End Use: Workers Exposure routes: Inhalation Potential health effects: Long-term systemic effects Value: 35 mg/m3

End Use: Workers Exposure routes: Inhalation Potential health effects: long-term - local Value: 35 mg/m3

End Use: Consumers Exposure routes: Skin contact Potential health effects: Long-term systemic effects Value: 53 mg/cm2

End Use: Consumers Exposure routes: Inhalation Potential health effects: Long-term systemic effects Value: 7 mg/m3

PNEC Sodium 2-hydroxyethylamino bis(methylenephosphonate)

Ethylene Glycol

: Fresh water Value: 0.032 mg/l

Marine water Value: 0.0032 mg/l

Marine water Value: 0.032 mg/l Other conditions

Intermittent use/release Value: 0.32 mg/l

Fresh water sediment Value: 8.9 mg/kg

Marine sediment Value: 0.89 mg/kg

Marine sediment Value: 8.9 mg/kg Other conditions

Sewage treatment plant Value: 46 mg/l

Soil Value: 3.5 mg/kg

: Fresh water Value: 10 mg/l

Marine water Value: 1 mg/l

Intermittent release Value: 10 mg/l

Fresh water sediment

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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 NALCO? EC6359A

Value: 20.9 mg/kg Water Value: 1995.5 mg/l Soil Value: 1.53 mg/kg

8.2 Exposure controls

Appropriate engineering controls

Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Individual protection measures

Hygiene measures

: Wash hands before breaks and immediately after handling the product.

Eye/face protection (EN 166) : Safety glasses

Hand protection (EN 374)

: Wear protective gloves. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Skin and body protection (EN : Wear suitable protective clothing. 14605)

Respiratory protection (EN 143, 14387)

: Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended.A suitable filter material depends on the amount and type of chemicals being handled.Consider the use of filter type:A-PB-PIf respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection.In event of emergency or planned entry into unknown concentrations a positive pressure, fullfacepiece SCBA should be used.

Environmental exposure controls

General advice

: Consider the provision of containment around storage vessels.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance

: Liquid

Colour Odour Flash point

: colourless : Mild : > 93.3 ?C

pH

: 3 - 4.2, 100 %

(25 ?C)

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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 NALCO? EC6359A

Odour Threshold

: no data available

Melting point/freezing point : MELTING POINT: -15 ?C, ASTM D-97

Initial boiling point and boiling : 100 ?C range

Evaporation rate

: no data available

Flammability (solid, gas)

: no data available

Upper explosion limit

: no data available

Lower explosion limit

: no data available

Vapour pressure

: no data available

Relative vapour density

: no data available

Relative density

: 1.256 (16 ?C)

Density

: 1.25 g/cm3

Solubility(ies)

Water solubility

: completely soluble

Solubility in other solvents

: no data available

Partition coefficient: noctanol/water

: no data available

Auto-ignition temperature

: no data available

Thermal decomposition temperature

: no data available

Viscosity Viscosity, dynamic Viscosity, kinematic

: no data available

: 3.6 mm2/s (40 ?C) Method: ASTM D 445

Explosive properties Oxidizing properties 9.2 Other information no data available

: no data available : no data available

Section: 10. STABILITY AND REACTIVITY

10.1 Reactivity

No dangerous reaction known under conditions of normal use.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous reactions

: No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid Conditions to avoid

: None known.

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