Composite Overwrapped Pressure Vessels Material …
Composite Overwrapped Pressure Vessels Material Development
Amit K. Naskar Carbon & Composites Group Oak Ridge National Laboratory
U.S. Department of Energy Workshop: Compressed Gas Storage for Medium and Heavy Duty Transportation Dayton, Ohio
January 21, 2020
ORNL is managed by UT-Battelle, LLC for the US Department of Energy
Hydrogen Storage Tank ? Cost Analysis
Carbon fiber composite layer shares the significant cost (75-80%) of the hydrogen fuel system Low-cost carbon fiber (LCCF) is needed for Hydrogen or CNG storage tank Simmons et al. AMR presentation 2013
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Nature of the gas
3
Simmons et al. AMR Presentation slide #24, 2013
COV in fiber properties plays significant role in this cost analysis.
LCCF must have consistent properties.
Outline
? Update on research status and future affordability perspective on the US manufactured carbon fibers
? Interfacial engineering of carbon fiber composites ? Devising composite tanks with health monitoring tools ? Thermoplastic liners and studies to reduce permeability
4
Globally studied precursor candidates
? Specialty acrylic fibers (SAF)
? High molecular weight polyacrylonitrile (PAN)
? Textile and PAN Variants (FISIPE, Sterling, Blue Star, Kaltex, Taekwang, Thai Acrylic, Montefibre)
? Renewable acrylonitrile
? Variant PAN compositions (comonomer variation)
? Melt-processible PAN precursors
? Polyolefin (polyethylene)
? Pitch precursors
? Mesophase synthesis ? Natural gas (for CNT yarn) ? Cellulosic precursor
Defect density
? Lignin (MeadWestvaco/GrafTech)
Long-range order
? Spider silk
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