PRACTICE PROBLEMS FOR BRONSTED-LOWRY ACID-BASE CHEMISTRY
ORGANIC CHEMISTRY I PRACTICE PROBLEMS FOR BRONSTED-LOWRY ACID-BASE CHEMISTRY
1. For each of the species below, identify the most acidic proton and provide the structure of the corresponding conjugate base. You might want to draw detailed Lewis formulas in some cases.
HF CH3CH2OH
H3O H2O RNH3
CH3CH3 CH3CN HC CH
H2 CH3OH2
2. For each of the species below, identify the basic atom and provide the structure of the corresponding conjugate acid. You might want to draw detailed Lewis formulas in some cases.
CN _2 SO4
CH3CH2O OH
CH3CH2OH
PhCOO
H2O
Br
OO NH2
3. Fill in the reactants or products for the following acid-base reactions. Keep in mind that in line-angle formulas hydrogens are not shown. When in doubt, write complete Lewis structures. Abbreviations used: Ph=phenyl (a benzene ring attached to a carbon chain)
HNO3 + H2O
O
H3C
+ OH CH3
F + H3O PhCOO + HCl
H2CO3 + OH
+ H2O
NH3 + HC C
OH + H
4. Arrange the substances by order of acidity or basicity as indicated. You may use pKa tables, periodic tables, or any other tools available to you (except for your cell phone).
H2Se H2O H2S weakest acid
strongest acid
Br F I Cl strongest base
weakest base
CH4 HI PH3 H2Se strongest acid
F OH NH2 CH3CH2CH2CH2
weakest basse CH3CH2OH CH3COOH HF Benzene
weakest acid
weakest acid strongest base strongest acid
5. Circle the side favored by equilibrium in the following acid-base reactions.
CN + NH3
HCN + NH2
O
OH
+ H3C
CH2
O
O
+ H3C CH3
H2O +
NH3
H3O +
NH2
H2CO3 + H2O
CH3CH2CH2CH3 +
CH2
HCO3 + H3O CH3CH2CH2CH2 +
CH3
6. The conjugate acid of ammonia, NH3, is:
A) NH4+ B) NH2OH
C) NH2- D) none of the above
7. Methanesulfonic acid, CH3SO3H, has a pKa of -7 while ethanol, CH3CH2OH, has a pKa of 15.9. Which is the stronger acid and what accounts for this large difference in relative acidity?
8. Would you predict trifluoromethanesulfonic acid, CF3SO3H, to be a stronger or weaker acid than methanesulfonic acid, CH3SO3H? Explain your reasoning.
9. Consider the species CH3O-, NH2-, and CH3COO-. Rank these ions in order of increasing basicity, and explain your rationale.
10. The Ka of formic acid is 1.7 x 10-4. The pKa of formic acid is __________.
A) 1.7
B) 10.3
C) 4.0
D) 3.8
E) -2.3
11. Provide the structure of the conjugate base of phenol (shown below) and all its resonance forms.
OH
12. Rank the following in order of increasing acidity: CH OH, HCl, NH , and CH .
3
3
4
13. Rank the following in order of increasing basicity: CH O-, H N-, H O, and NH .
3
2
2
3
14. When methanol (CH OH) acts as a base, its conjugate acid is __________. 3
A) CH OH 4
B) CH OH + 32
C) CH O+ 4
D) CH O3
E) -CH OH 2
15. Which of the following pairs of bases lists the stronger base first?
A) H O > HO2
B) H N- > CH COO-
2
3
C) CH COO- > HO3
D) I- > Cl-
E) HO- > H N2
16. Draw the structure of the conjugate acid of acetone (CH COCH ).
3
3
ANSWERS
1.
HF
F
CH3CH2OH H3O H2O RNH3
CH3CH3O H2O OH
RNH2
CH3CH3 CH3CN HC CH
H2 CH3OH2
CH3CH2 CH2CN HC C
H CH3OH
2.
CN
HCN
_2 SO4
HSO4
CH3CH2OH
CH3CH2OH2
H2O
H3O
OO
OO
CH3CH3O OH
PhCOO Br
NH2
CH3CH2OH H2O
PhCOOH HBr
NH3
................
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