Green Chemistry: Principles and Practice - American Chemical Society

Green Chemistry: Principles and Practice

Mary M. Kirchhoff Summer School on Green Chemistry

and Sustainable Energy 23 July 2013

What Is Green Chemistry?

Green chemistry is the design of chemical products and processes that reduce or eliminate the use and generation of hazardous substances.

Growth in U.S.

Environmental Regulations

120 110 100

90 80 70 60 50 40 30 20 10

YA

0 1870 1880

RHA

NBRAWA AA IA

NPS

TA FWCA

BPA MBCA

1890 1900 1910 1920 1930

AMFA ARPAA

AJA ASBCAA ESAA-AECA

FFRAA FEAPRA

IRA NWPAA CODRA/NMSPAA FCRPA MMPAA

AQ A NAWCA

APA SWDA CERCLA CZMIA COWLDA FWLCA MPRSAA CAAA

CWA SMCRA SWRCA SDWAA

RCRAA WLDI

WQA

NWPA

ARPA

MPRSAA

BLBA FWPCA MPRSA

CZMA NCA

FEPCA PWSA MMPA

HMTA ESA TAPA

AQA FOIA

FCMHSA

FRRRPA SOWA DPA

WRPA AFCA

FHSA NFMUA AEPA FIFRA PAA

NHPA

FAWRA NLRA WPA

WLDA FWCAA FWA AEA

WSRA EA RCFHSA

EPACT FFCA CERFA CRAA PPA PPVA IEREA ANTPA GLCPA ABA CZARA WRDA EDP OPA RECA CAAA GCRA GLFWRA HMTUSA NEEA

SDWAA SARA BLRA ERDDAA EAWA NOPPA PTSA UMTRCA ESAA QGA NCPA TSCA FLPMA RCRA NFMA CZMAA NEPA EQIA CAA EPA EEA OSHA FAWRAA NPAA

1940 1950 1960 1970 1980 1990 2000

Number of Law s

Pollution Prevention Act of 1990

Pollution Prevention

Source Reduction Recycling

Treatment

Disposal

12 Principles

1. Prevention 2. Atom Economy 3. Less Hazardous Chemical Syntheses 4. Designing Safer Chemicals 5. Safer Solvents and Auxiliaries 6. Design for Energy Efficiency 7. Use of Renewable Feedstocks 8. Reduce Derivatives 9. Catalysis 10. Design for Degradation 11. Real-time Analysis for Pollution Prevention 12. Inherently Safer Chemistry for Accident Prevention

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