192nd Fall Technical Meeting of the Rubber Division ...

192nd Fall Technical Meeting of the Rubber Division, American Chemical Society 2017

Cleveland, Ohio, USA 10-12 October 2017 Volume 1 of 3

ISBN: 978-1-5108-5535-9

Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571

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Copyright? (2017) by Rubber Division, American Chemical Society All rights reserved. Printed by Curran Associates, Inc. (2018) For permission requests, please contact Rubber Division, American Chemical Society at the address below. Rubber Division, American Chemical Society 411 Wolf Ledges Pkwy. Ste 201 Akron, OH 44311 USA

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TABLE OF CONTENTS

VOLUME 1

SESSION A: FUNCTIONALAIZED ELASTOMER AND ADDITIVES

CONTROLLING THE CONDUCTIVE NETWORK FORMATION OF POLYMER NANOCOMPOSITES FILLED WITH NANORODS THROUGH THE ELECTRIC FIELD ...................................... 1

Yangyang Gao, L. Zhang

DEVELOPMENT OF SULPHUR CURED CHLOROBUTYL RUBBER COMPOUND WITH EXCELLENT CURE-REVERSION RESISTANCE AND LOW-COMPRESSION SET PROPERTIES USING A NOVEL CROSSLINKING CO-AGENT ............................................................................... 20

Shibulal Gopisathi, Jinseok Jeon, Chang Hyun Yun, Joohye Won, Changwoon Nah

REINFORCEMENT OF RUBBER COMPOUNDS UTILIZING FUNCTIONALIZED & DISCRETE MULTI-WALL CARBON NANOTUBES ........................................................................................................................ 29

August Krupp, Sateesh Peddini

STUDIES ON NOVEL FUNCTIONALIZED SSBR AND DIFFERENT TYPE OF SILICA ? SILANE SYSTEMS ON MODEL TIRE TREAD COMPOUNDS PROPERTIES ....................................................................... 44

Natalia Meissner, Jaroslaw Rogoza, Pawel Weda

A NOVEL FUNCTIONAL ADDITIVE FOR TAILORING THE CURE REVERSION, CROSSLINK DENSITY AND SET PROPERTIES IN POLYISOPRENE AND CHLORINATED ISOBUTYLENEISOPRENE RUBBERS ....................................................................................................................................................... 59

Changwoon Nah, Wonseok Wang, Shibulal Gopisathi, Hak Hyun Kim

DEVELOPMENT OF POLYMERS BASED ON 1-FUNCTIONALIZED BENZOCYCLOBUTENEBASED MONOMERS WITH CONTROLLED CURING TEMPERATURES ............................................................ 68

Coleen Pugh, William K. Storms-Miller, Ajay Amrutkar, Isamau Ono, James S. Baker

INCREASING THE MILEAGE ? NEW FUNCTIONALIZED SSBR FOR FUEL EFFICIENT TIRES ................................................................................................................................................................................... 72

Michael Roessle, Christian D?ring, Sven K. H. Thiele, Sybill Ilisch, Dominique Thielemann, Daniel Heidenreich

THE EFFECT OF PLASMA FUNCTIONALISATION OF CARBON NANOMATERIAL ADDITIVES ON THE MECHANICAL AND PHYSICAL PROPERTIES OF NATURAL RUBBER ...................... 93

Matthew Thornton, Martyn Bennett

REINFORCEMENT OF STYRENE-BUTADIENE RUBBER BY SUPRAMOLECULAR FILLERS .................... 102

Xin Tan, Mengsha Qian, Yihong Zhao, Gary Hamed, Li Jia

HIGHLY AGING-RESISTANT ELASTOMERS DOPED WITH ANTIOXIDANT-LOADED CLAY NANOTUBES .................................................................................................................................................................... 122

Wencai Wang, Ye Fu, Liqun Zhang, Yuri Lvov

NEW DEVELOPMENTS IN TRUCK TYRES: PERFORMANCE AND SUSTAINABILITY................................. 126

Fabio Bacchelli, Federico Grasso, Barbara Pellizzari, Piera De Marco, Giovanni Cuder, Thomas Wu, Salvatore Coppola

INFLUENCE OF NEW GENERATION FILLERS ON THE PHYSICAL PROPERTIES, TEARING ENERGY AND ABRASION RESISTANCE OF TYRE TREAD COMPOUND......................................................... 136

Vivekanda Lodha, Sanjay Bhattacharyya, Saikat Dasgupta, Rabindra Mukhopadhyay, Preetom Sarkar, Anil K. Bhowmick

ANISOTROPIC EFFECTS AND MASTER CURVES FOR RUBBERS WITH SP2 CARBON ALLOTROPES: TOWARDS LIGHT WEIGHT MATERIALS .................................................................................. 167

Galimberti Maurizio, Guerra Silvia, Infortuna Giuseppe, Barbera Vincenzina, Bernardi Andrea, Mastinu Giampiero, Agnelli Silvia, Pandini Stefano

SERINOL: A BIOSOURCED BUILDING BLOCK FOR BETTER MECHANICAL REINFORCEMENT AND SUSTAINABLE VULCANIZATION OF RUBBER COMPOUNDS ............................. 196

Galimberti Maurizio, Barbera Vincenzina, Infortuna Giuseppe, Cipolletti Valeria, Citterio Attilio, Sun Shuquan

OPTIMIZATION OF THE SILICA / POLYMER INTERFACE IN THE CASE OF VERY HIGH SURFACE SILICA : NEW METHODS TO SUPPORT FORMULATION ADJUSTEMENTS FOR PASSENGER CAR AND TRUCK TIRE TREADS ....................................................................................................... 224

Laurent Guy , Thomas Chauss?e

BREAKTHROUGH SINGLE WALL CARBON NANOTUBE TECHNOLOGY EXPANDS MECHANICAL AND ELECTRICAL PROPERTIES OF ELASTOMERS ............................................................... 248

Jean-Nicholas Helt

TRADE-OFF BETWEEN FILLER DISPERSION AND HYSTERESIS..................................................................... 266

Sadhan C. Jana

NOVEL APPROACH TO COUPLING FUNCTIONALIZED CARBON BLACK IN NONFUNCTIONALIZED ELASTOMER SYSTEMS ........................................................................................................... 269

Zachary A. Combs, Charles Herd, John Curtis, Mahatab Chowdhury

PLASMA MODIFICATION OF POLYMERIC SINGLE END CORDS AS AN ALTERNATIVE TO RFL TREATMENT........................................................................................................................................................... 279

A. Louis, J. W. M. Noordermeer, W. K. Dierkes, A. Blume

EVALUATION OF RUBBER PROCESS OILS IN WINTER TIRES......................................................................... 313

Mika Lahtinen, Kamyar Alavi, Patrik Salomonsson, Herbert Fruhmann, Anna Eriksson

ADVANCED CARBON BLACKS TO ENHANCE TIRE PERFORMANCE............................................................. 324

Leszek Nikiel, Wesley Wampler

POWDER LIQUID DISPERSIONS OF PLASTICIZERS TO INCREASE THROUGHPUT AND MEET SUSTAINABILITY GOALS FOR TIRE TREAD FORMULATIONS ........................................................... 349

Dejan Andjelkovic, Bradley Pentzien, Stephen O'Rourke

PERFORMANCE IMPROVEMENTS WITH SYLVATRAXXTM TREAD ENHANCEMENT ADDITIVES - INFLUENCE OF THE SELECTION OF POLYMERS AND POLYMER BLENDS ....................... 359

Wolfgang Pille-Wolf

VINYL CIS RUBBER (VCR) SUPERIOR POLYMER FOR FUTURE TRENDS..................................................... 370

Toemphong Puvanatvattana, Thawat Chansorn

MANIPULATING SSBR MICROSTRUCTURES FOR UNIQUE MATERIAL PROPERTIES AND HIGHER TIRE PERFORMANCE.................................................................................................................................. 382

Jm Yu, Chun Lin Chen, Joseph Chiu, Adel F. Halasa

ADHESION OF MILLABLE (SOLID RUBBER) POLYURETHANES TO GENERAL PURPOSE RUBBER ............................................................................................................................................................................ 393

Thomas L. Jablonowski

GRAPHENE IN MIXED SOLVENTS: A PATH TOWARDS GRAPHENE FILMS, EMULSIONS AND FOAMS ..................................................................................................................................................................... 406

Andrey V. Dobrynin

ADHESION AND TENSILE PROPERTIES OF AN AGED AND NON-AGED SBR RUBBER BLEND, ANALYZED USING MULTISCALE-CONTACT-MECHANICS AND A CHEMICAL KINETICS AGING MODEL ........................................................................................................................................... 410

Nestor Rodriguez, D. Cusato, L. Dorogin, K. T. Chew, B. N. J. Persson

EVALUATING THE OCTAVINYL POLYHEDRAL OLIGOMERIC SILSESQUIOXANE AS AN ADHESION PROMOTER FOR POLYMERIC TEXTILE CORDS AND TIRE-RUBBER MATRIX .................... 428

Bagdag?l Karaaga?, Samet Dursun, Nazli Yazici, Burak Kilic, T. Yanci, G. Ozkoc, M. Kodal

SESSION B: MIZING & PROCESSING TECHNOLOGY

THE NEW CONCEPT OF NATURAL RUBBER QUALITY CHECK....................................................................... 440

David Chang

COMPARISON OF STATES OF MIX USING THE NEW ASTM PAYNE EFFECT METHOD VERSUS THE ASTM DISPERSION METHOD ........................................................................................................... 452

John S. Dick, Edward Norton

THE EFFECT OF METAL SOAPS ON EXTRUSION RHEOLOGICAL PROPERTIES OF SILICA FILLED SBR/BR COMPOSITES.................................................................................................................................... 495

Kunhao Feng, Yanni Long, Shuang Wang, Xianping Sun, Zhaohui Chen

NEW DEVELOPMENT IN PROCESSING ADDITIVES FOR THE MODERN RUBBER INDUSTRY ........................................................................................................................................................................ 509

K. P. Ho, Jens Schwentner

THE ROLE OF COUPLING AGENTS IN DUAL DISPERSION OF SILICA AND CARBON BLACK............................................................................................................................................................................... 529

Sadhan Jana, Hamad Albehaijan, Darnell Wims, Nicole Swanson, Coleen Pugh

SILICA MIXING............................................................................................................................................................... 535

Richard Jorkasky

NEW EPDM MOLECULAR ARCHITECTURE AND ITS EFFECT ON PROCESSING CHARACTERISTICS AND COMPOUND PROPERTIES .......................................................................................... 552

Greg Li, Colin Shan, Lena Nguyen, Juan Tuberquia, Sharon Wu, Ray Laakso, Tao Han, Rongjuan Cong, Dean Lee

ADDITION CURE HCR: IMPACT OF INHIBITORS ON THE ELASTOMER CURE PROFILE ........................ 570

Charles Olsen Jr., Hans Haas, George Stamper

USING VEGETAL TANNIN TO PRESERVE NATURAL RUBBER LATEX AND TO DECREASE OR SUPPRESS ITS ALLERGENIC ACTION............................................................................................................... 578

Floriano Pastore, Jo?o Bosco Peres, J?lia Kramer, Natalia Gomes, Carlos Wolf, Leonardo Paterno

VOLUME 2

EXAMINATION OF WALL SLIPPING EFFECTS IN EPDM RUBBERS AS A FUNCTION OF THE MOLAR MASS, THE MIXTURE COMPOSITION AND SURFACE COATINGS IN THE HIGH-PRESSURE CAPILLARY VISCOSIMETER (HCV)........................................................................................ 592

Katja Putzig, Ulrich Giese, B. Klie

CASE STUDY: PROCESS OPTIMIZATION FOR HIGHLY FILLED NBR/SBR COMPOUNDS......................... 610

Travis Rosmus

IMPROVE BANBURY MIX QUALITY......................................................................................................................... 616

Leighton Spadone

FKM MATERIAL STORAGE & PERFORMANCE ANALYSIS ............................................................................... 626

Blake White

ADVANCED IP STRATEGY: YOU DON'T NEED A PATENT IF .... ....................................................................... 645

Jacob Ward

LIVING WITH THE NEW TOXIC SUBSTANCES CONTROL ACT ....................................................................... 653

Mark Duvall

GENERAL LEGAL CONSIDERATIONS FOR PRODUCT DEVELOPMENT IN POLYMER & MATERIAL INDUSTRIES .............................................................................................................................................. 664

Jiazhong (Jason) Luo

PROPOSED MECHANISM FOR A NOVELTY INTERPENETRATING POLYMER NETWORK...................... 675

Gina Butuc, Auke Talma, Wilma K. Dierkes, Louis Reuvekamp, Anke Blume

VISUALIZING RUBBER MOLECULES AND THEIR MONOMERS ? A COMPUTER AIDED SIMULATION APPROACH............................................................................................................................................ 693

Subhabrata Saha, Tuhin Saha, Preetom Sarkar, Anil K Bhowmick

MAGIC SULFUR, CYCLODODECASULFUR: A NOVEL VULCANIZING AGENT ............................................ 736

Frederick Ignatz-Hoover, Scott Barnicki, Robert Hembre

RUBBER MAGNETS CURED WITH PEROXIDE CURING SYSTEMS .................................................................. 752

J?n Kruzel?k, Rastislav Dosoudil, Ivan Hudec

RUBBER CHEMISTRY AND TECHNOLOGY: TRENDS, OPPORTUNITIES AND GETTING PUBLISHED IN YOUR SCIENTIFIC JOURNAL ........................................................................................................ 761

William Mars

PREDISPERSED SHORT FIBERS: A COST EFFECTIVE WAY TO REINFORCE RUBBER COMPOUNDS ................................................................................................................................................................... 774

Joel Neilsen, Steven Monthey, Cristian Oprisoni

ANALYSIS ON PARTITION BEHAVIOR OF HYDROCARBON RESINS IN TIRE COMPOUNDS OF AN IMMISCIBLE BLEND ........................................................................................................................................ 792

Xiao-Dong Pan

RATIONALISING EPDM RUBBER COMPOUND DATA VIA MASTER CURVES: NOT ONLY PRACTICAL BUT ALSO ENHANCED UNDERSTANDING ..................................................................................... 838

Martin Van Duin, Pete Spanos

DETERMINATION OF PAHS IN TIRES BY GC/MS AND NMR - HOW WELL DOES THE ISO 21461 (NMR) METHOD UPHOLD THE EU'S ORIGINAL PAH STANDARDS FOR THE TIRES?..................... 856

Joseph Pan, Robert Legg

THE BENEFITS OF LASER MOLD CLEANING........................................................................................................ 872

Timothy Graham

MORPHOLOGY AND NANOMECHANICAL CHARACTERISTICS OF NR/SBR BLENDS ............................... 881

Anna Kepas-Suwara, Darja Klat, Jorge Lacayo-Pineda, Stuart Cook

A NEW CONSTITUTIVE MODEL FOR THE NONLINEAR VISCOELASTIC BEHAVIOUR OF CARBON-BLACK REINFORCED RUBBER IN MEDIUM DYNAMIC STRAINS AND MEDIUM STRAIN RATES................................................................................................................................................................ 908

Francesca Carleo, E. Barbieri, J. J. C. Busfield

FATIGUE BEHAVIOUR OF CORD-RUBBER COMPOSITES UNDER A COMPLEX TENSION AND BENDING LOADING ............................................................................................................................................. 914

Y. Tao, E. Bilotti, J. J. C. Busfield

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