PURELL® Advanced Instant Hand Sanitizer
SAFETY DATA SHEET
PURELL? Advanced Instant Hand Sanitizer
Version 1.1
Revision Date: 02/10/2015
MSDS Number: 36762-00002
Date of last issue: 12/12/2014 Date of first issue: 12/12/2014
SECTION 1. IDENTIFICATION Product name
: PURELL? Advanced Instant Hand Sanitizer
Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc.
Address
: One GOJO Plaza, Suite 500 Akron OH 44311
Telephone
: 1 (330) 255-6000
Emergency telephone
: 1-800-424-9300 CHEMTREC
Recommended use of the chemical and restrictions on use
Recommended use
: Hand Sanitizer
Restrictions on use
: This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification Flammable liquids
Eye irritation
: Category 3 : Category 2A
GHS Label element
Hazard pictograms
:
Signal Word Hazard Statements
: Warning : H226 Flammable liquid and vapor.
H319 Causes serious eye irritation.
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SAFETY DATA SHEET
PURELL? Advanced Instant Hand Sanitizer
Version 1.1
Revision Date: 02/10/2015
MSDS Number: 36762-00002
Date of last issue: 12/12/2014 Date of first issue: 12/12/2014
Precautionary Statements
: Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards Vapors may form explosive mixture with air.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture
: Mixture
Hazardous ingredients
Chemical Name Ethanol Propan-2-ol
CAS-No. 64-17-5 67-63-0
Concentration (%) >= 50 - < 70 >= 1 - < 5
SECTION 4. FIRST AID MEASURES
General advice
: In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
If inhaled
: If inhaled, remove to fresh air. Get medical attention if symptoms occur.
In case of skin contact
: Wash with water and soap as a precaution. Get medical attention if symptoms occur.
In case of eye contact
: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn.
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SAFETY DATA SHEET
PURELL? Advanced Instant Hand Sanitizer
Version 1.1
Revision Date: 02/10/2015
MSDS Number: 36762-00002
Date of last issue: 12/12/2014 Date of first issue: 12/12/2014
If swallowed
Most important symptoms and effects, both acute and delayed Protection of first-aiders
Notes to physician
Get medical attention.
: If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.
: Causes serious eye irritation.
: First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.
: Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
: Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2)
Unsuitable extinguishing media
: High volume water jet
Specific hazards during fire fighting
: Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health.
Hazardous combustion prod- : Carbon oxides ucts
Specific extinguishing methods
: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters
Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
: Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations.
Environmental precautions : Discharge into the environment must be avoided.
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SAFETY DATA SHEET
PURELL? Advanced Instant Hand Sanitizer
Version 1.1
Revision Date: 02/10/2015
MSDS Number: 36762-00002
Date of last issue: 12/12/2014 Date of first issue: 12/12/2014
Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for containment and cleaning up
: Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures
: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation
: Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation.
Advice on safe handling
: Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment.
Conditions for safe storage
: Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition.
Materials to avoid
: Do not store with the following product types: Strong oxidizing agents
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SAFETY DATA SHEET
PURELL? Advanced Instant Hand Sanitizer
Version 1.1
Revision Date: 02/10/2015
MSDS Number: 36762-00002
Date of last issue: 12/12/2014 Date of first issue: 12/12/2014
Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Ingredients
CAS-No.
Value type (Form of exposure)
Ethanol
64-17-5
TWA
TWA
Propan-2-ol
67-63-0
STEL TWA STEL TWA
ST
TWA
Control parameters / Permissible concentration 1,000 ppm 1,900 mg/m3 1,000 ppm 1,900 mg/m3 1,000 ppm 200 ppm 400 ppm 400 ppm 980 mg/m3 500 ppm 1,225 mg/m3 400 ppm 980 mg/m3
Basis
NIOSH REL OSHA Z-1 ACGIH ACGIH ACGIH NIOSH REL NIOSH REL OSHA Z-1
Biological occupational exposure limits
Ingredients
CAS-No. Control parameters
Propan-2-ol
67-63-0 Acetone
Biological specimen
Urine
Sampling time
End of shift at end of workweek
Permissible Basis
concentratio
n
40 mg/l
ACGIH
BEI
Engineering measures
: Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation.
Personal protective equipment
Respiratory protection
: General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and
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