PEAK Windshield Wash and Deicer -20 ºF

[Pages:9]PEAK Windshield Wash and Deicer -20 ?F

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Revision date: 06/26/2017

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1.

Product identifier

Product form

: Mixture

Product name

: PEAK Windshield Wash and Deicer -20 ?F

1.2.

Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

: Windshield washer fluid

1.3.

Details of the supplier of the safety data sheet

Old World Industries, LLC 4065 Commercial Ave. Northbrook, IL 60062 - USA T (847) 559-2000

1.4.

Emergency telephone number

Emergency number

: (800) 424-9300; (703) 527 3887 (International) Chemtrec

SECTION 2: Hazards identification

2.1.

Classification of the substance or mixture

GHS-US classification

Flammable liquids, Category 3 Acute toxicity (oral), Category 4 Acute toxicity (dermal), Category 3 Acute toxicity (inhalation:dust,mist) Category 4 Specific target organ toxicity -- single exposure, Category 1

H226 H302 H311 H332

H370

Full text of H statements : see section 16

2.2.

Label elements

GHS-US labelling

Hazard pictograms (GHS-US)

:

Flammable liquid and vapor Harmful if swallowed Toxic in contact with skin Harmful if inhaled

Causes damage to organs (May cause blindness if swallowed)

Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US)

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GHS02

GHS06

GHS08

: Danger

: H226 - Flammable liquid and vapor H302+H332 - Harmful if swallowed or if inhaled H311 - Toxic in contact with skin H370 - Causes damage to organs (May cause blindness if swallowed)

: P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P233 - Keep container tightly closed P240 - Ground/Bond container and receiving equipment P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P260 - Do not breathe mist, spray, vapors P264 - Wash affected areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area

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PEAK Windshield Wash and Deicer -20 ?F

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

P280 - Wear personal protective equipment as required P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P307+P311 - If exposed: Call a poison center/doctor P301+P310 - If swallowed: Immediately call doctor/physician or poison center. Rinse Mouth P312 - Call doctor/physician or poison center if you feel unwell P361+P364 - Take off immediately all contaminated clothing and wash it before reuse P370+P378 - In case of fire: Use Carbon dioxide, Dry powder, foam, sand to extinguish P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local/regional/national/international regulations

2.3.

Other hazards

No additional information available

2.4.

Unknown acute toxicity (GHS US)

No data available

SECTION 3: Composition/information on ingredients

3.1.

Substances

Not applicable

3.2.

Mixtures

Name

water

Product identifier

(CAS-No.) 7732-18-5

% by wt

>= 67

GHS-US classification

Not classified

methanol

(CAS-No.) 67-56-1

Full text of hazard classes and H-statements : see section 16

5,000.00 mg/kg (Rat; BASF test; Literature study; 1187-2769 mg/kg bodyweight; Rat; Weight of evidence) 15,800.00 mg/kg (Rabbit; Literature study) 85.00 mg/l/4h (Rat; Literature study) 64,000.00 ppm/4h (Rat; Literature study) 100.00 mg/kg bodyweight 300.00 mg/kg bodyweight 700.00 ppmv/4h 3.00 mg/l/4h 0.50 mg/l/4h

Skin corrosion/irritation

: Not classified

Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity

: Not classified : Not classified : Not classified

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PEAK Windshield Wash and Deicer -20 ?F

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Carcinogenicity

: Not classified

Reproductive toxicity

: Not classified

Specific target organ toxicity (single exposure) : Causes damage to organs (May cause blindness if swallowed) .

Specific target organ toxicity (repeated exposure)

: Not classified

Aspiration hazard Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion Chronic symptoms

: Not classified

: High concentrations may cause central nervous system characterized by severe headaches, dizziness, nausea and confusion. May cause irritation of the nose and throat.

: Prolonged exposure to skin may cause skin irritation experienced as burning, dryness, cracking and redness.

: May cause severe irritation.

: May cause nausea, abdominal pain, headache, shortness of breath, visual impairment and blindness. Severe poisoning can lead to coma and death.

: ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin, Dry skin, Skin rash/inflammation, Headache, Feeling of weakness, Disturbed tactile sensibility, Visual disturbances, Sleeplessness, Gastrointestinal complaints, Cardiac and blood circulation effects.

SECTION 12: Ecological information

12.1. Toxicity

methanol (67-56-1) LC50 fish 1

EC50 Daphnia 1

LC50 fish 2

15,400.00 mg/l (LC50; EPA 660/3 - 75/009; 96 h; Lepomis macrochirus; Flow-through system; Fresh water; Experimental value)

> 10,000.00 mg/l (EC50; DIN 38412-11; 48 h; Daphnia magna; Static system; Fresh water; Experimental value)

10,800.00 mg/l (LC50; 96 h; Salmo gairdneri)

12.2. Persistence and degradability methanol (67-56-1) Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD)

Readily biodegradable in water. Biodegradable in the soil. Highly mobile in soil. 0.6 - 1.12 g O2/g substance 1.42 g O2/g substance 1.50 g O2/g substance 0.80 (Literature study)

12.3. Bioaccumulative potential

methanol (67-56-1) BCF fish 1 Log Pow Bioaccumulative potential

< 10.00 (BCF; 72 h; Leuciscus idus) -0.77 (Experimental value; Other) Low potential for bioaccumulation (BCF < 500).

12.4. Mobility in soil

methanol (67-56-1) Surface tension Log Koc

0.02 N/m (20 ?C) Koc,PCKOCWIN v1.66; 1; Calculated value

12.5. Other adverse effects Effect on ozone layer

Effect on global warming

: No known effect on the ozone layer : No known effects from this product.

Other information

: Avoid release to the environment.

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PEAK Windshield Wash and Deicer -20 ?F

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 13: Disposal considerations

13.1. Waste treatment methods Product/Packaging disposal recommendations

Ecology - waste materials

: Dispose of contents/container to appropriate waste disposal facility, in accordance with local/regional/national/international regulations.

: Avoid release to the environment.

SECTION 14: Transport information

Department of Transportation (DOT) In accordance with DOT

Transport document description

: NA1993 Combustible liquid, n.o.s., 3, III

UN-No.(DOT)

: NA1993

Proper Shipping Name (DOT)

: Combustible liquid, n.o.s.

Class (DOT)

: 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120

Packing group (DOT)

: III - Minor Danger

DOT Packaging Non Bulk (49 CFR 173.xxx)

: 203

DOT Packaging Bulk (49 CFR 173.xxx)

: 241

DOT Symbols

: D - Proper shipping name for domestic use only, or to and from Canada,G - Identifies PSN requiring a technical name

DOT Packaging Exceptions (49 CFR 173.xxx) : 150

DOT Quantity Limitations Passenger aircraft/rail : 60 L (49 CFR 173.27)

DOT Quantity Limitations Cargo aircraft only (49 : 220 L CFR 175.75)

DOT Vessel Stowage Location

: A - The material may be stowed ``on deck'' or ``under deck'' on a cargo vessel and on a passenger vessel.

Emergency Response Guide (ERG) Number : 128

Other information

: In inner packaging no more than 5.0 L: Proper Shipping Name: Limited Quantity of Class III Per 49 CFR Part 173.10 (PG III, inner packaging no more than 5.0L).

Transportation of Dangerous Goods Refer to current TDG Canada for further Canadian regulations

Transport by sea

UN-No. (IMDG) Transport document description (IMDG) Class (IMDG) Packing group (IMDG) Limited quantities (IMDG) Limited quantities (IMDG)

: 1992

: UN 1992 Flammable Liquid, Toxic, n.o.s. (methanol) , 3, III

: 3 - Flammable liquids

: III - substances presenting low danger

: 5L

: In Non-Bulk quantities with inner packaging no more than 5.0L: Proper Shipping Name: Dangerous Goods in Limited Class 3 (Windshield Wash Containing Methanol) Packages or pallets must be marked "Dangerous Goods in Limited Quantities of Class 3" Outer Package cannot weigh more than 30 kg.

Air transport

UN-No. (IATA) Transport document description (IATA) Class (IATA) Packing group (IATA) Subsidiary risks (IATA) Instruction "passenger" - Limited quantities (ICAO)

: 1992 : UN 1992 Flammable Liquid, Toxic, n.o.s. (methanol), 3 (6.1), III : 3 - Flammable Liquids : III - Minor Danger : 6.1 - Toxic substances : Y343 (Max qty. per package 2.0L) Special Provision A3

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PEAK Windshield Wash and Deicer -20 ?F

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 15: Regulatory information

15.1. US Federal regulations

PEAK Windshield Wash and Deicer -20 ?F EPA TSCA Regulatory Flag SARA Section 302 Threshold Planning Quantity (TPQ) SARA Section 311/312 Hazard Classes

SARA Section 313 - Emission Reporting

Toxic Substances Control Act (TSCA): The intentional ingredients of this product are listed

None

Delayed (chronic) health hazard Fire hazard Immediate (acute) health hazard

33 % (Methanol CAS # 67-56-1)

methanol (67-56-1) CERCLA RQ

5000 lb(s) (2270 kg)

water (7732-18-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory

15.2. International regulations

CANADA PEAK Windshield Wash and Deicer -20 ?F WHMIS Classification

This SDS has been prepared according to the criteria of the Hazardous Products Regulations (HPR) (WHMIS 2015) and the SDS contains all of the information required by the HPR. Applicable GHS information is listed in section 2.2 of this SDS.

EU-Regulations No additional information available

National regulations PEAK Windshield Wash and Deicer -20 ?F DSL (Canada): The intentional ingredients of this product are listed ECL (South Korea): The intentional ingredients of this product are listed. EINECS (Europe): The intentional ingredients of this product are listed ENCS (Japan): The intentional ingredients of this product are listed

15.3. US State regulations

California Proposition 65 - This product contains, or may contain, substance(s) known to the state of California to cause cancer, developmental toxicity and/or reproductive toxicity

methanol (67-56-1)

U.S. - California Proposition 65 Carcinogens List

No

U.S. - California Proposition 65 Developmental Toxicity

Yes

U.S. - California Proposition 65 Reproductive Toxicity Female

No

U.S. - California Proposition 65 Reproductive Toxicity Male

No

No significant risk level (NSRL)

methanol (67-56-1)

U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List

SECTION 16: Other information

Revision date

: 06/26/2017

06/26/2017

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