11.1 Oil, water, and dish soap (polarity and emulsions)

UMassAmherstDepartmentofChemistry

LectureDemonstrations

11.1Oil,water,anddishsoap(IntermolecularforcesI) Subjects:Propertiesofliquids,intermolecularforces Description:Cookingoilandwaterareusedtoillustratethatpolarandnon-polar substancesdonotmix.Whendishsoapisadded,anemulsioniscreatedbyallowing thedispersionofoilintowater. Materials: Cookingoil Water(optional:addfoodcoloringtomakeitmorevisible) Dishwashingsoap 2500mLErlenmeyerflaskswithstoppers Procedure: Note:Usethedemocameratodisplaytheprocedure. 1.Pourwaterandoilintooneflask.Observehowtheoil"floats"ontopofthewater andthattheydon'tmixspontaneously. 2.Stopperandagitatetocreateanemulsion.Letthemixturestandandwithinafew moments,thelayerswillseparate. 3.Addoil,wateranddishsoaptothesecondflask. 4.Shaketheflasktomixthecontents.Inthepresenceoftheemulsifier,theemulsion willpersist. Discussion: "Likedissolveslike".Waterandethanolwillmixtoformahomogenousmixture,but oilandwaterdonot.Bothwaterandethanolarepolarmolecules.Theymixbecause oftheabilityoftheirdipolestointeract.Theenergyofattractionbetweenthetwo moleculesisenoughtoovercometheenergyexpendedinmixing.Oilisnon-polar andthusthereisnoattractionbetweenthetwomolecules. Anemulsionisadispersionofoneliquidintoanother.Anemulsifyingagentisadded toattainstabilityoftheemulsion.Someexamplesofemulsionsarehomogenized milk,butter,mayonnaise,andgravy.Inmayonnaisetheeggyolkistheemulsifier andingravyflouristheemulsifierthatallowsthewaterandthefattomix.Inthis demonstration,thedishsoapistheemulsifyingagent.Theemulsifyingactionof soapallowsgreaseandoiltoberemovedfromobjectsbeingcleaned. Safety:None Disposal:Solutionscanbepoureddownthedrain. References: 1.B.Z.Shakhashiri;ChemicalDemonstrations:AHandbookforTeachersofChemistry; Volume3;Wisconsin;1989;p.351-352 2.NCSUChemistryDepartmentLecturedemonstrationwebsite:

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UMassAmherstDepartmentofChemistry

LectureDemonstrations



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